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href="/w/index.php?title=Special:%E7%94%A8%E6%88%B7%E7%99%BB%E5%BD%95&returnto=%E5%86%A0%E9%86%9A" title="建议你登录，尽管并非必须。[o]" accesskey="o"><span class="vector-icon mw-ui-icon-logIn mw-ui-icon-wikimedia-logIn"></span> <span>登录</span></a></li> </ul> </div> </div> <div id="p-user-menu-anon-editor" class="vector-menu mw-portlet mw-portlet-user-menu-anon-editor" > <div class="vector-menu-heading"> 未登录编辑者的页面 <a href="/wiki/Help:%E6%96%B0%E6%89%8B%E5%85%A5%E9%97%A8" aria-label="了解有关编辑的更多信息"><span>了解详情</span></a> </div> <div class="vector-menu-content"> <ul class="vector-menu-content-list"> <li id="pt-anoncontribs" class="mw-list-item"><a href="/wiki/Special:%E6%88%91%E7%9A%84%E8%B4%A1%E7%8C%AE" title="来自此IP地址的编辑列表[y]" accesskey="y"><span>贡献</span></a></li><li id="pt-anontalk" class="mw-list-item"><a href="/wiki/Special:%E6%88%91%E7%9A%84%E8%AE%A8%E8%AE%BA%E9%A1%B5" title="对于来自此IP地址编辑的讨论[n]" accesskey="n"><span>讨论</span></a></li> </ul> </div> </div> </div> </div> </nav> </div> </header> </div> <div class="mw-page-container"> <div class="mw-page-container-inner"> <div class="vector-sitenotice-container"> <div id="siteNotice"></div> </div> <div class="vector-column-start"> <div class="vector-main-menu-container"> <div id="mw-navigation"> <nav id="mw-panel" class="vector-main-menu-landmark" aria-label="站点"> <div id="vector-main-menu-pinned-container" class="vector-pinned-container"> </div> </nav> </div> </div> <div class="vector-sticky-pinned-container"> <nav id="mw-panel-toc" aria-label="目录" data-event-name="ui.sidebar-toc" class="mw-table-of-contents-container vector-toc-landmark"> <div id="vector-toc-pinned-container" class="vector-pinned-container"> <div id="vector-toc" class="vector-toc vector-pinnable-element"> <div class="vector-pinnable-header vector-toc-pinnable-header vector-pinnable-header-pinned" data-feature-name="toc-pinned" data-pinnable-element-id="vector-toc" > <h2 class="vector-pinnable-header-label">目录</h2> <button class="vector-pinnable-header-toggle-button 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<ul id="toc-命名-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-阳离子亲和性" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#阳离子亲和性"> <div class="vector-toc-text"> <span class="vector-toc-numb">3</span> <span>阳离子亲和性</span> </div> </a> <ul id="toc-阳离子亲和性-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-氮杂冠醚" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#氮杂冠醚"> <div class="vector-toc-text"> <span class="vector-toc-numb">4</span> <span>氮杂冠醚</span> </div> </a> <ul id="toc-氮杂冠醚-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-自然界中的“冠醚”" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#自然界中的“冠醚”"> <div class="vector-toc-text"> <span class="vector-toc-numb">5</span> <span>自然界中的“冠醚”</span> </div> </a> <ul id="toc-自然界中的“冠醚”-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-安全" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#安全"> <div class="vector-toc-text"> <span class="vector-toc-numb">6</span> <span>安全</span> </div> </a> <ul id="toc-安全-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-参考文献" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#参考文献"> <div class="vector-toc-text"> <span class="vector-toc-numb">7</span> <span>参考文献</span> </div> </a> <ul id="toc-参考文献-sublist" class="vector-toc-list"> </ul> </li> </ul> </div> </div> </nav> </div> </div> <div class="mw-content-container"> <main id="content" class="mw-body"> <header class="mw-body-header vector-page-titlebar"> <nav aria-label="目录" class="vector-toc-landmark"> <div id="vector-page-titlebar-toc" class="vector-dropdown vector-page-titlebar-toc vector-button-flush-left" > <input type="checkbox" id="vector-page-titlebar-toc-checkbox" role="button" aria-haspopup="true" data-event-name="ui.dropdown-vector-page-titlebar-toc" class="vector-dropdown-checkbox " aria-label="开关目录" > <label id="vector-page-titlebar-toc-label" for="vector-page-titlebar-toc-checkbox" class="vector-dropdown-label cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--icon-only " aria-hidden="true" ><span class="vector-icon mw-ui-icon-listBullet mw-ui-icon-wikimedia-listBullet"></span> <span class="vector-dropdown-label-text">开关目录</span> </label> <div class="vector-dropdown-content"> <div id="vector-page-titlebar-toc-unpinned-container" class="vector-unpinned-container"> </div> </div> </div> </nav> <h1 id="firstHeading" class="firstHeading mw-first-heading"><span class="mw-page-title-main">冠醚</span></h1> <div id="p-lang-btn" class="vector-dropdown mw-portlet mw-portlet-lang" > <input type="checkbox" id="p-lang-btn-checkbox" role="button" aria-haspopup="true" data-event-name="ui.dropdown-p-lang-btn" class="vector-dropdown-checkbox mw-interlanguage-selector" aria-label="前往另一种语言写成的文章。25种语言可用" > <label id="p-lang-btn-label" for="p-lang-btn-checkbox" class="vector-dropdown-label cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--action-progressive mw-portlet-lang-heading-25" aria-hidden="true" ><span class="vector-icon mw-ui-icon-language-progressive mw-ui-icon-wikimedia-language-progressive"></span> <span class="vector-dropdown-label-text">25种语言</span> </label> <div class="vector-dropdown-content"> <div class="vector-menu-content"> <ul class="vector-menu-content-list"> <li class="interlanguage-link interwiki-ar mw-list-item"><a href="https://ar.wikipedia.org/wiki/%D8%A5%D9%8A%D8%AB%D8%B1_%D8%AA%D8%A7%D8%AC%D9%8A" title="إيثر تاجي – 阿拉伯语" lang="ar" hreflang="ar" data-title="إيثر تاجي" data-language-autonym="العربية" data-language-local-name="阿拉伯语" class="interlanguage-link-target"><span>العربية</span></a></li><li class="interlanguage-link interwiki-az mw-list-item"><a href="https://az.wikipedia.org/wiki/Kraun_efirl%C9%99ri" title="Kraun efirləri – 阿塞拜疆语" lang="az" hreflang="az" data-title="Kraun efirləri" data-language-autonym="Azərbaycanca" data-language-local-name="阿塞拜疆语" class="interlanguage-link-target"><span>Azərbaycanca</span></a></li><li class="interlanguage-link interwiki-be mw-list-item"><a href="https://be.wikipedia.org/wiki/%D0%9A%D1%80%D0%B0%D1%9E%D0%BD-%D1%8D%D1%84%D1%96%D1%80%D1%8B" title="Краўн-эфіры – 白俄罗斯语" lang="be" hreflang="be" data-title="Краўн-эфіры" data-language-autonym="Беларуская" data-language-local-name="白俄罗斯语" class="interlanguage-link-target"><span>Беларуская</span></a></li><li class="interlanguage-link interwiki-ca mw-list-item"><a href="https://ca.wikipedia.org/wiki/%C3%88ter_corona" title="Èter corona – 加泰罗尼亚语" lang="ca" hreflang="ca" data-title="Èter corona" data-language-autonym="Català" data-language-local-name="加泰罗尼亚语" class="interlanguage-link-target"><span>Català</span></a></li><li class="interlanguage-link interwiki-de mw-list-item"><a href="https://de.wikipedia.org/wiki/Kronenether" title="Kronenether – 德语" lang="de" hreflang="de" data-title="Kronenether" data-language-autonym="Deutsch" data-language-local-name="德语" class="interlanguage-link-target"><span>Deutsch</span></a></li><li class="interlanguage-link interwiki-en mw-list-item"><a href="https://en.wikipedia.org/wiki/Crown_ether" title="Crown ether – 英语" lang="en" hreflang="en" data-title="Crown ether" data-language-autonym="English" data-language-local-name="英语" class="interlanguage-link-target"><span>English</span></a></li><li class="interlanguage-link interwiki-es mw-list-item"><a