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</div> </div> <div class="vector-sticky-pinned-container"> <nav id="mw-panel-toc" aria-label="目录" data-event-name="ui.sidebar-toc" class="mw-table-of-contents-container vector-toc-landmark"> <div id="vector-toc-pinned-container" class="vector-pinned-container"> <div id="vector-toc" class="vector-toc vector-pinnable-element"> <div class="vector-pinnable-header vector-toc-pinnable-header vector-pinnable-header-pinned" data-feature-name="toc-pinned" data-pinnable-element-id="vector-toc" > <h2 class="vector-pinnable-header-label">目录</h2> <button class="vector-pinnable-header-toggle-button vector-pinnable-header-pin-button" data-event-name="pinnable-header.vector-toc.pin">移至侧栏</button> <button class="vector-pinnable-header-toggle-button vector-pinnable-header-unpin-button" data-event-name="pinnable-header.vector-toc.unpin">隐藏</button> </div> <ul class="vector-toc-contents" id="mw-panel-toc-list"> <li id="toc-mw-content-text" class="vector-toc-list-item vector-toc-level-1"> <a href="#" class="vector-toc-link"> <div class="vector-toc-text">序言</div> </a> </li> <li id="toc-制备" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#制备"> <div class="vector-toc-text"> <span class="vector-toc-numb">1</span> <span>制备</span> </div> </a> <ul id="toc-制备-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-结构" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#结构"> <div class="vector-toc-text"> <span class="vector-toc-numb">2</span> <span>结构</span> </div> </a> <ul id="toc-结构-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-应用" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#应用"> <div class="vector-toc-text"> <span class="vector-toc-numb">3</span> <span>应用</span> </div> </a> <button aria-controls="toc-应用-sublist" class="cdx-button cdx-button--weight-quiet cdx-button--icon-only vector-toc-toggle"> <span class="vector-icon mw-ui-icon-wikimedia-expand"></span> <span>开关应用子章节</span> </button> <ul id="toc-应用-sublist" class="vector-toc-list"> <li id="toc-蓝图与摄影" class="vector-toc-list-item vector-toc-level-2"> <a class="vector-toc-link" href="#蓝图与摄影"> <div class="vector-toc-text"> <span class="vector-toc-numb">3.1</span> <span>蓝图与摄影</span> </div> </a> <ul id="toc-蓝图与摄影-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-有机合成试剂" class="vector-toc-list-item vector-toc-level-2"> <a class="vector-toc-link" href="#有机合成试剂"> <div class="vector-toc-text"> <span class="vector-toc-numb">3.2</span> <span>有机合成试剂</span> </div> </a> <ul id="toc-有机合成试剂-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-其他" class="vector-toc-list-item vector-toc-level-2"> <a class="vector-toc-link" href="#其他"> <div class="vector-toc-text"> <span class="vector-toc-numb">3.3</span> <span>其他</span> </div> </a> <ul id="toc-其他-sublist" class="vector-toc-list"> </ul> </li> </ul> </li> <li id="toc-普鲁士蓝" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#普鲁士蓝"> <div class="vector-toc-text"> <span class="vector-toc-numb">4</span> <span>普鲁士蓝</span> </div> </a> <ul id="toc-普鲁士蓝-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-安全" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#安全"> <div class="vector-toc-text"> <span class="vector-toc-numb">5</span> <span>安全</span> </div> </a> <ul id="toc-安全-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-參見" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#參見"> <div class="vector-toc-text"> <span class="vector-toc-numb">6</span> <span>參見</span> </div> </a> <ul id="toc-參見-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-参考资料" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#参考资料"> <div class="vector-toc-text"> <span class="vector-toc-numb">7</span> <span>参考资料</span> </div> </a> <ul id="toc-参考资料-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-外部链接" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#外部链接"> <div class="vector-toc-text"> <span class="vector-toc-numb">8</span> <span>外部链接</span> </div> </a> <ul id="toc-外部链接-sublist" class="vector-toc-list"> </ul> </li> </ul> </div> </div> </nav> </div> </div> <div class="mw-content-container"> <main id="content" class="mw-body"> <header class="mw-body-header vector-page-titlebar"> <nav aria-label="目录" class="vector-toc-landmark"> <div id="vector-page-titlebar-toc" class="vector-dropdown vector-page-titlebar-toc vector-button-flush-left" > <input type="checkbox" id="vector-page-titlebar-toc-checkbox" role="button" aria-haspopup="true" data-event-name="ui.dropdown-vector-page-titlebar-toc" class="vector-dropdown-checkbox " aria-label="开关目录" > <label id="vector-page-titlebar-toc-label" for="vector-page-titlebar-toc-checkbox" class="vector-dropdown-label cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--icon-only " aria-hidden="true" ><span class="vector-icon mw-ui-icon-listBullet mw-ui-icon-wikimedia-listBullet"></span> <span class="vector-dropdown-label-text">开关目录</span> </label> <div class="vector-dropdown-content"> <div id="vector-page-titlebar-toc-unpinned-container" class="vector-unpinned-container"> </div> </div> </div> </nav> <h1 id="firstHeading" class="firstHeading mw-first-heading"><span class="mw-page-title-main">铁氰化钾</span></h1> <div id="p-lang-btn" class="vector-dropdown mw-portlet mw-portlet-lang" > <input type="checkbox" id="p-lang-btn-checkbox" role="button" aria-haspopup="true" data-event-name="ui.dropdown-p-lang-btn" class="vector-dropdown-checkbox mw-interlanguage-selector" aria-label="前往另一种语言写成的文章。