href="https://es.wikipedia.org/wiki/%C3%89ter_de_corona" title="Éter de corona – 西班牙语" lang="es" hreflang="es" data-title="Éter de corona" data-language-autonym="Español" data-language-local-name="西班牙语" class="interlanguage-link-target"><span>Español</span></a></li><li class="interlanguage-link interwiki-et mw-list-item"><a href="https://et.wikipedia.org/wiki/Krooneetrid" title="Krooneetrid – 爱沙尼亚语" lang="et" hreflang="et" data-title="Krooneetrid" data-language-autonym="Eesti" data-language-local-name="爱沙尼亚语" class="interlanguage-link-target"><span>Eesti</span></a></li><li class="interlanguage-link interwiki-fa mw-list-item"><a href="https://fa.wikipedia.org/wiki/%D8%A7%D8%AA%D8%B1_%D8%AA%D8%A7%D8%AC%DB%8C" title="اتر تاجی – 波斯语" lang="fa" hreflang="fa" data-title="اتر تاجی" data-language-autonym="فارسی" data-language-local-name="波斯语" class="interlanguage-link-target"><span>فارسی</span></a></li><li class="interlanguage-link interwiki-fi mw-list-item"><a href="https://fi.wikipedia.org/wiki/Kruunueetterit" title="Kruunueetterit – 芬兰语" lang="fi" hreflang="fi" data-title="Kruunueetterit" data-language-autonym="Suomi" data-language-local-name="芬兰语" class="interlanguage-link-target"><span>Suomi</span></a></li><li class="interlanguage-link interwiki-fr mw-list-item"><a href="https://fr.wikipedia.org/wiki/%C3%89ther_couronne" title="Éther couronne – 法语" lang="fr" hreflang="fr" data-title="Éther couronne" data-language-autonym="Français" data-language-local-name="法语" class="interlanguage-link-target"><span>Français</span></a></li><li class="interlanguage-link interwiki-he mw-list-item"><a href="https://he.wikipedia.org/wiki/%D7%90%D7%AA%D7%A8_%D7%9B%D7%AA%D7%A8" title="אתר כתר – 希伯来语" lang="he" hreflang="he" data-title="אתר כתר" data-language-autonym="עברית" data-language-local-name="希伯来语" class="interlanguage-link-target"><span>עברית</span></a></li><li class="interlanguage-link interwiki-hu mw-list-item"><a href="https://hu.wikipedia.org/wiki/Korona%C3%A9ter" title="Koronaéter – 匈牙利语" lang="hu" hreflang="hu" data-title="Koronaéter" data-language-autonym="Magyar" data-language-local-name="匈牙利语" class="interlanguage-link-target"><span>Magyar</span></a></li><li class="interlanguage-link interwiki-id mw-list-item"><a href="https://id.wikipedia.org/wiki/Eter_mahkota" title="Eter mahkota – 印度尼西亚语" lang="id" hreflang="id" data-title="Eter mahkota" data-language-autonym="Bahasa Indonesia" data-language-local-name="印度尼西亚语" class="interlanguage-link-target"><span>Bahasa Indonesia</span></a></li><li class="interlanguage-link interwiki-it mw-list-item"><a href="https://it.wikipedia.org/wiki/Eteri_corona" title="Eteri corona – 意大利语" lang="it" hreflang="it" data-title="Eteri corona" data-language-autonym="Italiano" data-language-local-name="意大利语" class="interlanguage-link-target"><span>Italiano</span></a></li><li class="interlanguage-link interwiki-ja mw-list-item"><a href="https://ja.wikipedia.org/wiki/%E3%82%AF%E3%83%A9%E3%82%A6%E3%83%B3%E3%82%A8%E3%83%BC%E3%83%86%E3%83%AB" title="クラウンエーテル – 日语" lang="ja" hreflang="ja" data-title="クラウンエーテル" data-language-autonym="日本語" data-language-local-name="日语" class="interlanguage-link-target"><span>日本語</span></a></li><li class="interlanguage-link interwiki-ko mw-list-item"><a href="https://ko.wikipedia.org/wiki/%ED%81%AC%EB%9D%BC%EC%9A%B4_%EC%97%90%ED%84%B0" title="크라운 에터 – 韩语" lang="ko" hreflang="ko" data-title="크라운 에터" data-language-autonym="한국어" data-language-local-name="韩语" class="interlanguage-link-target"><span>한국어</span></a></li><li class="interlanguage-link interwiki-nl mw-list-item"><a href="https://nl.wikipedia.org/wiki/Kroonether" title="Kroonether – 荷兰语" lang="nl" hreflang="nl" data-title="Kroonether" data-language-autonym="Nederlands" data-language-local-name="荷兰语" class="interlanguage-link-target"><span>Nederlands</span></a></li><li class="interlanguage-link interwiki-pl mw-list-item"><a href="https://pl.wikipedia.org/wiki/Etery_koronowe" title="Etery koronowe – 波兰语" lang="pl" hreflang="pl" data-title="Etery koronowe" data-language-autonym="Polski" data-language-local-name="波兰语" class="interlanguage-link-target"><span>Polski</span></a></li><li class="interlanguage-link interwiki-pt mw-list-item"><a href="https://pt.wikipedia.org/wiki/%C3%89ter_coroa" title="Éter coroa – 葡萄牙语" lang="pt" hreflang="pt" data-title="Éter coroa" data-language-autonym="Português" data-language-local-name="葡萄牙语" class="interlanguage-link-target"><span>Português</span></a></li><li class="interlanguage-link interwiki-ro mw-list-item"><a href="https://ro.wikipedia.org/wiki/Eter_coroan%C4%83" title="Eter coroană – 罗马尼亚语" lang="ro" hreflang="ro" data-title="Eter coroană" data-language-autonym="Română" data-language-local-name="罗马尼亚语" class="interlanguage-link-target"><span>Română</span></a></li><li class="interlanguage-link interwiki-ru mw-list-item"><a href="https://ru.wikipedia.org/wiki/%D0%9A%D1%80%D0%B0%D1%83%D0%BD-%D1%8D%D1%84%D0%B8%D1%80%D1%8B" title="Краун-эфиры – 俄语" lang="ru" hreflang="ru" data-title="Краун-эфиры" data-language-autonym="Русский" data-language-local-name="俄语" class="interlanguage-link-target"><span>Русский</span></a></li><li class="interlanguage-link interwiki-tr mw-list-item"><a href="https://tr.wikipedia.org/wiki/Ta%C3%A7_eter" title="Taç eter – 土耳其语" lang="tr" hreflang="tr" data-title="Taç eter" data-language-autonym="Türkçe" data-language-local-name="土耳其语" class="interlanguage-link-target"><span>Türkçe</span></a></li><li class="interlanguage-link interwiki-uk mw-list-item"><a href="https://uk.wikipedia.org/wiki/%D0%9A%D1%80%D0%B0%D1%83%D0%BD-%D0%B5%D1%82%D0%B5%D1%80%D0%B8" title="Краун-етери – 乌克兰语" lang="uk" hreflang="uk" data-title="Краун-етери" data-language-autonym="Українська" data-language-local-name="乌克兰语" class="interlanguage-link-target"><span>Українська</span></a></li><li class="interlanguage-link interwiki-uz mw-list-item"><a href="https://uz.wikipedia.org/wiki/Kraun_efirlari" title="Kraun efirlari – 乌兹别克语" lang="uz" hreflang="uz" data-title="Kraun efirlari" data-language-autonym="Oʻzbekcha / ўзбекча" 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<div id="vector-appearance-pinned-container" class="vector-pinned-container"> <div id="vector-appearance" class="vector-appearance vector-pinnable-element"> <div class="vector-pinnable-header vector-appearance-pinnable-header vector-pinnable-header-pinned" data-feature-name="appearance-pinned" data-pinnable-element-id="vector-appearance" data-pinned-container-id="vector-appearance-pinned-container" data-unpinned-container-id="vector-appearance-unpinned-container" > <div class="vector-pinnable-header-label">外观</div> <button class="vector-pinnable-header-toggle-button vector-pinnable-header-pin-button" data-event-name="pinnable-header.vector-appearance.pin">移至侧栏</button> <button class="vector-pinnable-header-toggle-button vector-pinnable-header-unpin-button" data-event-name="pinnable-header.vector-appearance.unpin">隐藏</button> </div> </div> </div> </nav> </div> </div> <div id="bodyContent" class="vector-body" aria-labelledby="firstHeading" data-mw-ve-target-container> <div class="vector-body-before-content"> <div class="mw-indicators"> </div> <div id="siteSub" class="noprint">维基百科，自由的百科全书</div> </div> <div id="contentSub"><div id="mw-content-subtitle"></div></div> <div id="mw-content-text" class="mw-body-content"><div class="mw-content-ltr mw-parser-output" lang="zh" dir="ltr"><figure class="mw-halign-right" typeof="mw:File/Thumb"><a href="/wiki/File:18-crown-6-potassium-3D-balls-A.png" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/2/20/18-crown-6-potassium-3D-balls-A.png/200px-18-crown-6-potassium-3D-balls-A.png" decoding="async" width="200" height="199" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/2/20/18-crown-6-potassium-3D-balls-A.png/300px-18-crown-6-potassium-3D-balls-A.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/2/20/18-crown-6-potassium-3D-balls-A.png/400px-18-crown-6-potassium-3D-balls-A.png 2x" data-file-width="1100" data-file-height="1096" /></a><figcaption><a href="/wiki/18-%E5%86%A0-6" title="18-冠-6">18-冠-6</a>与一个钾离子配位</figcaption></figure> <p><b>冠醚</b>是一种<a href="/wiki/%E6%9D%82%E7%8E%AF" class="mw-redirect" title="杂环">杂环</a><a href="/wiki/%E6%9C%89%E6%9C%BA%E5%8C%96%E5%90%88%E7%89%A9" title="有机化合物">有机化合物</a>，包含有多个<a href="/wiki/%E9%86%9A" title="醚">醚</a>基团。最常见的冠醚就是<a href="/wiki/%E4%B9%99%E6%92%91%E6%B0%A7" class="mw-redirect" title="乙撑氧">乙撑氧</a>的低聚物，其中重复的单位是乙烯氧基（-CH<sub>2</sub>CH<sub>2</sub>O- 可看作是<a href="/wiki/%E7%8E%AF%E6%B0%A7%E4%B9%99%E7%83%B7" title="环氧乙烷">环氧乙烷</a>断裂碳氧键后的剩余基团）。这一系列中最重要的是四聚体、五聚体和六聚体。之所以用“冠”来命名，是因为就像<a href="/wiki/%E7%9A%87%E5%86%A0" title="皇冠">皇冠</a>可以戴在头上一样，冠醚能够和一个<a href="/wiki/%E9%98%B3%E7%A6%BB%E5%AD%90" class="mw-redirect" title="阳离子">阳离子</a>成键。在冠醚的命名法中，前面那个数字代表了环内的原子数，第二个数字代表<a href="/wiki/%E6%B0%A7" title="氧">氧</a>的个数。冠醚的概念远远大于乙撑氧的低聚物，另外一个很重要的系列是<a href="/wiki/%E9%82%BB%E8%8B%AF%E4%BA%8C%E9%85%9A" title="邻苯二酚">鄰苯二酚</a>的衍生物。 </p><p>冠醚一般通过<a href="/wiki/%E5%8D%A4%E4%BB%A3%E7%83%83" class="mw-redirect" title="卤代烃">卤代烃</a>与<a href="/wiki/%E9%86%87%E7%9B%90" title="醇盐">醇盐</a>的<a href="/wiki/%E5%A8%81%E5%BB%89%E5%A7%86%E9%80%8A%E5%90%88%E6%88%90" class="mw-redirect" title="威廉姆逊合成">威廉姆逊合成</a>反应制取。 </p> <figure class="mw-halign-center" typeof="mw:File/Thumb"><a href="/wiki/File:Various_crown_ethers_(molecular_diagrams).png" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/9/9f/Various_crown_ethers_%28molecular_diagrams%29.png/700px-Various_crown_ethers_%28molecular_diagrams%29.png" decoding="async" width="700" height="119" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/9/9f/Various_crown_ethers_%28molecular_diagrams%29.png/1050px-Various_crown_ethers_%28molecular_diagrams%29.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/9/9f/Various_crown_ethers_%28molecular_diagrams%29.png/1400px-Various_crown_ethers_%28molecular_diagrams%29.png 2x" data-file-width="1909" data-file-height="325" /></a><figcaption>常见冠醚的结构：<a href="/wiki/12-%E5%86%A0-4" title="12-冠-4">12-冠-4</a>、<a href="/wiki/15-%E5%86%A0-5" title="15-冠-5">15-冠-5</a>、<a href="/wiki/18-%E5%86%A0-6" title="18-冠-6">18-冠-6</a>、<a href="/wiki/%E4%BA%8C%E8%8B%AF%E5%B9%B6-18-%E5%86%A0-6" title="二苯并-18-冠-6">二苯并-18-冠-6</a>和<a href="/w/index.php?title=%E4%BA%8C%E6%B0%AE-18-%E5%86%A0-6&action=edit&redlink=1" class="new" title="二氮-18-冠-6（页面不存在）">二氮-18-冠-6</a>。</figcaption></figure> <meta property="mw:PageProp/toc" /> <div class="mw-heading mw-heading2"><h2 id="历史"><span id=".E5.8E.86.E5.8F.B2"></span>历史</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E5%86%A0%E9%86%9A&action=edit&section=1" title="编辑章节：历史"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <figure typeof="mw:File/Thumb"><a href="/wiki/File:Cyclen_Zinc_InorgChem_1997_4579_commons.jpg" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/9/97/Cyclen_Zinc_InorgChem_1997_4579_commons.jpg/150px-Cyclen_Zinc_InorgChem_1997_4579_commons.jpg" decoding="async" width="150" height="188" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/9/97/Cyclen_Zinc_InorgChem_1997_4579_commons.jpg/225px-Cyclen_Zinc_InorgChem_1997_4579_commons.jpg 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/9/97/Cyclen_Zinc_InorgChem_1997_4579_commons.jpg/300px-Cyclen_Zinc_InorgChem_1997_4579_commons.jpg 2x" data-file-width="503" data-file-height="629" /></a><figcaption>Zn(II)与环楞胺和乙醇配位的晶体结构。</figcaption></figure> <p>1967年，<a href="/wiki/%E6%9D%9C%E9%82%A6" title="杜邦">杜邦</a>公司的化学家<a href="/wiki/%E6%9F%A5%E5%B0%94%E6%96%AF%C2%B7%E4%BD%A9%E5%BE%B7%E6%A3%AE" title="查尔斯·佩德森">查尔斯·彼得森</a>在试图制备二价离子配体时发现了一种简单方法用以合成冠醚。<sup id="cite_ref-pedersen_1-0" class="reference"><a href="#cite_note-pedersen-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup>他的策略是试图通过分子上的一个羟基，连接两个苯邻二酚基团。这样就形成了一个<a href="/w/index.php?title=%E5%A4%9A%E9%BD%BF%E9%85%8D%E4%BD%93&action=edit&redlink=1" class="new" title="多齿配体（页面不存在）">多齿配体</a>，可以部分的包裹阳离子。接下来再使酚羟基离子化并中和包裹的二价阳离子。他很惊讶地发现，此反应的一个<a href="/wiki/%E5%89%AF%E4%BA%A7%E7%89%A9" class="mw-redirect" title="副产物">副产物</a>能够牢牢的与钾离子配位。在一份早期关于在16-冠-4中溶解钾的报告中提到，<sup id="cite_ref-stewart_2-0" class="reference"><a href="#cite_note-stewart-2"><span class="cite-bracket">[</span>2<span class="cite-bracket">]</span></a></sup> <sup id="cite_ref-down_3-0" class="reference"><a href="#cite_note-down-3"><span class="cite-bracket">[</span>3<span class="cite-bracket">]</span></a></sup>彼得森发现环多醚实际上是一类全新的化合物，有着与碱金属结合的能力。接下来，他发表了一系列的论文报告了经过系统研究的合成方法以及冠醚的成键性质。很多不同学科受益于冠醚的发现，包括<a href="/wiki/%E6%9C%89%E6%9C%BA%E5%90%88%E6%88%90" title="有机合成">有机合成</a>、<a href="/w/index.php?title=%E7%9B%B8%E8%BD%AC%E7%A7%BB%E5%82%AC%E5%8C%96&action=edit&redlink=1" class="new" title="相转移催化（页面不存在）">相转移催化</a>等。 </p><p>彼得森个人主要将注意力集中在二苯冠醚上。<sup id="cite_ref-4" class="reference"><a href="#cite_note-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup>他也因为发现了冠醚的合成方法及其性质，而分享了1987年的<a href="/wiki/%E8%AF%BA%E8%B4%9D%E5%B0%94%E5%8C%96%E5%AD%A6%E5%A5%96" title="诺贝尔化学奖">诺贝尔化学奖</a>。 </p> <div class="mw-heading mw-heading2"><h2 id="命名"><span id=".E5.91.BD.E5.90.8D"></span>命名</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E5%86%A0%E9%86%9A&action=edit&section=2" title="编辑章节：命名"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>命名时，把环上所含原子的总数标注在“冠”字之前，其中所含氧原子数标注在名称之后。如<a href="/wiki/18-%E5%86%A0-6" title="18-冠-6">18-冠(醚)-6</a>、15-冠（醚）-5、二环己烷并-18-冠（醚）-6。 </p> <div class="mw-heading mw-heading2"><h2 id="阳离子亲和性"><span id=".E9.98.B3.E7.A6.BB.E5.AD.90.E4.BA.B2.E5.92.8C.E6.80.A7"></span>阳离子亲和性</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E5%86%A0%E9%86%9A&action=edit&section=3" title="编辑章节：阳离子亲和性"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>除了与钾离子之间有着很高的亲和性，18-冠-6也能与质子化的<a href="/wiki/%E8%83%BA" title="胺">胺</a>结合，形成<a href="/wiki/%E6%B0%A3%E7%9B%B8" class="mw-redirect" title="氣相">气相</a>、<a href="/wiki/%E6%B6%B2%E7%9B%B8" class="mw-redirect" title="液相">液相</a>均很稳定的配合物。一些<a href="/wiki/%E6%B0%A8%E5%9F%BA%E9%85%B8" title="氨基酸">氨基酸</a>，例如<a href="/wiki/%E8%B5%96%E6%B0%A8%E9%85%B8" class="mw-redirect" title="赖氨酸">赖氨酸</a>，支链上有伯胺，因此它们能够与18-冠-6结合形成气相稳定的配合物。质子化以后的胺上的三个氢与18-冠-6上的三个氧形成<a href="/wiki/%E6%B0%A2%E9%94%AE" title="氢键">氢键</a>，使得结构更为稳定。 </p> <div class="mw-heading mw-heading2"><h2 id="氮杂冠醚"><span id=".E6.B0.AE.E6.9D.82.E5.86.A0.E9.86.9A"></span>氮杂冠醚</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E5%86%A0%E9%86%9A&action=edit&section=4" title="编辑章节：氮杂冠醚"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <style data-mw-deduplicate="TemplateStyles:r85100532">.mw-parser-output .hatnote{font-size:small}.mw-parser-output div.hatnote{padding-left:2em;margin-bottom:0.8em;margin-top:0.8em}.mw-parser-output .hatnote-notice-img::after{content:"\202f \202f \202f \202f "}.mw-parser-output .hatnote-notice-img-small::after{content:"\202f \202f "}.mw-parser-output .hatnote+link+.hatnote{margin-top:-0.5em}body.skin-minerva .mw-parser-output .hatnote-notice-img,body.skin-minerva .mw-parser-output .hatnote-notice-img-small{display:none}@media print{body.ns-0 .mw-parser-output .hatnote{display:none!important}}</style><div role="note" class="hatnote navigation-not-searchable">主条目：<span class="ilh-all" data-orig-title="氮雜冠醚" data-lang-code="en" data-lang-name="英语" data-foreign-title="Aza-crown ether"><span class="ilh-page"><a href="/w/index.php?title=%E6%B0%AE%E9%9B%9C%E5%86%A0%E9%86%9A&action=edit&redlink=1" class="new" title="氮雜冠醚（页面不存在）">氮雜冠醚</a></span><span class="noprint ilh-comment">（<span class="ilh-lang">英语</span><span class="ilh-colon">：</span><span class="ilh-link"><a href="https://en.wikipedia.org/wiki/Aza-crown_ether" class="extiw" title="en:Aza-crown ether"><span lang="en" dir="auto">Aza-crown ether</span></a></span>）</span></span></div> <p>氮杂冠醚是指将冠醚中的氧都换成氨基后形成的化合物，其中最著名的是一个四氮杂冠醚——<a href="/wiki/1,4,7,10-%E5%9B%9B%E6%B0%AE%E6%9D%82%E7%8E%AF%E5%8D%81%E4%BA%8C%E7%83%B7" title="1,4,7,10-四氮杂环十二烷">1,4,7,10-四氮雜環十二烷</a>。除此之外亦有氮氧混合冠醚以及<a href="/wiki/%E7%A9%B4%E7%8A%B6%E9%85%8D%E4%BD%93" title="穴状配体">穴狀配體</a>等衍生物。<sup id="cite_ref-5" class="reference"><a href="#cite_note-5"><span class="cite-bracket">[</span>5<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading2"><h2 id="自然界中的“冠醚”"><span id=".E8.87.AA.E7.84.B6.E7.95.8C.E4.B8.AD.E7.9A.84.E2.80.9C.E5.86.A0.E9.86.9A.E2.80.9D"></span>自然界中的“冠醚”</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E5%86%A0%E9%86%9A&action=edit&section=5" title="编辑章节：自然界中的“冠醚”"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>冠醚并不是唯一能够与钾离子结合的大环配体，诸如<a href="/w/index.php?title=%E6%97%A0%E6%B4%BB%E8%8F%8C%E7%B4%A0&action=edit&redlink=1" class="new" title="无活菌素（页面不存在）">无活菌素</a>或<a href="/wiki/%E7%BC%AC%E6%B0%A8%E9%9C%89%E7%B4%A0" title="缬氨霉素">缬氨霉素</a>等<a href="/w/index.php?title=%E7%A6%BB%E5%AD%90%E8%BD%BD%E4%BD%93&action=edit&redlink=1" class="new" title="离子载体（页面不存在）">离子载体</a>同样对钾离子有着特殊的亲和性。 </p> <div class="mw-heading mw-heading2"><h2 id="安全"><span id=".E5.AE.89.E5.85.A8"></span>安全</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E5%86%A0%E9%86%9A&action=edit&section=6" title="编辑章节：安全"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>冠醚有毒，尤其是对皮肤黏膜和眼睛有刺激作用，使用冠醚时，应避免吸入其蒸气、避免皮肤接触。<sup id="cite_ref-6" class="reference"><a href="#cite_note-6"><span class="cite-bracket">[</span>6<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading2"><h2 id="参考文献"><span id=".E5.8F.82.E8.80.83.E6.96.87.E7.8C.AE"></span>参考文献</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E5%86%A0%E9%86%9A&action=edit&section=7" title="编辑章节：参考文献"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <div class="reflist" style="list-style-type: decimal;"> <ol class="references"> <li id="cite_note-pedersen-1"><span class="mw-cite-backlink"><b><a href="#cite_ref-pedersen_1-0">^</a></b></span> <span class="reference-text">C. J. Pedersen, <i><a href="/wiki/J._Am._Chem._Soc." class="mw-redirect" title="J. Am. Chem. Soc.">J. Am. Chem. Soc.</a></i>, <b>1967</b>, 89, 7017.</span> </li> <li id="cite_note-stewart-2"><span class="mw-cite-backlink"><b><a href="#cite_ref-stewart_2-0">^</a></b></span> <span class="reference-text">D. G. Stewart. D. Y. Waddan and E. T. Borrows, British Patent 785,229, Oct. 23, <b>1957</b>.</span> </li> <li id="cite_note-down-3"><span class="mw-cite-backlink"><b><a href="#cite_ref-down_3-0">^</a></b></span> <span class="reference-text">J. L. Down, J. Lewis, B. Moore and G. W. Wilkinson, Proc. Chem. Soc., 1959, 209; J. Chem. Soc., <b>1959</b>, 3767.</span> </li> <li id="cite_note-4"><span class="mw-cite-backlink"><b><a href="#cite_ref-4">^</a></b></span> <span class="reference-text"><cite style="font-style:normal">Charles J. Pedersen (1988). "<a rel="nofollow" class="external text" href="http://www.orgsyn.org/demo.aspx?prep=CV6P0395">Macrocyclic Polyethers: Dibenzo-18-Crown-6 Polyether and Dicyclohexyl-18-Crown-6 Polyether</a>". <i><a href="/wiki/%E6%9C%89%E6%9C%BA%E5%90%88%E6%88%90_(%E6%9C%9F%E5%88%8A)" title="有机合成 (期刊)">Org. Synth.</a></i>; <i>Coll. Vol.</i> <b>6</b>: 395.</cite><span class="Z3988" title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Macrocyclic+Polyethers%3A+Dibenzo-18-Crown-6+Polyether+and+Dicyclohexyl-18-Crown-6+Polyether &rft.date=1988&rft.au=Charles+J.+Pedersen"> </span></span> </li> <li id="cite_note-5"><span class="mw-cite-backlink"><b><a href="#cite_ref-5">^</a></b></span> <span class="reference-text"><cite style="font-style:normal">Vincent J. Gatto, Steven R. Miller, and George W. Gokel (1988). "<a rel="nofollow" class="external text" href="http://www.orgsyn.org/demo.aspx?prep=CV8P0152">4,13-Diaza-18-Crown-6</a>". <i><a href="/wiki/%E6%9C%89%E6%9C%BA%E5%90%88%E6%88%90_(%E6%9C%9F%E5%88%8A)" title="有机合成 (期刊)">Org. Synth.</a></i>; <i>Coll. Vol.</i> <b>8</b>: 152.</cite><span class="Z3988" title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=4%2C13-Diaza-18-Crown-6 &rft.date=1988&rft.au=Vincent+J.+Gatto%2C+Steven+R.+Miller%2C+and+George+W.+Gokel"> </span></span> </li> <li id="cite_note-6"><span class="mw-cite-backlink"><b><a href="#cite_ref-6">^</a></b></span> <span class="reference-text">《有机化学》第二版.高等教育出版社.<b>9.8 环醚</b>.P<sub>336</sub>.<i>9.8.2 冠醚</i></span> </li> </ol></div> <p><a rel="nofollow" class="external text" href="http://www.labgogo.com/product/prolist_290.html">冠醚衍生物</a> （<a rel="nofollow" class="external text" href="//web.archive.org/web/20200924054333/http://www.labgogo.com/product/prolist_290.html">页面存档备份</a>，存于<a href="/wiki/%E4%BA%92%E8%81%94%E7%BD%91%E6%A1%A3%E6%A1%88%E9%A6%86" title="互联网档案馆">互联网档案馆</a>） </p> <div class="navbox-styles"><style data-mw-deduplicate="TemplateStyles:r84265675">.mw-parser-output .hlist dl,.mw-parser-output .hlist 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.navbar{display:none!important}}</style><div class="navbar plainlinks hlist navbar-mini"><ul><li class="nv-view"><a href="/wiki/Template:%E7%8E%AF%E7%8A%B6%E5%8C%96%E5%90%88%E7%89%A9" title="Template:环状化合物"><abbr title="查看该模板">查</abbr></a></li><li class="nv-talk"><a href="/wiki/Template_talk:%E7%8E%AF%E7%8A%B6%E5%8C%96%E5%90%88%E7%89%A9" title="Template talk:环状化合物"><abbr title="讨论该模板">论</abbr></a></li><li class="nv-edit"><a href="/wiki/Special:%E7%BC%96%E8%BE%91%E9%A1%B5%E9%9D%A2/Template:%E7%8E%AF%E7%8A%B6%E5%8C%96%E5%90%88%E7%89%A9" title="Special:编辑页面/Template:环状化合物"><abbr title="编辑该模板">编</abbr></a></li></ul></div><div id="环状化合物母体" style="font-size:110%;margin:0 5em"><a href="/wiki/%E7%8E%AF%E7%8A%B6%E5%8C%96%E5%90%88%E7%89%A9" title="环状化合物">环状化合物</a>母体</div></th></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/w/index.php?title=%E5%8D%95%E7%8E%AF%E5%8C%96%E5%90%88%E7%89%A9&action=edit&redlink=1" class="new" title="单环化合物（页面不存在）">單環</a></th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"></div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th scope="row" class="navbox-group" style="width:1%">三元环</th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E7%92%B0%E4%B8%99%E7%83%B7" title="環丙烷">环丙烷</a></li> <li><a href="/wiki/%E7%8E%AF%E6%B0%A7%E4%B9%99%E7%83%B7" title="环氧乙烷">环氧乙烷</a></li> <li><a href="/wiki/%E7%8E%AF%E7%A1%AB%E4%B9%99%E7%83%B7" title="环硫乙烷">环硫乙烷</a></li> <li><a href="/wiki/%E6%B0%AE%E4%B8%99%E7%8E%AF" title="氮丙环">氮丙环</a></li> <li><a