35种语言可用" > <label id="p-lang-btn-label" for="p-lang-btn-checkbox" class="vector-dropdown-label cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--action-progressive mw-portlet-lang-heading-35" aria-hidden="true" ><span class="vector-icon mw-ui-icon-language-progressive mw-ui-icon-wikimedia-language-progressive"></span> <span class="vector-dropdown-label-text">35种语言</span> </label> <div class="vector-dropdown-content"> <div class="vector-menu-content"> <ul class="vector-menu-content-list"> <li class="interlanguage-link interwiki-af mw-list-item"><a href="https://af.wikipedia.org/wiki/Kaliumheksasianoferraat(III)" title="Kaliumheksasianoferraat(III) – 南非荷兰语" lang="af" hreflang="af" data-title="Kaliumheksasianoferraat(III)" data-language-autonym="Afrikaans" data-language-local-name="南非荷兰语" class="interlanguage-link-target"><span>Afrikaans</span></a></li><li class="interlanguage-link interwiki-ar mw-list-item"><a href="https://ar.wikipedia.org/wiki/%D9%81%D8%B1%D9%8A%D8%B3%D9%8A%D8%A7%D9%86%D9%8A%D8%AF_%D8%A7%D9%84%D8%A8%D9%88%D8%AA%D8%A7%D8%B3%D9%8A%D9%88%D9%85" title="فريسيانيد البوتاسيوم – 阿拉伯语" lang="ar" hreflang="ar" data-title="فريسيانيد البوتاسيوم" data-language-autonym="العربية" data-language-local-name="阿拉伯语" class="interlanguage-link-target"><span>العربية</span></a></li><li class="interlanguage-link interwiki-azb mw-list-item"><a href="https://azb.wikipedia.org/wiki/%D9%BE%D9%88%D8%AA%D8%A7%D8%B3%DB%8C%D9%88%D9%85_%D9%81%D8%B1%DB%8C%E2%80%8C%D8%B3%DB%8C%D8%A7%D9%86%DB%8C%D8%AF" title="پوتاسیوم فری‌سیانید – South Azerbaijani" lang="azb" hreflang="azb" data-title="پوتاسیوم فری‌سیانید" data-language-autonym="تۆرکجه" data-language-local-name="South Azerbaijani" class="interlanguage-link-target"><span>تۆرکجه</span></a></li><li class="interlanguage-link interwiki-bn mw-list-item"><a href="https://bn.wikipedia.org/wiki/%E0%A6%AA%E0%A6%9F%E0%A6%BE%E0%A6%B8%E0%A6%BF%E0%A6%AF%E0%A6%BC%E0%A6%BE%E0%A6%AE_%E0%A6%AB%E0%A7%87%E0%A6%B0%E0%A6%BF%E0%A6%B8%E0%A6%BE%E0%A6%AF%E0%A6%BC%E0%A6%BE%E0%A6%A8%E0%A6%BE%E0%A6%87%E0%A6%A1" title="পটাসিয়াম ফেরিসায়ানাইড – 孟加拉语" lang="bn" hreflang="bn" data-title="পটাসিয়াম ফেরিসায়ানাইড" data-language-autonym="বাংলা" data-language-local-name="孟加拉语" class="interlanguage-link-target"><span>বাংলা</span></a></li><li class="interlanguage-link interwiki-ca mw-list-item"><a href="https://ca.wikipedia.org/wiki/Ferricianur_de_potassi" title="Ferricianur de potassi – 加泰罗尼亚语" lang="ca" hreflang="ca" data-title="Ferricianur de potassi" data-language-autonym="Català" data-language-local-name="加泰罗尼亚语" class="interlanguage-link-target"><span>Català</span></a></li><li class="interlanguage-link interwiki-cs mw-list-item"><a href="https://cs.wikipedia.org/wiki/Hexakyanido%C5%BEelezitan_draseln%C3%BD" title="Hexakyanidoželezitan draselný – 捷克语" lang="cs" hreflang="cs" data-title="Hexakyanidoželezitan draselný" data-language-autonym="Čeština" data-language-local-name="捷克语" class="interlanguage-link-target"><span>Čeština</span></a></li><li class="interlanguage-link interwiki-cv mw-list-item"><a href="https://cv.wikipedia.org/wiki/%D0%9A%D0%B0%D0%BB%D0%B8%D0%B9_%D0%B3%D0%B5%D0%BA%D1%81%D0%B0%D1%86%D0%B8%D0%B0%D0%BD%D0%BE%D1%84%D0%B5%D1%80%D1%80%D0%B0%D1%87%C4%95(III)" title="Калий гексацианоферрачĕ(III) – 楚瓦什语" lang="cv" hreflang="cv" data-title="Калий гексацианоферрачĕ(III)" data-language-autonym="Чӑвашла" data-language-local-name="楚瓦什语" class="interlanguage-link-target"><span>Чӑвашла</span></a></li><li class="interlanguage-link interwiki-de mw-list-item"><a href="https://de.wikipedia.org/wiki/Kaliumhexacyanidoferrat(III)" title="Kaliumhexacyanidoferrat(III) – 德语" lang="de" hreflang="de" data-title="Kaliumhexacyanidoferrat(III)" data-language-autonym="Deutsch" data-language-local-name="德语" class="interlanguage-link-target"><span>Deutsch</span></a></li><li class="interlanguage-link interwiki-el mw-list-item"><a href="https://el.wikipedia.org/wiki/%CE%A3%CE%B9%CE%B4%CE%B7%CF%81%CE%B9%CE%BA%CF%85%CE%B1%CE%BD%CE%B9%CE%BF%CF%8D%CF%87%CE%BF_%CE%BA%CE%AC%CE%BB%CE%B9%CE%BF" title="Σιδηρικυανιούχο κάλιο – 希腊语" lang="el" hreflang="el" data-title="Σιδηρικυανιούχο κάλιο" data-language-autonym="Ελληνικά" data-language-local-name="希腊语" class="interlanguage-link-target"><span>Ελληνικά</span></a></li><li class="interlanguage-link interwiki-en mw-list-item"><a href="https://en.wikipedia.org/wiki/Potassium_ferricyanide" title="Potassium ferricyanide – 英语" lang="en" hreflang="en" data-title="Potassium ferricyanide" data-language-autonym="English" data-language-local-name="英语" class="interlanguage-link-target"><span>English</span></a></li><li class="interlanguage-link interwiki-eo mw-list-item"><a href="https://eo.wikipedia.org/wiki/Kalia_fericianido" title="Kalia fericianido – 世界语" lang="eo" hreflang="eo" data-title="Kalia fericianido" data-language-autonym="Esperanto" data-language-local-name="世界语" class="interlanguage-link-target"><span>Esperanto</span></a></li><li class="interlanguage-link interwiki-es mw-list-item"><a href="https://es.wikipedia.org/wiki/Ferricianuro_de_potasio" title="Ferricianuro de potasio – 西班牙语" lang="es" hreflang="es" data-title="Ferricianuro de potasio" data-language-autonym="Español" data-language-local-name="西班牙语" class="interlanguage-link-target"><span>Español</span></a></li><li class="interlanguage-link interwiki-fa mw-list-item"><a href="https://fa.wikipedia.org/wiki/%D9%BE%D8%AA%D8%A7%D8%B3%DB%8C%D9%85_%D9%81%D8%B1%DB%8C%E2%80%8C%D8%B3%DB%8C%D8%A7%D9%86%DB%8C%D8%AF" title="پتاسیم فری‌سیانید – 波斯语" lang="fa" hreflang="fa" data-title="پتاسیم فری‌سیانید" data-language-autonym="فارسی" data-language-local-name="波斯语" class="interlanguage-link-target"><span>فارسی</span></a></li><li class="interlanguage-link interwiki-fi mw-list-item"><a href="https://fi.wikipedia.org/wiki/Kaliumferrisyanidi" title="Kaliumferrisyanidi – 芬兰语" lang="fi" hreflang="fi" data-title="Kaliumferrisyanidi" data-language-autonym="Suomi" data-language-local-name="芬兰语" class="interlanguage-link-target"><span>Suomi</span></a></li><li class="interlanguage-link interwiki-fr mw-list-item"><a href="https://fr.wikipedia.org/wiki/Ferricyanure_de_potassium" title="Ferricyanure de potassium – 法语" lang="fr" hreflang="fr" data-title="Ferricyanure de potassium" data-language-autonym="Français" data-language-local-name="法语" class="interlanguage-link-target"><span>Français</span></a></li><li class="interlanguage-link interwiki-hu mw-list-item"><a href="https://hu.wikipedia.org/wiki/K%C3%A1lium-ferricianid" title="Kálium-ferricianid – 匈牙利语" lang="hu" hreflang="hu" data-title="Kálium-ferricianid" data-language-autonym="Magyar" data-language-local-name="匈牙利语" class="interlanguage-link-target"><span>Magyar</span></a></li><li class="interlanguage-link interwiki-id mw-list-item"><a href="https://id.wikipedia.org/wiki/Kalium_ferisianida" title="Kalium ferisianida – 印度尼西亚语" lang="id" hreflang="id" data-title="Kalium ferisianida" data-language-autonym="Bahasa