href="/wiki/%E7%8E%AF%E4%B8%99%E7%83%AF" title="环丙烯">环丙烯</a></li> <li><a href="/wiki/%E7%8E%AF%E4%B8%99%E9%85%AE" title="环丙酮">环丙酮</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">四元環</th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E7%8E%AF%E4%B8%81%E7%83%B7" title="环丁烷">环丁烷</a></li> <li><a href="/wiki/%E5%90%96%E4%B8%81%E5%95%B6" title="吖丁啶">吖丁啶</a></li> <li><a href="/wiki/%E6%B0%A7%E6%9D%82%E7%8E%AF%E4%B8%81%E7%83%B7" title="氧杂环丁烷">噁丁环</a></li> <li><a href="/wiki/%E5%99%BB%E4%B8%81%E7%8E%AF" title="噻丁环">噻丁环</a></li> <li><a href="/wiki/%E4%BA%8C%E6%B0%A7%E6%9D%82%E7%8E%AF%E4%B8%81%E7%83%B7" title="二氧杂环丁烷">二氧杂环丁烷</a></li> <li><a href="/w/index.php?title=%E4%BA%8C%E7%A1%AB%E6%9D%82%E7%8E%AF%E4%B8%81%E7%83%B7&action=edit&redlink=1" class="new" title="二硫杂环丁烷（页面不存在）">二硫杂环丁烷</a></li> <li><a href="/wiki/%E4%BA%8C%E7%A1%AB%E6%9D%82%E7%8E%AF%E4%B8%81%E7%83%AF" title="二硫杂环丁烯">二硫杂环丁烯</a></li> <li><a href="/wiki/%E7%8E%AF%E4%B8%81%E7%83%AF" title="环丁烯">环丁烯</a></li> <li><a href="/wiki/%E7%8E%AF%E4%B8%81%E4%BA%8C%E7%83%AF" title="环丁二烯">环丁二烯</a></li> <li><a href="/wiki/%CE%92-%E5%86%85%E9%85%B0%E8%83%BA" title="Β-内酰胺">β-内酰胺</a></li> <li><a href="/wiki/%E6%A2%AF%E5%BD%A2%E7%83%B7" title="梯形烷">梯形烷</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">五元環</th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E7%8E%AF%E6%88%8A%E7%83%B7" title="环戊烷">环戊烷</a></li> <li><a href="/wiki/%E5%91%8B%E5%96%83" title="呋喃">呋喃</a></li> <li><a href="/wiki/%E5%90%A1%E5%92%AF" title="吡咯">吡咯</a></li> <li><a href="/wiki/%E5%99%BB%E5%90%A9" title="噻吩">噻吩</a></li> <li><a href="/wiki/%E5%90%96%E5%94%91" class="mw-redirect" title="吖唑">吖唑</a></li> <li><a href="/wiki/%E5%92%AA%E5%94%91" title="咪唑">咪唑</a></li> <li><a href="/wiki/%E5%90%A1%E5%94%91" title="吡唑">吡唑</a></li> <li><a href="/wiki/%E5%99%81%E5%94%91" title="噁唑">噁唑</a></li> <li><a href="/wiki/%E7%95%B0%E5%99%81%E5%94%91" title="異噁唑">异噁唑</a></li> <li><a href="/wiki/%E5%99%BB%E5%94%91" title="噻唑">噻唑</a></li> <li><a href="/wiki/%E5%BC%82%E5%99%BB%E5%94%91" title="异噻唑">异噻唑</a></li> <li><a href="/wiki/%E4%B8%89%E5%94%91" title="三唑">三唑</a></li> <li><a href="/wiki/%E5%9B%9B%E5%94%91" title="四唑">四唑</a></li> <li><a href="/wiki/%E4%BA%94%E5%94%91" title="五唑">五唑</a></li> <li><a href="/wiki/%E5%91%8B%E5%92%B1" title="呋咱">呋咱</a></li> <li><a href="/wiki/%E7%8E%AF%E6%88%8A%E7%83%AF" title="环戊烯">环戊烯</a></li> <li><a href="/wiki/%E7%8E%AF%E6%88%8A%E4%BA%8C%E7%83%AF" title="环戊二烯">环戊二烯</a></li> <li><a href="/wiki/%E7%8E%AF%E6%88%8A%E9%85%AE" title="环戊酮">环戊酮</a></li> <li><a href="/wiki/%E5%9B%9B%E6%B0%A2%E5%91%8B%E5%96%83" title="四氢呋喃">四氢呋喃</a></li> <li><a href="/wiki/%E5%9B%9B%E6%B0%A2%E5%99%BB%E5%90%A9" title="四氢噻吩">四氢噻吩</a></li> <li><a href="/wiki/%E5%90%A1%E5%92%AF%E7%83%B7" title="吡咯烷">吡咯烷</a></li> <li><a href="/wiki/%E5%90%A1%E5%92%AF%E5%95%89" title="吡咯啉">吡咯啉</a></li> <li><a href="/wiki/%E5%92%AA%E5%94%91%E5%95%89%E5%95%B6" title="咪唑啉啶">咪唑啉啶</a></li> <li><a href="/wiki/%E5%92%AA%E5%94%91%E5%95%89" title="咪唑啉">咪唑啉</a></li> <li><a href="/wiki/%E5%99%81%E5%94%91%E7%83%B7" title="噁唑烷">噁唑烷</a></li> <li><a href="/w/index.php?title=%E5%99%BB%E5%94%91%E7%83%B7&action=edit&redlink=1" class="new" title="噻唑烷（页面不存在）">噻唑烷</a></li> <li><a href="/w/index.php?title=%E4%BA%8C%E6%B0%A7%E4%BA%94%E7%8E%AF&action=edit&redlink=1" class="new" title="二氧五环（页面不存在）">二氧五环</a></li> <li><a href="/wiki/%E4%BA%8C%E7%A1%AB%E6%88%8A%E7%8E%AF" title="二硫戊环">二硫戊环</a></li> <li><a href="/w/index.php?title=%E5%A4%9A%E5%B9%B6%E4%BA%94%E5%85%83%E7%8E%AF&action=edit&redlink=1" class="new" title="多并五元环（页面不存在）">多并五元环</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">六元環</th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E7%8E%AF%E5%B7%B1%E7%83%B7" title="环己烷">环己烷</a></li> <li><a href="/wiki/%E8%8B%AF" title="苯">苯</a></li> <li><a href="/wiki/%E5%90%A1%E5%96%83" title="吡喃">吡喃</a></li> <li><a href="/wiki/%E5%90%A1%E5%95%B6" title="吡啶">吡啶</a></li> <li><a href="/wiki/%E4%BA%8C%E5%97%AA" title="二嗪">二嗪</a>（<a href="/wiki/%E5%90%A1%E5%97%AA" title="吡嗪">吡嗪</a></li> <li><a href="/wiki/%E5%93%92%E5%97%AA" title="哒嗪">哒嗪</a></li> <li><a href="/wiki/%E5%98%A7%E5%95%B6" title="嘧啶">嘧啶</a>）</li> <li><a href="/wiki/%E4%B8%89%E5%97%AA" title="三嗪">三嗪</a></li> <li><a href="/wiki/%E5%9B%9B%E5%97%AA" title="四嗪">四嗪</a></li> <li><a href="/wiki/%E4%BA%94%E5%97%AA" title="五嗪">五嗪</a></li> <li><a href="/wiki/%E5%85%AD%E5%97%AA" title="六嗪">六嗪</a></li> <li><a href="/wiki/%E5%90%A1%E5%96%83%E9%85%AE" title="吡喃酮">吡喃酮</a></li> <li><a href="/wiki/%E5%93%8C%E5%95%B6" title="哌啶">哌啶</a></li> <li><a href="/wiki/%E5%93%8C%E5%97%AA" title="哌嗪">哌嗪</a></li> <li><a href="/w/index.php?title=%E5%99%81%E5%97%AA&action=edit&redlink=1" class="new" title="噁嗪（页面不存在）">噁嗪</a></li> <li><a href="/wiki/%E5%99%BB%E5%97%AA" title="噻嗪">噻嗪</a></li> <li><a href="/w/index.php?title=%E4%BA%8C%E5%99%BB%E7%83%B7&action=edit&redlink=1" class="new" title="二噻烷（页面不存在）">二噻烷</a></li> <li><a href="/wiki/1,4-%E4%BA%8C%E5%99%81%E7%83%B7" title="1,4-二噁烷">二噁烷</a></li> <li><a href="/wiki/%E4%BA%8C%E5%99%81%E8%8B%B1" class="mw-redirect" title="二噁英">二噁英</a></li> <li><a href="/wiki/%F0%AB%AB%87%E5%99%BB%E7%83%B7" class="mw-redirect" title="𫫇噻烷">噁噻烷</a></li> <li><a href="/wiki/%E4%B8%89%E5%99%81%E7%83%B7" title="三噁烷">三噁烷</a></li> <li><a href="/w/index.php?title=%E5%99%BB%E4%BA%8C%E5%97%AA&action=edit&redlink=1" class="new" title="噻二嗪（页面不存在）">噻二嗪</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">七元环</th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E7%8E%AF%E5%BA%9A%E7%83%B7" title="环庚烷">环庚烷</a></li> <li><a href="/wiki/%E6%B0%AE%E6%9D%82%E4%93%AC" class="mw-redirect" title="氮杂䓬">氮杂䓬</a>（<a href="/w/index.php?title=%E5%90%96%E5%BA%9A%E5%9B%A0&action=edit&redlink=1" class="new" title="吖庚因（页面不存在）">吖庚因</a>）</li> <li><a href="/wiki/%E5%99%81%E5%BA%9A%E5%9B%A0" title="噁庚因">噁庚因</a></li> <li><a href="/w/index.php?title=%E7%A1%AB%E6%9D%82%E4%93%AC&action=edit&redlink=1" class="new" title="硫杂䓬（页面不存在）">硫杂䓬</a>（<a href="/w/index.php?title=%E5%99%BB%E5%BA%9A%E5%9B%A0&action=edit&redlink=1" class="new" title="噻庚因（页面不存在）">噻庚因</a>）</li> <li><a href="/wiki/%E7%8E%AF%E5%BA%9A%E4%B8%89%E7%83%AF" title="环庚三烯">环庚三烯</a></li> <li><a href="/w/index.php?title=%E4%BA%9A%E6%B0%A8%E5%9F%BA%E8%8A%AA&action=edit&redlink=1" class="new" title="亚氨基芪（页面不存在）">亚氨基芪</a></li> <li><a href="/w/index.php?title=%E5%85%A8%E6%B0%A2%E6%B0%AE%E6%9D%82%E4%93%AC&action=edit&redlink=1" class="new" title="全氢氮杂䓬（页面不存在）">全氢氮杂䓬</a></li> <li><a href="/wiki/%E5%B7%B1%E5%86%85%E9%85%B0%E8%83%BA" title="己内酰胺">己内酰胺</a></li> <li><a href="/w/index.php?title=%E4%BA%8C%E6%B0%AE%E6%9D%82%E4%93%AC&action=edit&redlink=1" class="new" title="二氮杂䓬（页面不存在）">二氮杂䓬</a></li> <li><a href="/w/index.php?title=%E5%99%81%E5%BA%9A%E7%8E%AF&action=edit&redlink=1" class="new" title="噁庚环（页面不存在）">噁庚环</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">八元环</th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E7%8E%AF%E8%BE%9B%E7%83%B7" title="环辛烷">环辛烷</a></li> <li><a href="/wiki/%E7%8E%AF%E8%BE%9B%E5%9B%9B%E7%83%AF" title="环辛四烯">环辛四烯</a></li></ul> </div></td></tr></tbody></table><div></div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/%E8%9E%BA%E7%8E%AF%E5%8C%96%E5%90%88%E7%89%A9" title="螺环化合物">螺环</a></th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E8%9E%BA%E6%88%8A%E4%BA%8C%E7%83%AF" title="螺戊二烯">螺戊二烯</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/%E5%A4%9A%E7%92%B0%E8%8A%B3%E9%A6%99%E7%83%B4" title="多環芳香烴">稠环</a></th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"></div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th scope="row" class="navbox-group" style="width:1%">六并四</th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E8%8B%AF%E5%B9%B6%E7%8E%AF%E4%B8%81%E7%83%AF" title="苯并环丁烯">苯并环丁烯</a></li> <li><a href="/wiki/%E8%8B%AF%E5%B9%B6%E7%8E%AF%E4%B8%81%E4%BA%8C%E7%83%AF" title="苯并环丁二烯">苯并环丁二烯</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">六并五</th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E8%8C%9A" title="茚">茚</a></li> <li><a href="/wiki/%E8%8A%B4" title="芴">芴</a></li> <li><a href="/wiki/%E8%8B%AF%E5%B9%B6%E5%91%8B%E5%96%83" title="苯并呋喃">苯并呋喃</a></li> <li><a href="/wiki/%E5%BC%82%E8%8B%AF%E5%B9%B6%E5%91%8B%E5%96%83" title="异苯并呋喃">异苯并呋喃</a></li> <li><a href="/w/index.php?title=%E8%8B%AF%E5%B9%B6%E5%91%8B%E5%92%B1&action=edit&redlink=1" class="new" title="苯并呋咱（页面不存在）">苯并呋咱</a></li> <li><a href="/wiki/%E8%8B%AF%E5%B9%B6%E5%99%BB%E5%90%A9" title="苯并噻吩">苯并[b]噻吩</a></li> <li><a href="/wiki/%E7%95%B0%E8%8B%AF%E5%B9%B6%E5%99%BB%E5%90%A9" title="異苯并噻吩">苯并[c]噻吩</a></li> <li><a href="/wiki/%E5%90%B2%E5%93%9A" title="吲哚">吲哚</a></li> <li><a href="/wiki/%E5%BC%82%E5%90%B2%E5%93%9A" title="异吲哚">异吲哚</a></li> <li><a href="/wiki/%E5%92%94%E5%94%91" title="咔唑">咔唑</a></li> <li><a href="/wiki/%E8%8B%AF%E5%B9%B6%E5%92%AA%E5%94%91" title="苯并咪唑">苯并咪唑</a></li> <li><a href="/wiki/%E5%90%B2%E5%94%91" title="吲唑">吲唑</a></li> <li><a href="/wiki/%E8%8B%AF%E4%B8%A6%E5%99%81%E5%94%91" title="苯並噁唑">苯并噁唑</a></li> <li><a href="/wiki/%E8%8B%AF%E5%B9%B6%E5%BC%82%F0%AB%AB%87%E5%94%91" title="苯并异𫫇唑">苯并异噁唑</a></li> <li><a href="/w/index.php?title=%E5%92%94%E5%95%89&action=edit&redlink=1" class="new" title="咔啉（页面不存在）">咔啉</a></li> <li><a href="/wiki/%E8%8B%AF%E5%B9%B6%E4%B8%89%E5%94%91" title="苯并三唑">苯并三唑</a></li> <li><a href="/wiki/%E5%98%8C%E5%91%A4" title="嘌呤">嘌呤</a></li> <li><a href="/wiki/%E5%B0%BF%E9%85%B8" title="尿酸">尿酸</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">六并六</th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E5%8D%81%E6%B0%A2%E5%8C%96%E8%90%98" title="十氢化萘">十氢化萘</a></li> <li><a href="/wiki/%E5%9B%9B%E6%B0%A2%E5%8C%96%E8%90%98" title="四氢化萘">四氢化萘</a></li> <li><a href="/wiki/%E8%90%98" title="萘">萘</a></li> <li><a href="/wiki/%E8%92%BD" title="蒽">蒽</a></li> <li><a href="/wiki/%E8%8A%98" title="芘">芘</a></li> <li><a href="/wiki/%E4%93%9B" title="䓛">䓛</a></li> <li><a href="/wiki/%E5%96%B9%E5%95%89" title="喹啉">喹啉</a></li> <li><a href="/wiki/%E5%BC%82%E5%96%B9%E5%95%89" title="异喹啉">异喹啉</a></li> <li><a href="/wiki/%E5%96%B9%E5%96%94%E5%95%89" title="喹喔啉">喹喔啉</a></li> <li><a href="/wiki/%E5%96%B9%E5%94%91%E5%95%89" title="喹唑啉">喹唑啉</a></li> <li><a href="/wiki/%E5%99%8C%E5%95%89" title="噌啉">噌啉</a></li> <li><a href="/wiki/%E9%85%9E%E5%97%AA" title="酞嗪">酞嗪</a></li> <li><a href="/w/index.php?title=%E8%8B%AF%E5%B9%B6%E4%BA%8C%E5%99%81%E7%83%B7&action=edit&redlink=1" class="new" title="苯并二噁烷（页面不存在）">苯并二噁烷</a></li> <li><a href="/wiki/%E5%90%96%E5%95%B6" title="吖啶">吖啶</a></li> <li><a href="/wiki/%E8%8F%B2%E5%95%B6" title="菲啶">菲啶</a></li> <li><a href="/wiki/%E5%90%A9%E5%97%AA" title="吩嗪">吩嗪</a></li> <li><a href="/wiki/%E5%90%A9%E5%99%81%E5%97%AA" title="吩噁嗪">吩噁嗪</a></li> <li><a href="/wiki/%E5%90%A9%E5%99%BB%E5%97%AA" title="吩噻嗪">吩噻嗪</a></li> <li><a href="/wiki/%E5%91%AB%E5%99%B8" title="呫噸">呫噸</a></li> <li><a href="/wiki/%E8%9D%B6%E5%95%B6" title="蝶啶">蝶啶</a></li> <li><a href="/wiki/%E5%96%B9%E5%94%91%E5%95%89%E9%85%AE" title="喹唑啉酮">喹唑啉酮</a></li> <li><a href="/wiki/%E9%A6%99%E8%B1%86%E7%B4%A0" title="香豆素">香豆素</a></li> <li><a href="/wiki/%E9%BB%84%E9%85%AE%E7%B1%BB%E5%8C%96%E5%90%88%E7%89%A9" title="黄酮类化合物">黄酮类</a></li> <li><a href="/wiki/%E7%95%B0%E9%BB%83%E9%85%AE" title="異黃酮">异黄酮</a></li> <li><a href="/wiki/%E8%8A%B1%E9%9D%92%E7%B4%A0" title="花青素">花色素</a></li> <li><a href="/wiki/%E5%91%AB%E5%90%A8%E9%85%AE" class="mw-redirect" title="呫吨酮">呫吨酮</a></li> <li><a href="/wiki/%E8%9D%B6%E5%91%A4" title="蝶呤">蝶呤</a></li> <li><a href="/w/index.php?title=%E5%92%AF%E5%97%AA&action=edit&redlink=1" class="new" title="咯嗪（页面不存在）">咯嗪</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">七并五</th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E8%96%81" title="薁">薁</a></li></ul> </div></td></tr></tbody></table><div></div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/%E6%A1%A5%E7%8E%AF%E5%8C%96%E5%90%88%E7%89%A9" title="桥环化合物">桥环</a></th><td class="navbox-list-with-group navbox-list navbox-even hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E9%99%8D%E5%86%B0%E7%89%87%E7%83%B7" title="降冰片烷">降冰片烷</a></li> <li><a href="/wiki/%E5%8F%8C%E7%8E%AF%E6%88%8A%E4%BA%8C%E7%83%AF" title="双环戊二烯">双环戊二烯</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">其他</th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E6%AD%A3%E5%9B%9B%E9%9D%A2%E4%BD%93%E7%83%B7" title="正四面体烷">正四面体烷</a></li> <li><a href="/wiki/%E7%AB%8B%E6%96%B9%E7%83%B7" title="立方烷">立方烷</a></li> <li><a href="/wiki/%E6%AD%A3%E5%8D%81%E4%BA%8C%E9%9D%A2%E4%BD%93%E7%83%B7" title="正十二面体烷">正十二面体烷</a></li> <li><a href="/wiki/%E5%AF%8C%E5%8B%92%E7%83%AF" title="富勒烯">富勒烯</a></li> <li><a href="/wiki/%E5%A4%9A%E7%8E%AF%E8%8A%B3%E7%83%83" class="mw-redirect" title="多环芳烃">多环芳烃</a></li> <li><a href="/wiki/%E6%9D%82%E7%8E%AF%E5%8C%96%E5%90%88%E7%89%A9" title="杂环化合物">杂环化合物</a></li> <li><a href="/wiki/%E5%8D%9F%E5%95%89" title="卟啉">卟啉</a></li> <li><a href="/wiki/%E8%BD%AE%E7%83%AF" title="轮烯">轮烯</a></li> <li><a class="mw-selflink selflink">冠醚</a></li> <li><a href="/wiki/%E7%A9%B4%E7%8A%B6%E9%85%8D%E4%BD%93" title="穴状配体">穴状配体</a></li> <li><a href="/wiki/%E9%87%91%E5%88%9A%E7%83%B7" title="金刚烷">金刚烷</a></li> <li><a href="/wiki/%E6%89%AD%E6%9B%B2%E7%83%B7" title="扭曲烷">扭曲烷</a></li> <li><a href="/wiki/CL-20" class="mw-redirect" title="CL-20">CL-20</a></li> <li><a href="/wiki/%E4%B9%8C%E6%B4%9B%E6%89%98%E5%93%81" title="乌洛托品">乌洛托品</a></li> <li><a href="/wiki/%E5%86%B0%E7%83%B7" title="冰烷">冰烷</a></li> <li><a href="/wiki/%E4%B8%89%E8%9D%B6%E7%83%AF" title="三蝶烯">三蝶烯</a></li></ul> </div></td></tr></tbody></table></div> <div class="navbox-styles"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r84265675"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r84261037"></div><div role="navigation" class="navbox" aria-labelledby="醚" style="padding:3px"><table class="nowraplinks mw-collapsible autocollapse navbox-inner" style="border-spacing:0;background:transparent;color:inherit"><tbody><tr><th scope="col" class="collapsible-title navbox-title" colspan="2"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r84265675"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r84244141"><div class="navbar plainlinks hlist navbar-mini"><ul><li class="nv-view"><a href="/wiki/Template:%E9%86%9A" title="Template:醚"><abbr title="查看该模板">查</abbr></a></li><li class="nv-talk"><a href="/wiki/Template_talk:%E9%86%9A" title="Template talk:醚"><abbr title="讨论该模板">论</abbr></a></li><li class="nv-edit"><a href="/wiki/Special:%E7%BC%96%E8%BE%91%E9%A1%B5%E9%9D%A2/Template:%E9%86%9A" title="Special:编辑页面/Template:醚"><abbr title="编辑该模板">编</abbr></a></li></ul></div><div id="醚" style="font-size:110%;margin:0 5em"><a href="/wiki/%E9%86%9A" title="醚">醚</a></div></th></tr><tr><th