Indonesia" data-language-local-name="印度尼西亚语" class="interlanguage-link-target"><span>Bahasa Indonesia</span></a></li><li class="interlanguage-link interwiki-it mw-list-item"><a href="https://it.wikipedia.org/wiki/Ferricianuro_di_potassio" title="Ferricianuro di potassio – 意大利语" lang="it" hreflang="it" data-title="Ferricianuro di potassio" data-language-autonym="Italiano" data-language-local-name="意大利语" class="interlanguage-link-target"><span>Italiano</span></a></li><li class="interlanguage-link interwiki-ja mw-list-item"><a href="https://ja.wikipedia.org/wiki/%E3%83%95%E3%82%A7%E3%83%AA%E3%82%B7%E3%82%A2%E3%83%B3%E5%8C%96%E3%82%AB%E3%83%AA%E3%82%A6%E3%83%A0" title="フェリシアン化カリウム – 日语" lang="ja" hreflang="ja" data-title="フェリシアン化カリウム" data-language-autonym="日本語" data-language-local-name="日语" class="interlanguage-link-target"><span>日本語</span></a></li><li class="interlanguage-link interwiki-ko mw-list-item"><a href="https://ko.wikipedia.org/wiki/%ED%8E%98%EB%A6%AC%EC%8B%9C%EC%95%88%ED%99%94_%EC%B9%BC%EB%A5%A8" title="페리시안화 칼륨 – 韩语" lang="ko" hreflang="ko" data-title="페리시안화 칼륨" data-language-autonym="한국어" data-language-local-name="韩语" class="interlanguage-link-target"><span>한국어</span></a></li><li class="interlanguage-link interwiki-lv mw-list-item"><a href="https://lv.wikipedia.org/wiki/K%C4%81lija_heksacianofer%C4%81ts(III)" title="Kālija heksacianoferāts(III) – 拉脱维亚语" lang="lv" hreflang="lv" data-title="Kālija heksacianoferāts(III)" data-language-autonym="Latviešu" data-language-local-name="拉脱维亚语" class="interlanguage-link-target"><span>Latviešu</span></a></li><li class="interlanguage-link interwiki-mk mw-list-item"><a href="https://mk.wikipedia.org/wiki/%D0%9A%D0%B0%D0%BB%D0%B8%D1%83%D0%BC_%D1%84%D0%B5%D1%80%D0%B8%D1%86%D0%B8%D1%98%D0%B0%D0%BD%D0%B8%D0%B4" title="Калиум ферицијанид – 马其顿语" lang="mk" hreflang="mk" data-title="Калиум ферицијанид" data-language-autonym="Македонски" data-language-local-name="马其顿语" class="interlanguage-link-target"><span>Македонски</span></a></li><li class="interlanguage-link interwiki-ms mw-list-item"><a href="https://ms.wikipedia.org/wiki/Kalium_ferisianida" title="Kalium ferisianida – 马来语" lang="ms" hreflang="ms" data-title="Kalium ferisianida" data-language-autonym="Bahasa Melayu" data-language-local-name="马来语" class="interlanguage-link-target"><span>Bahasa Melayu</span></a></li><li class="interlanguage-link interwiki-nl mw-list-item"><a href="https://nl.wikipedia.org/wiki/Kaliumhexacyanoferraat(III)" title="Kaliumhexacyanoferraat(III) – 荷兰语" lang="nl" hreflang="nl" data-title="Kaliumhexacyanoferraat(III)" data-language-autonym="Nederlands" data-language-local-name="荷兰语" class="interlanguage-link-target"><span>Nederlands</span></a></li><li class="interlanguage-link interwiki-pl mw-list-item"><a href="https://pl.wikipedia.org/wiki/%C5%BBelazicyjanek_potasu" title="Żelazicyjanek potasu – 波兰语" lang="pl" hreflang="pl" data-title="Żelazicyjanek potasu" data-language-autonym="Polski" data-language-local-name="波兰语" class="interlanguage-link-target"><span>Polski</span></a></li><li class="interlanguage-link interwiki-pt mw-list-item"><a href="https://pt.wikipedia.org/wiki/Ferricianeto_de_pot%C3%A1ssio" title="Ferricianeto de potássio – 葡萄牙语" lang="pt" hreflang="pt" data-title="Ferricianeto de potássio" data-language-autonym="Português" data-language-local-name="葡萄牙语" class="interlanguage-link-target"><span>Português</span></a></li><li class="interlanguage-link interwiki-ro mw-list-item"><a href="https://ro.wikipedia.org/wiki/Fericianur%C4%83_de_potasiu" title="Fericianură de potasiu – 罗马尼亚语" lang="ro" hreflang="ro" data-title="Fericianură de potasiu" data-language-autonym="Română" data-language-local-name="罗马尼亚语" class="interlanguage-link-target"><span>Română</span></a></li><li class="interlanguage-link interwiki-ru mw-list-item"><a href="https://ru.wikipedia.org/wiki/%D0%93%D0%B5%D0%BA%D1%81%D0%B0%D1%86%D0%B8%D0%B0%D0%BD%D0%BE%D1%84%D0%B5%D1%80%D1%80%D0%B0%D1%82(III)_%D0%BA%D0%B0%D0%BB%D0%B8%D1%8F" title="Гексацианоферрат(III) калия – 俄语" lang="ru" hreflang="ru" data-title="Гексацианоферрат(III) калия" data-language-autonym="Русский" data-language-local-name="俄语" class="interlanguage-link-target"><span>Русский</span></a></li><li class="interlanguage-link interwiki-sh mw-list-item"><a href="https://sh.wikipedia.org/wiki/Kalijum_fericijanid" title="Kalijum fericijanid – 塞尔维亚-克罗地亚语" lang="sh" hreflang="sh" data-title="Kalijum fericijanid" data-language-autonym="Srpskohrvatski / српскохрватски" data-language-local-name="塞尔维亚-克罗地亚语" class="interlanguage-link-target"><span>Srpskohrvatski / српскохрватски</span></a></li><li class="interlanguage-link interwiki-sk mw-list-item"><a href="https://sk.wikipedia.org/wiki/Hexakyano%C5%BEelezitan_draseln%C3%BD" title="Hexakyanoželezitan draselný – 斯洛伐克语" lang="sk" hreflang="sk" data-title="Hexakyanoželezitan draselný" data-language-autonym="Slovenčina" data-language-local-name="斯洛伐克语" class="interlanguage-link-target"><span>Slovenčina</span></a></li><li class="interlanguage-link interwiki-sr mw-list-item"><a href="https://sr.wikipedia.org/wiki/Kalijum_fericijanid" title="Kalijum fericijanid – 塞尔维亚语" lang="sr" hreflang="sr" data-title="Kalijum fericijanid" data-language-autonym="Српски / srpski" data-language-local-name="塞尔维亚语" class="interlanguage-link-target"><span>Српски / srpski</span></a></li><li class="interlanguage-link interwiki-sv mw-list-item"><a href="https://sv.wikipedia.org/wiki/Kaliumferricyanid" title="Kaliumferricyanid – 瑞典语" lang="sv" hreflang="sv" data-title="Kaliumferricyanid" data-language-autonym="Svenska" data-language-local-name="瑞典语" class="interlanguage-link-target"><span>Svenska</span></a></li><li class="interlanguage-link interwiki-tr mw-list-item"><a href="https://tr.wikipedia.org/wiki/Potasyum_ferrisiyan%C3%BCr" title="Potasyum ferrisiyanür – 土耳其语" lang="tr" hreflang="tr" data-title="Potasyum ferrisiyanür" data-language-autonym="Türkçe" data-language-local-name="土耳其语" class="interlanguage-link-target"><span>Türkçe</span></a></li><li class="interlanguage-link interwiki-uk mw-list-item"><a href="https://uk.wikipedia.org/wiki/%D0%93%D0%B5%D0%BA%D1%81%D0%B0%D1%86%D1%96%D0%B0%D0%BD%D0%BE%D1%84%D0%B5%D1%80%D0%B0%D1%82(III)_%D0%BA%D0%B0%D0%BB%D1%96%D1%8E" title="Гексаціаноферат(III) калію – 乌克兰语" lang="uk" hreflang="uk" data-title="Гексаціаноферат(III) калію" data-language-autonym="Українська" data-language-local-name="乌克兰语" class="interlanguage-link-target"><span>Українська</span></a></li><li class="interlanguage-link interwiki-vi mw-list-item"><a href="https://vi.wikipedia.org/wiki/Kali_ferricyanide" title="Kali ferricyanide – 越南语" lang="vi" hreflang="vi" data-title="Kali ferricyanide" data-language-autonym="Tiếng Việt" 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href="https://www.wikidata.org/wiki/Special:EntityPage/Q408810" title="链接到连接的数据仓库项目[g]" accesskey="g"><span>维基数据项目</span></a></li> </ul> </div> </div> </div> </div> </div> </div> </nav> </div> </div> </div> <div class="vector-column-end"> <div class="vector-sticky-pinned-container"> <nav class="vector-page-tools-landmark" aria-label="页面工具"> <div id="vector-page-tools-pinned-container" class="vector-pinned-container"> </div> </nav> <nav class="vector-appearance-landmark" aria-label="外观"> <div id="vector-appearance-pinned-container" class="vector-pinned-container"> <div id="vector-appearance" class="vector-appearance vector-pinnable-element"> <div class="vector-pinnable-header vector-appearance-pinnable-header vector-pinnable-header-pinned" data-feature-name="appearance-pinned" data-pinnable-element-id="vector-appearance" data-pinned-container-id="vector-appearance-pinned-container" data-unpinned-container-id="vector-appearance-unpinned-container" > <div class="vector-pinnable-header-label">外观</div> <button class="vector-pinnable-header-toggle-button vector-pinnable-header-pin-button" data-event-name="pinnable-header.vector-appearance.pin">移至侧栏</button> <button class="vector-pinnable-header-toggle-button vector-pinnable-header-unpin-button" data-event-name="pinnable-header.vector-appearance.unpin">隐藏</button> </div> </div> </div> </nav> </div> </div> <div id="bodyContent" class="vector-body" aria-labelledby="firstHeading" data-mw-ve-target-container> <div class="vector-body-before-content"> <div class="mw-indicators"> </div> <div id="siteSub" class="noprint">维基百科，自由的百科全书</div> </div> <div id="contentSub"><div id="mw-content-subtitle"></div></div> <div id="mw-content-text" class="mw-body-content"><div class="mw-content-ltr mw-parser-output" lang="zh" dir="ltr"><style data-mw-deduplicate="TemplateStyles:r84001320">.mw-parser-output .ib-chembox{border-collapse:collapse;text-align:left}.mw-parser-output .ib-chembox td,.mw-parser-output .ib-chembox th{border:1px solid #a2a9b1;width:40%}.mw-parser-output .ib-chembox td+td{width:60%}</style> <table class="infobox ib-chembox nounderlines" cellspacing="0" cellpadding="3" rules="all" style="background-color:#f0f0f0; float:right; margin: 0 0 1em 1em; border-color: #aaaaaa; border-style:solid; border:1px; border-collapse:collapse; empty-cells:show; width:305px; font-size:90%;"> <tbody><tr> <th colspan="2" style="font-size:120%; text-align:center; background:#d6e0dc;">铁氰化钾 </th></tr> <tr> <td colspan="2" style="background:#ffffff; text-align:center;"><span typeof="mw:File"><a href="/wiki/File:Structure_of_potassium_ferricyanide.png" class="mw-file-description"><img alt="" src="//upload.wikimedia.org/wikipedia/commons/thumb/f/fd/Structure_of_potassium_ferricyanide.png/200px-Structure_of_potassium_ferricyanide.png" decoding="async" width="200" height="163" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/f/fd/Structure_of_potassium_ferricyanide.png/300px-Structure_of_potassium_ferricyanide.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/f/fd/Structure_of_potassium_ferricyanide.png/400px-Structure_of_potassium_ferricyanide.png 2x" data-file-width="1642" data-file-height="1339" /></a></span> </td></tr> <tr> <td colspan="2" style="background:#ffffff; text-align:center;"><span typeof="mw:File"><a href="/wiki/File:Potassium_ferricyanide.jpg" class="mw-file-description"><img alt="" src="//upload.wikimedia.org/wikipedia/commons/thumb/f/fe/Potassium_ferricyanide.jpg/200px-Potassium_ferricyanide.jpg" decoding="async" width="200" height="200" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/f/fe/Potassium_ferricyanide.jpg/300px-Potassium_ferricyanide.jpg 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/f/fe/Potassium_ferricyanide.jpg/400px-Potassium_ferricyanide.jpg 2x" data-file-width="867" data-file-height="867" /></a></span> </td></tr> <tr> <td colspan="2" style="max-width:305px; word-wrap: break-word; text-align: center;"><a href="/wiki/IUPAC%E5%91%BD%E5%90%8D%E6%B3%95" title="IUPAC命名法">IUPAC名</a><br />Potassium hexacyanoferrate(III)<br />六氰合铁(III)酸钾 </td></tr> <tr> <td>别名 </td> <td>铁氰酸钾<br />赤血盐 </td></tr> <tr> <th style="background:#D6E0DC; text-align:center;" colspan="2">识别 </th></tr> <tr> <td><a href="/wiki/CAS%E5%8F%B7" title="CAS号">CAS号</a> </td> <td><span class="reflink plainlinks nourlexpansion"><a rel="nofollow" class="external text" href="https://commonchemistry.cas.org/detail?cas_rn=13746-66-2">13746-66-2</a></span> <sup> <span typeof="mw:File"><span><img alt="check" src="//upload.wikimedia.org/wikipedia/commons/thumb/f/fb/Yes_check.svg/7px-Yes_check.svg.png" decoding="async" width="7" height="7" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/f/fb/Yes_check.svg/11px-Yes_check.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/f/fb/Yes_check.svg/14px-Yes_check.svg.png 2x" data-file-width="600" data-file-height="600" /></span></span><span style="display:none">Y</span></sup> </td></tr> <tr> <td><a href="/wiki/PubChem" title="PubChem">PubChem</a> </td> <td><span class="reflink plainlinks nourlexpansion"><a rel="nofollow" class="external text" href="https://pubchem.ncbi.nlm.nih.gov/compound/26250">26250</a></span> </td></tr> <tr> <td><a href="/wiki/ChemSpider" title="ChemSpider">ChemSpider</a> </td> <td><span class="reflink plainlinks nourlexpansion"><a rel="nofollow" class="external text" href="http://www.chemspider.com/24458">24458</a></span> </td></tr> <tr> <td><a href="/wiki/SMILES" class="mw-redirect" title="SMILES">SMILES</a> </td> <td><div style="word-break:break-all;"><div class="collapsible-list mw-collapsible mw-collapsed" style="text-align: left;"> <div style="line-height: 1.6em; font-weight: bold;"><div> </div></div> <ul class="mw-collapsible-content" style="margin-top: 0; margin-bottom: 0; line-height: inherit; list-style: none; margin-left: 0;"><li style="line-height: inherit; margin: 0"><span lang="en">[K+].