scope="row" class="navbox-group" style="width:1%">脂肪醚</th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"></div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/Category:%E4%BA%8C%E7%83%B7%E5%9F%BA%E9%86%9A" title="Category:二烷基醚">二烷基醚</a></th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0px"><div style="padding:0em 0.25em"></div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/Category:%E7%94%B2%E6%B0%A7%E5%9F%BA%E5%8C%96%E5%90%88%E7%89%A9" title="Category:甲氧基化合物">甲基烷基醚</a></th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E4%BA%8C%E7%94%B2%E9%86%9A" title="二甲醚">二甲醚</a></li> <li><a href="/wiki/%E7%94%B2%E4%B9%99%E9%86%9A" title="甲乙醚">甲乙醚</a></li> <li><a href="/wiki/%E7%94%B2%E4%B8%99%E9%86%9A" title="甲丙醚">甲丙醚</a></li> <li><a href="/wiki/%E7%94%B2%E5%BC%82%E4%B8%99%E9%86%9A" title="甲异丙醚">甲异丙醚</a></li> <li>甲丁醚 <ul><li><a href="/wiki/%E7%94%B2%E5%9F%BA%E5%8F%94%E4%B8%81%E5%9F%BA%E9%86%9A" title="甲基叔丁基醚">甲基叔丁基醚</a></li> <li><a href="/wiki/%E7%94%B2%E5%9F%BA%E5%BC%82%E4%B8%81%E5%9F%BA%E9%86%9A" title="甲基异丁基醚">甲基异丁基醚</a></li> <li><a href="/wiki/%E7%94%B2%E5%9F%BA%E4%BB%B2%E4%B8%81%E5%9F%BA%E9%86%9A" title="甲基仲丁基醚">甲基仲丁基醚</a></li> <li><a href="/wiki/1-%E7%94%B2%E6%B0%A7%E5%9F%BA%E4%B8%81%E7%83%B7" title="1-甲氧基丁烷">甲基正丁基醚</a></li></ul></li> <li>甲戊醚 <ul><li><a href="/wiki/%E7%94%B2%E5%9F%BA%E5%8F%94%E6%88%8A%E5%9F%BA%E9%86%9A" title="甲基叔戊基醚">甲基叔戊基醚</a></li> <li><span class="ilh-all" data-orig-title="甲基异戊基醚" data-lang-code="eo" data-lang-name="世界语" data-foreign-title="Metila izopentila etero"><span class="ilh-page"><a href="/w/index.php?title=%E7%94%B2%E5%9F%BA%E5%BC%82%E6%88%8A%E5%9F%BA%E9%86%9A&action=edit&redlink=1" class="new" title="甲基异戊基醚（页面不存在）">甲基异戊基醚</a></span><span class="noprint ilh-comment">（<span class="ilh-lang">世界语</span><span class="ilh-colon">：</span><span class="ilh-link"><a href="https://eo.wikipedia.org/wiki/Metila_izopentila_etero" class="extiw" title="eo:Metila izopentila etero"><span lang="eo" dir="auto">Metila izopentila etero</span></a></span>）</span></span></li> <li><span class="ilh-all" data-orig-title="1-甲氧基-2-甲基丁烷" data-lang-code="d" data-lang-name="維基數據" data-foreign-title="Q82100840"><span class="ilh-page"><a href="/w/index.php?title=1-%E7%94%B2%E6%B0%A7%E5%9F%BA-2-%E7%94%B2%E5%9F%BA%E4%B8%81%E7%83%B7&action=edit&redlink=1" class="new" title="1-甲氧基-2-甲基丁烷（页面不存在）">1-甲氧基-2-甲基丁烷</a></span><span class="noprint ilh-comment">（<span class="ilh-lang">維基數據所列</span><span class="ilh-colon">：</span><span class="ilh-link"><a href="https://www.wikidata.org/wiki/Q82100840" class="extiw" title="d:Q82100840"><span lang="d" dir="auto">Q82100840</span></a></span>）</span></span></li> <li><span class="ilh-all" data-orig-title="2-甲氧基-3-甲基丁烷" data-lang-code="d" data-lang-name="維基數據" data-foreign-title="Q82106473"><span class="ilh-page"><a href="/w/index.php?title=2-%E7%94%B2%E6%B0%A7%E5%9F%BA-3-%E7%94%B2%E5%9F%BA%E4%B8%81%E7%83%B7&action=edit&redlink=1" class="new" title="2-甲氧基-3-甲基丁烷（页面不存在）">2-甲氧基-3-甲基丁烷</a></span><span class="noprint ilh-comment">（<span class="ilh-lang">維基數據所列</span><span class="ilh-colon">：</span><span class="ilh-link"><a href="https://www.wikidata.org/wiki/Q82106473" class="extiw" title="d:Q82106473"><span lang="d" dir="auto">Q82106473</span></a></span>）</span></span></li> <li><span class="ilh-all" data-orig-title="甲基新戊基醚" data-lang-code="d" data-lang-name="維基數據" data-foreign-title="Q83015600"><span class="ilh-page"><a href="/w/index.php?title=%E7%94%B2%E5%9F%BA%E6%96%B0%E6%88%8A%E5%9F%BA%E9%86%9A&action=edit&redlink=1" class="new" title="甲基新戊基醚（页面不存在）">甲基新戊基醚</a></span><span class="noprint ilh-comment">（<span class="ilh-lang">維基數據所列</span><span class="ilh-colon">：</span><span class="ilh-link"><a href="https://www.wikidata.org/wiki/Q83015600" class="extiw" title="d:Q83015600"><span lang="d" dir="auto">Q83015600</span></a></span>）</span></span></li> <li><span class="ilh-all" data-orig-title="甲基正戊基醚" data-lang-code="eo" data-lang-name="世界语" data-foreign-title="Metila pentila etero"><span class="ilh-page"><a href="/w/index.php?title=%E7%94%B2%E5%9F%BA%E6%AD%A3%E6%88%8A%E5%9F%BA%E9%86%9A&action=edit&redlink=1" class="new" title="甲基正戊基醚（页面不存在）">甲基正戊基醚</a></span><span class="noprint ilh-comment">（<span class="ilh-lang">世界语</span><span class="ilh-colon">：</span><span class="ilh-link"><a href="https://eo.wikipedia.org/wiki/Metila_pentila_etero" class="extiw" title="eo:Metila pentila etero"><span lang="eo" dir="auto">Metila pentila etero</span></a></span>）</span></span></li> <li><span class="ilh-all" data-orig-title="2-甲氧基戊烷" data-lang-code="d" data-lang-name="維基數據" data-foreign-title="Q82100975"><span class="ilh-page"><a href="/w/index.php?title=2-%E7%94%B2%E6%B0%A7%E5%9F%BA%E6%88%8A%E7%83%B7&action=edit&redlink=1" class="new" title="2-甲氧基戊烷（页面不存在）">2-甲氧基戊烷</a></span><span class="noprint ilh-comment">（<span class="ilh-lang">維基數據所列</span><span class="ilh-colon">：</span><span class="ilh-link"><a href="https://www.wikidata.org/wiki/Q82100975" class="extiw" title="d:Q82100975"><span lang="d" dir="auto">Q82100975</span></a></span>）</span></span></li> <li><span class="ilh-all" data-orig-title="3-甲氧基戊烷" data-lang-code="d" data-lang-name="維基數據" data-foreign-title="Q83062641"><span class="ilh-page"><a href="/w/index.php?title=3-%E7%94%B2%E6%B0%A7%E5%9F%BA%E6%88%8A%E7%83%B7&action=edit&redlink=1" class="new" title="3-甲氧基戊烷（页面不存在）">3-甲氧基戊烷</a></span><span class="noprint ilh-comment">（<span class="ilh-lang">維基數據所列</span><span class="ilh-colon">：</span><span class="ilh-link"><a href="https://www.wikidata.org/wiki/Q83062641" class="extiw" title="d:Q83062641"><span lang="d" dir="auto">Q83062641</span></a></span>）</span></span></li></ul></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/Category:%E4%B9%99%E6%B0%A7%E5%9F%BA%E5%8C%96%E5%90%88%E7%89%A9" title="Category:乙氧基化合物">乙基烷基醚</a></th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E4%B9%99%E9%86%9A" title="乙醚">二乙醚</a></li> <li><a href="/wiki/1-%E4%B9%99%E6%B0%A7%E5%9F%BA%E4%B8%99%E7%83%B7" title="1-乙氧基丙烷">乙丙醚</a></li> <li><a href="/wiki/2-%E4%B9%99%E6%B0%A7%E5%9F%BA%E4%B8%99%E7%83%B7" title="2-乙氧基丙烷">乙异丙醚</a></li> <li>乙丁醚 <ul><li><span class="ilh-all" data-orig-title="乙基正丁基醚" data-lang-code="de" data-lang-name="德语" data-foreign-title="N-Butylethylether"><span class="ilh-page"><a href="/w/index.php?title=%E4%B9%99%E5%9F%BA%E6%AD%A3%E4%B8%81%E5%9F%BA%E9%86%9A&action=edit&redlink=1" class="new" title="乙基正丁基醚（页面不存在）">乙基正丁基醚</a></span><span class="noprint ilh-comment">（<span class="ilh-lang">德语</span><span class="ilh-colon">：</span><span class="ilh-link"><a href="https://de.wikipedia.org/wiki/N-Butylethylether" class="extiw" title="de:N-Butylethylether"><span lang="de" dir="auto">N-Butylethylether</span></a></span>）</span></span></li> <li><span class="ilh-all" data-orig-title="乙基异丁基醚" data-lang-code="de" data-lang-name="德语" data-foreign-title="Isobutylethylether"><span class="ilh-page"><a href="/w/index.php?title=%E4%B9%99%E5%9F%BA%E5%BC%82%E4%B8%81%E5%9F%BA%E9%86%9A&action=edit&redlink=1" class="new" title="乙基异丁基醚（页面不存在）">乙基异丁基醚</a></span><span class="noprint ilh-comment">（<span class="ilh-lang">德语</span><span class="ilh-colon">：</span><span class="ilh-link"><a href="https://de.wikipedia.org/wiki/Isobutylethylether" class="extiw" title="de:Isobutylethylether"><span lang="de" dir="auto">Isobutylethylether</span></a></span>）</span></span></li> <li><span class="ilh-all" data-orig-title="乙基仲丁基醚" data-lang-code="de" data-lang-name="德语" data-foreign-title="Sec-Butylethylether"><span class="ilh-page"><a href="/w/index.php?title=%E4%B9%99%E5%9F%BA%E4%BB%B2%E4%B8%81%E5%9F%BA%E9%86%9A&action=edit&redlink=1" class="new" title="乙基仲丁基醚（页面不存在）">乙基仲丁基醚</a></span><span class="noprint ilh-comment">（<span class="ilh-lang">德语</span><span class="ilh-colon">：</span><span class="ilh-link"><a href="https://de.wikipedia.org/wiki/Sec-Butylethylether" class="extiw" title="de:Sec-Butylethylether"><span lang="de" dir="auto">Sec-Butylethylether</span></a></span>）</span></span></li> <li><a href="/wiki/%E4%B9%99%E5%9F%BA%E5%8F%94%E4%B8%81%E5%9F%BA%E9%86%9A" title="乙基叔丁基醚">乙基叔丁基醚</a></li></ul></li> <li>乙戊醚 <ul><li><a href="/wiki/%E4%B9%99%E5%9F%BA%E5%8F%94%E6%88%8A%E5%9F%BA%E9%86%9A" title="乙基叔戊基醚">乙基叔戊基醚</a></li></ul></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/Category:%E7%83%B7%E6%B0%A7%E5%9F%BA%E5%8C%96%E5%90%88%E7%89%A9" title="Category:烷氧基化合物">其它</a></th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E4%BA%8C%E4%B8%99%E9%86%9A" title="二丙醚">二丙醚</a></li> <li><a href="/wiki/%E5%BC%82%E4%B8%99%E9%86%9A" title="异丙醚">二异丙醚</a></li> <li><span class="ilh-all" data-orig-title="丙基异丙基醚" data-lang-code="de" data-lang-name="德语" data-foreign-title="Isopropyl-n-propylether"><span class="ilh-page"><a href="/w/index.php?title=%E4%B8%99%E5%9F%BA%E5%BC%82%E4%B8%99%E5%9F%BA%E9%86%9A&action=edit&redlink=1" class="new" title="丙基异丙基醚（页面不存在）">丙基异丙基醚</a></span><span class="noprint ilh-comment">（<span class="ilh-lang">德语</span><span class="ilh-colon">：</span><span class="ilh-link"><a href="https://de.wikipedia.org/wiki/Isopropyl-n-propylether" class="extiw" title="de:Isopropyl-n-propylether"><span lang="de" dir="auto">Isopropyl-n-propylether</span></a></span>）</span></span></li> <li><a href="/wiki/%E4%BA%8C%E4%B8%81%E9%86%9A" title="二丁醚">二丁醚</a></li> <li><a href="/wiki/%E4%BA%8C%E5%8F%94%E4%B8%81%E9%86%9A" title="二叔丁醚">二叔丁醚</a></li></ul> </div></td></tr></tbody></table><div></div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">不饱和醚</th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/w/index.php?title=%E4%B9%99%E7%83%AF%E9%86%9A&action=edit&redlink=1" class="new" title="乙烯醚（页面不存在）">乙烯醚</a> <ul><li><a href="/wiki/%E4%BA%8C%E4%B9%99%E7%83%AF%E9%86%9A" title="二乙烯醚">二乙烯醚</a></li> <li><a href="/wiki/%E4%B9%99%E7%83%AF%E5%9F%BA%E4%B9%99%E9%86%9A" title="乙烯基乙醚">乙烯基乙醚</a></li></ul></li> <li><a href="/w/index.php?title=%E4%B8%99%E7%83%AF%E9%86%9A&action=edit&redlink=1" class="new" title="丙烯醚（页面不存在）">丙烯醚</a> <ul><li><a href="/wiki/2-%E7%94%B2%E6%B0%A7%E5%9F%BA%E4%B8%99%E7%83%AF" title="2-甲氧基丙烯">2-甲氧基丙烯</a></li></ul></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">多醇醚</th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/w/index.php?title=%E7%94%B2%E4%BA%8C%E9%86%87%E9%86%9A&action=edit&redlink=1" class="new" title="甲二醇醚（页面不存在）">甲二醇醚</a> <ul><li><a href="/wiki/%E7%94%B2%E6%B0%A7%E5%9F%BA%E7%94%B2%E9%86%87" title="甲氧基甲醇">甲氧基甲醇</a></li> <li><a href="/wiki/%E7%94%B2%E7%BC%A9%E9%86%9B" title="甲缩醛">甲缩醛</a></li> <li><a href="/wiki/%E7%94%B2%E9%86%9B%E7%BC%A9%E4%BA%8C%E4%B9%99%E9%86%87" title="甲醛缩二乙醇">甲醛缩二乙醇</a></li></ul></li> <li><a href="/wiki/%E4%B9%99%E4%BA%8C%E9%86%87%E9%86%9A" title="乙二醇醚">乙二醇醚</a> <ul><li><a href="/wiki/%E4%B9%99%E4%BA%8C%E9%86%87%E5%8D%95%E7%94%B2%E9%86%9A" title="乙二醇单甲醚">乙二醇单甲醚</a></li> <li><a href="/wiki/%E4%B9%99%E4%BA%8C%E9%86%87%E4%BA%8C%E7%94%B2%E9%86%9A" title="乙二醇二甲醚">乙二醇二甲醚</a></li> <li><a href="/wiki/%E4%B9%99%E4%BA%8C%E9%86%87%E5%8D%95%E4%B9%99%E9%86%9A" title="乙二醇单乙醚">乙二醇单乙醚</a></li> <li><a href="/wiki/%E4%B9%99%E4%BA%8C%E9%86%87%E5%8D%95%E4%B8%81%E9%86%9A" title="乙二醇单丁醚">乙二醇单丁醚</a></li> <li><a href="/wiki/%E4%B9%99%E4%BA%8C%E9%86%87%E5%8D%95%E5%8F%94%E4%B8%81%E9%86%9A" title="乙二醇单叔丁醚">乙二醇单叔丁醚</a></li> <li><a href="/wiki/2-%E5%B7%B1%E6%B0%A7%E5%9F%BA%E4%B9%99%E9%86%87" title="2-己氧基乙醇">2-己氧基乙醇</a></li> <li><a href="/wiki/%E4%BA%8C%E4%B9%99%E4%BA%8C%E9%86%87%E4%BA%8C%E7%94%B2%E9%86%9A" title="二乙二醇二甲醚">二乙二醇二甲醚</a></li></ul></li> <li><a href="/w/index.php?title=%E4%B8%99%E4%BA%8C%E9%86%87%E9%86%9A&action=edit&redlink=1" class="new" title="丙二醇醚（页面不存在）">丙二醇醚</a> <ul><li><a href="/wiki/%E4%B8%99%E4%BA%8C%E9%86%87%E5%8D%95%E7%94%B2%E9%86%9A" title="丙二醇单甲醚">丙二醇单甲醚</a></li></ul></li> <li><a href="/w/index.php?title=%E7%94%98%E6%B2%B9%E9%86%9A&action=edit&redlink=1" class="new" title="甘油醚（页面不存在）">甘油醚</a></li></ul> </div></td></tr></tbody></table><div></div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/Category:%E8%8A%B3%E9%A6%99%E9%86%9A" title="Category:芳香醚">芳香醚</a></th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"></div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th scope="row" class="navbox-group" style="width:1%">单芳基醚</th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E8%8B%AF%E7%94%B2%E9%86%9A" title="苯甲醚">苯甲醚</a></li> <li><a href="/wiki/%E8%8B%AF%E4%B9%99%E9%86%9A" title="苯乙醚">苯乙醚</a></li> <li><a href="/wiki/%E7%94%B2%E5%9F%BA%E8%8B%AF%E7%94%B2%E9%86%9A" title="甲基苯甲醚">甲基苯甲醚</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/Category:%E4%BA%8C%E8%8A%B3%E5%9F%BA%E9%86%9A" title="Category:二芳基醚">二芳基醚</a></th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E4%BA%8C%E8%8B%AF%E9%86%9A" title="二苯醚">二苯醚</a></li></ul> </div></td></tr></tbody></table><div></div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">雜環醚</th><td class="navbox-list-with-group navbox-list navbox-even hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E7%8E%AF%E6%B0%A7%E4%B9%99%E7%83%B7" title="环氧乙烷">環氧乙烷</a></li> <li><a href="/wiki/%E5%9B%9B%E6%B0%A2%E5%91%8B%E5%96%83" title="四氢呋喃">四氫呋喃</a></li> <li><a href="/wiki/%E5%9B%9B%E6%B0%A2%E5%90%A1%E5%96%83" title="四氢吡喃">四氫吡喃</a></li> <li><a href="/wiki/1,4-%E4%BA%8C%E5%99%81%E7%83%B7" title="1,4-二噁烷">二噁烷</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a class="mw-selflink selflink">冠醚</a></th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/21-%E5%86%A0-7" title="21-冠-7">21-冠-7</a></li> <li><a href="/wiki/18-%E5%86%A0-6" title="18-冠-6">18-冠-6</a></li> <li><a href="/wiki/%E4%BA%8C%E8%8B%AF%E5%B9%B6-18-%E5%86%A0-6" title="二苯并-18-冠-6">二苯并-18-冠-6</a></li> <li><a href="/wiki/15-%E5%86%A0-5" title="15-冠-5">15-冠-5</a></li> <li><a href="/wiki/12-%E5%86%A0-4" title="12-冠-4">12-冠-4</a></li> <li><a href="/wiki/9-%E5%86%A0-3" title="9-冠-3">9-冠-3</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/%E7%A9%B4%E7%8A%B6%E9%85%8D%E4%BD%93" title="穴状配体">穴醚</a></th><td class="navbox-list-with-group navbox-list navbox-even hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%EF%BC%BB2.2.2%EF%BC%BD%E7%A9%B4%E9%86%9A" title="［2.2.2］穴醚">[2.2.2]-穴醚</a></li></ul> </div></td></tr></tbody></table></div> <div class="navbox-styles"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r84265675"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r84261037"></div><div role="navigation" class="navbox authority-control" aria-label="Navbox" style="padding:3px"><table class="nowraplinks hlist navbox-inner" style="border-spacing:0;background:transparent;color:inherit"><tbody><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/Help:%E8%A7%84%E8%8C%83%E6%8E%A7%E5%88%B6" title="Help:规范控制">规范控制数据库</a>：各地 <span class="mw-valign-text-top noprint" typeof="mw:File/Frameless"><a href="https://www.wikidata.org/wiki/Q410125#identifiers" title="編輯維基數據鏈接"><img alt="編輯維基數據鏈接" 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