[K+].N#C[Fe-3](C#N)(C#N)(C#N)(C#N)C#N.[K+]</span></li></ul> </div></div> </td></tr> <tr> <td><a href="/wiki/%E5%9B%BD%E9%99%85%E5%8C%96%E5%90%88%E7%89%A9%E6%A0%87%E8%AF%86" title="国际化合物标识">InChI</a> </td> <td><div style="word-break:break-all;"><div class="collapsible-list mw-collapsible mw-collapsed" style="text-align: left;"> <div style="line-height: 1.6em; font-weight: bold;"><div> </div></div> <ul class="mw-collapsible-content" style="margin-top: 0; margin-bottom: 0; line-height: inherit; list-style: none; margin-left: 0;"><li style="line-height: inherit; margin: 0">1S/6CN.Fe.3K/c6*1-2;;;;/q6*-1;+3;3*+1</li></ul> </div></div> </td></tr> <tr> <td><a href="/wiki/%E5%9B%BD%E9%99%85%E5%8C%96%E5%90%88%E7%89%A9%E6%A0%87%E8%AF%86" title="国际化合物标识">InChIKey</a> </td> <td><small>BYGOPQKDHGXNCD-UHFFFAOYAG</small> </td></tr> <tr> <td><a href="/wiki/%E7%9B%96%E5%A2%A8%E6%9E%97%E6%95%B0%E6%8D%AE%E5%BA%93" title="盖墨林数据库">Gmelin</a> </td> <td>21683 </td></tr> <tr> <td><a href="/wiki/ChEBI" title="ChEBI">ChEBI</a> </td> <td><span class="reflink plainlinks nourlexpansion"><a rel="nofollow" class="external text" href="http://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI:30060">30060</a></span> </td></tr> <tr> <td><a href="/wiki/%E5%8C%96%E5%AD%A6%E7%89%A9%E8%B4%A8%E6%AF%92%E6%80%A7%E6%95%B0%E6%8D%AE%E5%BA%93" title="化学物质毒性数据库">RTECS</a> </td> <td>LJ8225000 </td></tr> <tr> <th style="background:#D6E0DC; text-align:center;" colspan="2">性质 </th></tr> <tr> <td><a href="/wiki/%E5%8C%96%E5%AD%A6%E5%BC%8F" title="化学式">化学式</a> </td> <td><span lang="en">K<sub>3</sub>[Fe(CN)<sub>6</sub>]</span> </td></tr> <tr> <td><a href="/wiki/%E6%91%A9%E5%B0%94%E8%B4%A8%E9%87%8F" title="摩尔质量">摩尔质量</a> </td> <td>329.24 g·mol⁻¹ </td></tr> <tr> <td>外观 </td> <td>深红色晶体，橙色至深红色粉末 </td></tr> <tr> <td><a href="/wiki/%E5%AF%86%E5%BA%A6" title="密度">密度</a> </td> <td>1.89 g/cm<sup>3</sup> </td></tr> <tr> <td><a href="/wiki/%E7%86%94%E7%82%B9" title="熔点">熔点</a> </td> <td>300 °C（573 K） </td></tr> <tr> <td><a href="/wiki/%E6%B2%B8%E7%82%B9" title="沸点">沸点</a> </td> <td>分解 </td></tr> <tr> <td><a href="/wiki/%E6%BA%B6%E8%A7%A3%E6%80%A7" class="mw-redirect" title="溶解性">溶解性</a>（<a href="/wiki/%E6%B0%B4" title="水">水</a>） </td> <td>464 g/L (20 °C)<sup id="cite_ref-1" class="reference"><a href="#cite_note-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td><a href="/wiki/%E6%BA%B6%E8%A7%A3%E6%80%A7" class="mw-redirect" title="溶解性">溶解性</a> </td> <td>微溶于<a href="/wiki/%E4%B9%99%E9%86%87" title="乙醇">醇</a>，可溶于<a href="/wiki/%E9%85%B8" title="酸">酸</a> </td></tr> <tr> <td><a href="/wiki/%E7%A3%81%E5%8C%96%E7%8E%87" title="磁化率">磁化率</a> </td> <td>+2290.0·10<sup>−6</sup> cm<sup>3</sup>/mol </td></tr> <tr> <th style="background:#D6E0DC; text-align:center;" colspan="2">结构 </th></tr> <tr> <td><a href="/wiki/%E6%99%B6%E4%BD%93%E7%BB%93%E6%9E%84" title="晶体结构">晶体结构</a> </td> <td><a href="/wiki/%E5%8D%95%E6%96%9C" class="mw-redirect" title="单斜">单斜</a> </td></tr> <tr> <th style="background:#D6E0DC; text-align:center;" colspan="2">危险性 </th></tr> <tr> <td colspan="2" style="text-align: center;"><a href="/wiki/%E5%85%A8%E7%90%83%E5%8C%96%E5%AD%A6%E5%93%81%E7%BB%9F%E4%B8%80%E5%88%86%E7%B1%BB%E5%92%8C%E6%A0%87%E7%AD%BE%E5%88%B6%E5%BA%A6" title="全球化学品统一分类和标签制度">GHS危险性符号</a><br /><span typeof="mw:File"><a href="/wiki/File:GHS-pictogram-exclam.svg" class="mw-file-description" title="《全球化学品统一分类和标签制度》（简称“GHS”）中有害物质的标签图案"><img alt="《全球化学品统一分类和标签制度》（简称“GHS”）中有害物质的标签图案" src="//upload.wikimedia.org/wikipedia/commons/thumb/c/c3/GHS-pictogram-exclam.svg/50px-GHS-pictogram-exclam.svg.png" decoding="async" width="50" height="50" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/c/c3/GHS-pictogram-exclam.svg/75px-GHS-pictogram-exclam.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/c/c3/GHS-pictogram-exclam.svg/100px-GHS-pictogram-exclam.svg.png 2x" data-file-width="512" data-file-height="512" /></a></span> </td></tr> <tr> <td><a href="/wiki/%E5%85%A8%E7%90%83%E5%8C%96%E5%AD%A6%E5%93%81%E7%BB%9F%E4%B8%80%E5%88%86%E7%B1%BB%E5%92%8C%E6%A0%87%E7%AD%BE%E5%88%B6%E5%BA%A6" title="全球化学品统一分类和标签制度">GHS提示词</a> </td> <td>warning </td></tr> <tr> <td><a href="/wiki/GHS%E5%8D%B1%E9%99%A9%E8%AF%B4%E6%98%8E" title="GHS危险说明">H-术语</a> </td> <td><span class="abbr skin-invert" style="color: blue; border-bottom: 1px dotted blue" title="吞咽有害">H302</span>, <span class="abbr skin-invert" style="color: blue; border-bottom: 1px dotted blue" title="造成皮肤刺激">H315</span>, <span class="abbr skin-invert" style="color: blue; border-bottom: 1px dotted blue" title="造成严重眼刺激">H319</span>, <span class="abbr skin-invert" style="color: blue; border-bottom: 1px dotted blue" title="吸入有害">H332</span>, <span class="abbr skin-invert" style="color: blue; border-bottom: 1px dotted blue" title="可能引起呼吸道刺激">H335</span> </td></tr> <tr> <td><a href="/wiki/GHS%E9%98%B2%E8%8C%83%E8%AF%B4%E6%98%8E" title="GHS防范说明">P-术语</a> </td> <td><span class="abbr skin-invert" style="color: blue; border-bottom: 1px dotted blue" title="避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾">P261</span>, <span class="abbr skin-invert" style="color: blue; border-bottom: 1px dotted blue" title="作业后彻底清洗……">P264</span>, <span class="abbr skin-invert" style="color: blue; border-bottom: 1px dotted blue" title="使用本产品时不要进食、饮水或吸烟">P270</span>, <span class="abbr skin-invert" style="color: blue; border-bottom: 1px dotted blue" title="只能在室外或通风良好处使用">P271</span>, <span class="abbr skin-invert" style="color: blue; border-bottom: 1px dotted blue" title="戴防护手套/穿防护服/戴防护眼罩/戴防护面具">P280</span>, <span class="abbr skin-invert" style="color: blue; border-bottom: 1px dotted blue" title="如误吞咽：如感觉不适，呼叫解毒中心或医生">P301+312</span>, <span class="abbr skin-invert" style="color: blue; border-bottom: 1px dotted blue" title="如皮肤沾染：用大量肥皂和水清洗">P302+352</span>, <span class="abbr skin-invert" style="color: blue; border-bottom: 1px dotted blue" title="如误吸入：如感觉不适，呼叫解毒中心或医生">P304+312</span>, <span class="abbr skin-invert" style="color: blue; border-bottom: 1px dotted blue" title="如误吸入：将伤者转移到空气新鲜处，使其保持呼吸舒适的休息姿势">P304+340</span>, <span class="abbr skin-invert" style="color: blue; border-bottom: 1px dotted blue" title="如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜再继续冲洗">P305+351+338</span>, <span class="abbr skin-invert" style="color: blue; border-bottom: 1px dotted blue" title="如感觉不适，呼叫解毒中心或医生">P312</span>, <span class="abbr skin-invert" style="color: blue; border-bottom: 1px dotted blue" title="具体治疗（见本标签上的……）">P321</span>, <span class="abbr skin-invert" style="color: blue; border-bottom: 1px dotted blue" title="漱口">P330</span>, <span class="abbr skin-invert" style="color: blue; border-bottom: 1px dotted blue" title="如发生皮肤刺激：求医/就诊">P332+313</span> </td></tr> <tr> <td><a href="/wiki/NFPA_704" title="NFPA 704">NFPA 704</a> </td> <td> <div style="position: relative; height: 85px; width: 75px;"> <div style="position: absolute; height: 75px; width: 75px;"><span typeof="mw:File"><a href="/wiki/File:NFPA_704.svg" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/6/6f/NFPA_704.svg/75px-NFPA_704.svg.png" decoding="async" width="75" height="75" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/6/6f/NFPA_704.svg/113px-NFPA_704.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/6/6f/NFPA_704.svg/150px-NFPA_704.svg.png 2x" data-file-width="512" data-file-height="512" /></a></span></div> <div title="可燃性" style="background: transparent; width: 75px; height: 2em; text-align: center; vertical-align: middle; position: absolute; top: 3px; font-size: large;"><span class="abbr" style="color: black;" title="可燃性0級。不會燃燒（如水）。"><b>0</b></span></div> <div title="健康" style="background: transparent; width: 37.5px; height: 2em; text-align: center; vertical-align: middle; position: absolute; top: 21px; font-size: large;"><span class="abbr" style="color: black;" title="健康危險1級。暴露可能導致不適，但是僅可能有輕微持續性傷害（如松節油）。"><b>1</b></span></div> <div title="反應性" style="background: transparent; width: 37.5px; height: 2em; text-align: center; vertical-align: middle; position: absolute; top: 21px; left: 37.5px; font-size: large;"><span class="abbr" style="color: black;" title="反應性0級。通常情況下穩定，即使暴露於明火中也不反應，並且不與水反應（如液氮）。"><b>0</b></span></div> <div title="其它危險" style="background: transparent; width: 75px; height: 2em; text-align: center; vertical-align: middle; position: absolute; top: 44px; font-size: small;"> </div> </div> </td></tr> <tr> <td><a href="/wiki/%E9%97%AA%E7%82%B9" title="闪点">闪点</a> </td> <td>不可燃 </td></tr> <tr> <td colspan="2" style="text-align:left; background-color:#f1f1f1;">致死量或浓度： </td></tr> <tr class="skin-invert" style="background:#f1f1f1;"> <td style="padding-left:1em;"><div style="padding:0.1em 0;line-height:1.2em;">LD<sub>50</sub>（<a href="/wiki/%E5%8D%8A%E6%95%B8%E8%87%B4%E6%AD%BB%E9%87%8F" title="半數致死量">中位剂量</a>）</div> </td> <td>2970 mg/kg（大鼠经口） </td></tr> <tr> <th style="background:#D6E0DC; text-align:center;" colspan="2">相关物质 </th></tr> <tr> <td>其他<a href="/wiki/%E9%98%B4%E7%A6%BB%E5%AD%90" class="mw-redirect" title="阴离子">阴离子</a> </td> <td><a href="/wiki/%E4%BA%9A%E9%93%81%E6%B0%B0%E5%8C%96%E9%92%BE" title="亚铁氰化钾">亚铁氰化钾</a> </td></tr> <tr> <td>其他<a href="/wiki/%E9%98%B3%E7%A6%BB%E5%AD%90" class="mw-redirect" title="阳离子">阳离子</a> </td> <td><a href="/wiki/%E6%99%AE%E9%B2%81%E5%A3%AB%E8%93%9D" title="普鲁士蓝">普鲁士蓝</a> </td></tr> <tr> <th style="background:#D6E0DC; text-align:center;" colspan="2"><a href="/wiki/%E9%93%81%E6%B0%B0%E5%8C%96%E9%92%BE%E6%80%A7%E8%B4%A8%E8%A1%A8" title="铁氰化钾性质表">附加数据页</a> </th></tr> <tr> <td><a href="/wiki/%E9%93%81%E6%B0%B0%E5%8C%96%E9%92%BE%E6%80%A7%E8%B4%A8%E8%A1%A8#结构和属性" title="铁氰化钾性质表">结构和属性</a> </td> <td><a href="/wiki/%E6%8A%98%E5%B0%84%E7%8E%87" title="折射率">折射率</a>、<a href="/wiki/%E4%BB%8B%E9%9B%BB%E4%BF%82%E6%95%B8" class="mw-redirect" title="介電係數">介電係數</a>等 </td></tr> <tr> <td><a href="/wiki/%E9%93%81%E6%B0%B0%E5%8C%96%E9%92%BE%E6%80%A7%E8%B4%A8%E8%A1%A8#热力学数据" title="铁氰化钾性质表">热力学数据</a> </td> <td><a href="/wiki/%E7%9B%B8%E8%AE%8A" title="相變">相變</a>数据、固、液、气性质 </td></tr> <tr> <td><a href="/wiki/%E9%93%81%E6%B0%B0%E5%8C%96%E9%92%BE%E6%80%A7%E8%B4%A8%E8%A1%A8#光谱数据" title="铁氰化钾性质表">光谱数据</a> </td> <td><a href="/wiki/%E7%B4%AB%E5%A4%96%E5%8F%AF%E8%A7%81%E5%85%89%E8%B0%B1" class="mw-redirect" title="紫外可见光谱">UV-Vis</a>、<a href="/wiki/%E7%BA%A2%E5%A4%96%E5%85%89%E8%B0%B1" class="mw-redirect" title="红外光谱">IR</a>、<a href="/wiki/%E6%A0%B8%E7%A3%81%E5%85%B1%E6%8C%AF%E9%A0%BB%E8%AD%9C%E5%AD%B8" class="mw-redirect" title="核磁共振頻譜學">NMR</a>、<a href="/wiki/%E8%B4%A8%E8%B0%B1" class="mw-redirect" title="质谱">MS</a>等 </td></tr> <tr> <td style="background:#D6E0DC; text-align:center;" colspan="2">若非注明，所有数据均出自<a href="/wiki/%E6%A0%87%E5%87%86%E7%8A%B6%E6%80%81" title="标准状态">标准状态（25 ℃，100 kPa）</a>下。 </td></tr></tbody></table> <p><b>铁氰化钾</b>，俗稱<b>赤血鹽</b>，是化学式为K<sub>3</sub>[Fe(CN)<sub>6</sub>]的<a href="/wiki/%E5%8C%96%E5%90%88%E7%89%A9" title="化合物">化合物</a>。这种鲜红色的盐含有<a href="/wiki/%E5%85%AB%E9%9D%A2%E4%BD%93%E6%9E%84%E5%9E%8B" class="mw-redirect" title="八面体构型">八面体</a><a href="/wiki/%E9%85%8D%E4%BD%8D" class="mw-redirect" title="配位">配位</a>的<a href="/wiki/%E9%93%81%E6%B0%B0%E9%85%B8%E7%9B%90" class="mw-redirect" title="铁氰酸盐">[Fe(CN)<sub>6</sub>]<sup>3−</sup></a>离子<sup id="cite_ref-2" class="reference"><a href="#cite_note-2"><span class="cite-bracket">[</span>2<span class="cite-bracket">]</span></a></sup>。它易溶于水，溶液有黄绿色<a href="/wiki/%E8%8D%A7%E5%85%89" title="荧光">荧光</a>。它由<a href="/wiki/%E5%88%A9%E5%A5%A5%E6%B3%A2%E5%BE%B7%C2%B7%E6%A0%BC%E6%A2%85%E6%9E%97" title="利奥波德·格梅林">利奥波德·格梅林</a>于1822年发现<sup id="cite_ref-3" class="reference"><a href="#cite_note-3"><span class="cite-bracket">[</span>3<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-4" class="reference"><a href="#cite_note-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup>。 </p> <meta property="mw:PageProp/toc" /> <div class="mw-heading mw-heading2"><h2 id="制备"><span id=".E5.88.B6.E5.A4.87"></span>制备</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E9%93%81%E6%B0%B0%E5%8C%96%E9%92%BE&action=edit&section=1" title="编辑章节：制备"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>铁氰化钾由<a href="/wiki/%E6%B0%AF%E6%B0%94" title="氯气">氯气</a>通入<a href="/wiki/%E4%BA%9A%E9%93%81%E6%B0%B0%E5%8C%96%E9%92%BE" title="亚铁氰化钾">亚铁氰化钾</a>溶液制备： </p> <dl><dd><span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle {\ce {2K4[Fe(CN)6] +Cl2 -> 2K3[Fe(CN)6] +2KCl}}}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <mrow class="MJX-TeXAtom-ORD"> <mn>2</mn> <mspace width="thinmathspace" /> <msubsup> <mtext>K</mtext> <mrow class="MJX-TeXAtom-ORD"> <mn>4</mn> </mrow> <mrow class="MJX-TeXAtom-ORD"> <mspace width="0pt" height="0pt" depth=".2em" /> </mrow> </msubsup> <mrow class="MJX-TeXAtom-ORD"> <mo stretchy="false">[</mo> <mtext>Fe</mtext> <msubsup> <mrow class="MJX-TeXAtom-ORD"> <mo stretchy="false">(</mo> <mtext>CN</mtext> <mo stretchy="false">)</mo> </mrow> <mrow class="MJX-TeXAtom-ORD"> <mn>6</mn> </mrow> <mrow class="MJX-TeXAtom-ORD"> <mspace width="0pt" height="0pt" depth=".2em" /> </mrow> </msubsup> <mo stretchy="false">]</mo> </mrow> <mo>+</mo> <msubsup> <mtext>Cl</mtext> <mrow class="MJX-TeXAtom-ORD"> <mn>2</mn> </mrow> <mrow class="MJX-TeXAtom-ORD"> <mspace width="0pt" height="0pt" depth=".2em" /> </mrow> </msubsup> <mo stretchy="false">⟶</mo> <mn>2</mn> <mspace width="thinmathspace" /> <msubsup> <mtext>K</mtext> <mrow class="MJX-TeXAtom-ORD"> <mn>3</mn> </mrow> <mrow class="MJX-TeXAtom-ORD"> <mspace width="0pt" height="0pt" depth=".2em" /> </mrow> </msubsup> <mrow class="MJX-TeXAtom-ORD"> <mo stretchy="false">[</mo> <mtext>Fe</mtext> <msubsup> <mrow class="MJX-TeXAtom-ORD"> <mo stretchy="false">(</mo> <mtext>CN</mtext> <mo stretchy="false">)</mo> </mrow> <mrow class="MJX-TeXAtom-ORD"> <mn>6</mn> </mrow> <mrow class="MJX-TeXAtom-ORD"> <mspace width="0pt" height="0pt" depth=".2em" /> </mrow> </msubsup> <mo stretchy="false">]</mo> </mrow> <mo>+</mo> <mn>2</mn> <mspace width="thinmathspace" /> <mtext>KCl</mtext> </mrow> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle {\ce {2K4[Fe(CN)6] +Cl2 -> 2K3[Fe(CN)6] +2KCl}}}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/8317710a68796c50af2537976c9c3f21c05daa98" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -1.005ex; width:48.919ex; height:3.009ex;" alt="{\displaystyle {\ce {2K4[Fe(CN)6] +Cl2 -> 2K3[Fe(CN)6] +2KCl}}}"></span></dd></dl> <div class="mw-heading mw-heading2"><h2 id="结构"><span id=".E7.BB.93.E6.9E.84"></span>结构</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E9%93%81%E6%B0%B0%E5%8C%96%E9%92%BE&action=edit&section=2" title="编辑章节：结构"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>与其他金属氰化物一样，铁氰化钾固体具有复杂的聚合结构。该聚合物由八面体[Fe(CN)<sub>6</sub>]<sup>3−</sup>中心和与CN配体结合的K<sup>+</sup>离子交联<sup id="cite_ref-5" class="reference"><a href="#cite_note-5"><span class="cite-bracket">[</span>5<span class="cite-bracket">]</span></a></sup>。当固体溶解在水中时，K<sup>+</sup>-NCFe键会断裂。 </p> <div class="mw-heading mw-heading2"><h2 id="应用"><span id=".E5.BA.94.E7.94.A8"></span>应用</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E9%93%81%E6%B0%B0%E5%8C%96%E9%92%BE&action=edit&section=3" title="编辑章节：应用"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>铁氰化钾可用于钢铁<a href="/wiki/%E8%A1%A8%E9%9D%A2%E7%A1%AC%E5%8C%96" title="表面硬化">表面硬化</a>、<a href="/wiki/%E7%94%B5%E9%95%80" title="电镀">电镀</a>、羊毛染色、实验室<a href="/wiki/%E8%AF%95%E5%89%82" class="mw-redirect" title="试剂">试剂</a>和<a href="/wiki/%E6%9C%89%E6%9C%BA%E5%8C%96%E5%AD%A6" title="有机化学">有机化学</a>中的温和<a href="/wiki/%E6%B0%A7%E5%8C%96%E5%89%82" title="氧化剂">氧化剂</a>。 </p> <div class="mw-heading mw-heading3"><h3 id="蓝图与摄影"><span id=".E8.93.9D.E5.9B.BE.E4.B8.8E.E6.91.84.E5.BD.B1"></span>蓝图与摄影</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E9%93%81%E6%B0%B0%E5%8C%96%E9%92%BE&action=edit&section=4" title="编辑章节：蓝图与摄影"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>铁氰化钾广泛用于<a href="/wiki/%E8%93%9D%E5%9B%BE" class="mw-redirect" title="蓝图">蓝图</a>绘制和<a href="/wiki/%E6%91%84%E5%BD%B1" title="摄影">摄影</a>（<a href="/wiki/%E8%97%8D%E5%9C%96#蓝图工艺" title="藍圖">蓝晒法</a>）。一些<span class="ilh-all" data-orig-title="照相印刷调色" data-lang-code="en" data-lang-name="英语" data-foreign-title="Photographic print toning"><span class="ilh-page"><a href="/w/index.php?title=%E7%85%A7%E7%9B%B8%E5%8D%B0%E5%88%B7%E8%B0%83%E8%89%B2&action=edit&redlink=1" class="new" title="照相印刷调色（页面不存在）">照相印刷调色</a></span><span class="noprint ilh-comment">（<span class="ilh-lang">英语</span><span class="ilh-colon">：</span><span class="ilh-link"><a href="https://en.wikipedia.org/wiki/Photographic_print_toning" class="extiw" title="en:Photographic print toning"><span lang="en" dir="auto">Photographic print toning</span></a></span>）</span></span>过程涉及使用铁氰化钾。在处理过程中，铁氰化钾作为<a href="/wiki/%E6%B0%A7%E5%8C%96%E5%89%82" title="氧化剂">氧化剂</a>从彩色负片和正片中去除<a href="/wiki/%E9%93%B6" class="mw-redirect" title="银">银</a>，这一过程称为漂白。由于铁氰化钾漂白剂对环境不友好、寿命短，并且如果与高浓度和大量的酸混合会释放出氰化氢气体，自1972年引入柯达<a href="/wiki/C-41%E6%B2%96%E5%8D%B0%E8%99%95%E7%90%86" title="C-41沖印處理">C-41冲印处理</a>工艺以来，使用<a href="/wiki/EDTA" class="mw-redirect" title="EDTA">EDTA</a>铁的漂白剂已用于彩色刻印。在彩色刻印中，铁氰化钾用于在不减少点数的情况下减小色点的尺寸，作为一种称为点蚀刻的手动颜色校正。它还与少量<a href="/wiki/%E7%A1%AB%E4%BB%A3%E7%A1%AB%E9%85%B8%E9%92%A0" title="硫代硫酸钠">硫代硫酸钠</a>一起用于黑白摄影，以降低<a href="/wiki/%E8%B2%A0%E7%89%87" title="負片">负片</a>或<span class="ilh-all" data-orig-title="明胶银刻印" data-lang-code="en" data-lang-name="英语" data-foreign-title="Gelatin silver print"><span class="ilh-page"><a href="/w/index.php?title=%E6%98%8E%E8%83%B6%E9%93%B6%E5%88%BB%E5%8D%B0&action=edit&redlink=1" class="new" title="明胶银刻印（页面不存在）">明胶银刻印</a></span><span class="noprint ilh-comment">（<span class="ilh-lang">英语</span><span class="ilh-colon">：</span><span class="ilh-link"><a href="https://en.wikipedia.org/wiki/Gelatin_silver_print" class="extiw" title="en:Gelatin silver print"><span lang="en" dir="auto">Gelatin silver print</span></a></span>）</span></span>的密度；这可以帮助抵消因负片<a href="/wiki/%E6%9B%9D%E5%85%89" title="曝光">过曝</a>引起的问题，或使照片中的高光变亮<sup id="cite_ref-6" class="reference"><a href="#cite_note-6"><span class="cite-bracket">[</span>6<span class="cite-bracket">]</span></a></sup>。 </p> <div class="mw-heading mw-heading3"><h3 id="有机合成试剂"><span id=".E6.9C.89.E6.9C.BA.E5.90.88.E6.88.90.E8.AF.95.E5.89.82"></span>有机合成试剂</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E9%93%81%E6%B0%B0%E5%8C%96%E9%92%BE&action=edit&section=5" title="编辑章节：有机合成试剂"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>铁氰化钾在有机化学中用作氧化剂<sup id="cite_ref-7" class="reference"><a href="#cite_note-7"><span class="cite-bracket">[</span>7<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-8" class="reference"><a href="#cite_note-8"><span class="cite-bracket">[</span>8<span class="cite-bracket">]</span></a></sup>。它是<a href="/wiki/%E5%A4%8F%E6%99%AE%E8%8E%B1%E6%96%AF%E4%B8%8D%E5%AF%B9%E7%A7%B0%E5%8F%8C%E7%BE%9F%E5%9F%BA%E5%8C%96%E5%8F%8D%E5%BA%94" title="夏普莱斯不对称双羟基化反应">夏普莱斯不对称双羟基化反应</a>中催化剂再生的氧化剂<sup id="cite_ref-9" class="reference"><a href="#cite_note-9"><span class="cite-bracket">[</span>9<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-10" class="reference"><a href="#cite_note-10"><span class="cite-bracket">[</span>10<span class="cite-bracket">]</span></a></sup>。 </p> <div class="mw-heading mw-heading3"><h3 id="其他"><span id=".E5.85.B6.E4.BB.96"></span>其他</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E9%93%81%E6%B0%B0%E5%8C%96%E9%92%BE&action=edit&section=6" title="编辑章节：其他"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>铁氰化钾与<a href="/wiki/%E6%B0%A2%E6%B0%A7%E5%8C%96%E9%92%BE" title="氢氧化钾">氢氧化钾</a>（或作为替代品的<a href="/wiki/%E6%B0%A2%E6%B0%A7%E5%8C%96%E9%92%A0" title="氢氧化钠">氢氧化钠</a>）和水混合，可制成村上蚀刻剂。金相学家使用这种蚀刻剂来提供硬质合金中粘合剂和碳化物相之间的对比。 </p><p>铁氰化钾可用于检验<a href="/wiki/%E4%BA%9A%E9%93%81%E7%A6%BB%E5%AD%90" class="mw-redirect" title="亚铁离子">亚铁离子</a>，亞铁离子与铁氰化钾溶液（黄色）反应生成<a href="/wiki/%E6%99%AE%E9%B2%81%E5%A3%AB%E8%93%9D" title="普鲁士蓝">普鲁士蓝</a>沉淀。 </p> <div class="mw-heading mw-heading2"><h2 id="普鲁士蓝"><span id=".E6.99.AE.E9.B2.81.E5.A3.AB.E8.93.9D"></span>普鲁士蓝</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E9%93%81%E6%B0%B0%E5%8C%96%E9%92%BE&action=edit&section=7" title="编辑章节：普鲁士蓝"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p><a href="/wiki/%E6%99%AE%E9%B2%81%E5%A3%AB%E8%93%9D" title="普鲁士蓝">普鲁士蓝</a>是蓝印法中的深蓝色颜料，由K<sub>3</sub>[Fe(CN)<sub>6</sub>]<sup>-</sup>与亚铁（Fe<sup>2+</sup>）离子以及K<sub>4</sub>[Fe(CN)<sub>6</sub>]与铁盐反应生成。<sup id="cite_ref-11" class="reference"><a href="#cite_note-11"><span class="cite-bracket">[</span>11<span class="cite-bracket">]</span></a></sup> 在<a href="/wiki/%E7%BB%84%E7%BB%87%E5%AD%A6" title="组织学">组织学</a>中，铁氰化钾用于检测生物组织中的亚铁离子。铁氰化钾在酸性溶液中与亚铁离子反应生成不溶性蓝色色素，通常称为藤氏蓝或普鲁士蓝。为了检测三价铁（Fe<sup>3+</sup>）离子，在<span class="ilh-all" data-orig-title="Perls普鲁士蓝染色法" data-lang-code="en" data-lang-name="英语" data-foreign-title="Perls Prussian blue"><span class="ilh-page"><a href="/w/index.php?title=Perls%E6%99%AE%E9%B2%81%E5%A3%AB%E8%93%9D%E6%9F%93%E8%89%B2%E6%B3%95&action=edit&redlink=1" class="new" title="Perls普鲁士蓝染色法（页面不存在）">Perls普鲁士蓝染色法</a></span><span class="noprint ilh-comment">（<span class="ilh-lang">英语</span><span class="ilh-colon">：</span><span class="ilh-link"><a href="https://en.wikipedia.org/wiki/Perls_Prussian_blue" class="extiw" title="en:Perls Prussian blue"><span lang="en" dir="auto">Perls Prussian blue</span></a></span>）</span></span>中用<a href="/wiki/%E4%BA%9A%E9%93%81%E6%B0%B0%E5%8C%96%E9%92%BE" title="亚铁氰化钾">亚铁氰化钾</a>代替<sup id="cite_ref-12" class="reference"><a href="#cite_note-12"><span class="cite-bracket">[</span>12<span class="cite-bracket">]</span></a></sup>。在藤氏蓝反应中形成的物质和在普鲁士蓝反应中形成的化合物是相同的<sup id="cite_ref-13" class="reference"><a href="#cite_note-13"><span class="cite-bracket">[</span>13<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-14" class="reference"><a href="#cite_note-14"><span class="cite-bracket">[</span>14<span class="cite-bracket">]</span></a></sup>。 </p> <div class="mw-heading mw-heading2"><h2 id="安全"><span id=".E5.AE.89.E5.85.A8"></span>安全</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E9%93%81%E6%B0%B0%E5%8C%96%E9%92%BE&action=edit&section=8" title="编辑章节：安全"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>铁氰化钾毒性低，主要危害是对眼睛和皮肤有轻微刺激性。然而，在非常强的酸性条件下，会产生剧毒的<a href="/wiki/%E6%B0%B0%E5%8C%96%E6%B0%A2" title="氰化氢">氰化氢</a>气体： </p> <dl><dd><span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle {\ce {6H+ +[Fe(CN)6]^{3-}-> 6HCN + Fe^{3+}}}}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <mrow class="MJX-TeXAtom-ORD"> <mn>6</mn> <mspace width="thinmathspace" /> <msup> <mtext>H</mtext> <mrow class="MJX-TeXAtom-ORD"> <mo>+</mo> </mrow> </msup> <mo>+</mo> <msup> <mrow class="MJX-TeXAtom-ORD"> <mo stretchy="false">[</mo> <mtext>Fe</mtext> <msubsup> <mrow class="MJX-TeXAtom-ORD"> <mo stretchy="false">(</mo> <mtext>CN</mtext> <mo stretchy="false">)</mo> </mrow> <mrow class="MJX-TeXAtom-ORD"> <mn>6</mn> </mrow> <mrow class="MJX-TeXAtom-ORD"> <mspace width="0pt" height="0pt" depth=".2em" /> </mrow> </msubsup> <mo stretchy="false">]</mo> </mrow> <mrow class="MJX-TeXAtom-ORD"> <mn>3</mn> <mspace width="thinmathspace" /> <mrow class="MJX-TeXAtom-ORD"> <mo>−</mo> </mrow> </mrow> </msup> <mo stretchy="false">⟶</mo> <mn>6</mn> <mspace width="thinmathspace" /> <mtext>HCN</mtext> <mo>+</mo> <msup> <mtext>Fe</mtext> <mrow class="MJX-TeXAtom-ORD"> <mn>3</mn> <mspace width="thinmathspace" /> <mo>+</mo> </mrow> </msup> </mrow> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle {\ce {6H+ +[Fe(CN)6]^{3-}-> 6HCN + Fe^{3+}}}}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/af2b1e40e3deccd5203b2dd696cb2eb265c1c73e" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -1.005ex; width:40.413ex; height:3.509ex;" alt="{\displaystyle {\ce {6H+ +[Fe(CN)6]^{3-}-> 6HCN + Fe^{3+}}}}"></span><sup id="cite_ref-15" class="reference"><a href="#cite_note-15"><span class="cite-bracket">[</span>15<span class="cite-bracket">]</span></a></sup></dd></dl> <div class="mw-heading mw-heading2"><h2 id="參見"><span id=".E5.8F.83.E8.A6.8B"></span>參見</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E9%93%81%E6%B0%B0%E5%8C%96%E9%92%BE&action=edit&section=9" title="编辑章节：參見"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <ul><li><a href="/wiki/%E9%93%81%E6%B0%B0%E9%85%B8%E7%9B%90" class="mw-redirect" title="铁氰酸盐">铁氰酸盐</a></li> <li><a href="/wiki/%E4%BA%9A%E9%93%81%E6%B0%B0%E9%85%B8%E7%9B%90" class="mw-redirect" title="亚铁氰酸盐">亚铁氰酸盐</a></li> <li><a href="/wiki/%E4%BA%9A%E9%93%81%E6%B0%B0%E5%8C%96%E9%92%BE" title="亚铁氰化钾">亚铁氰化钾</a></li></ul> <div class="mw-heading mw-heading2"><h2 id="参考资料"><span id=".E5.8F.82.E8.80.83.E8.B5.84.E6.96.99"></span>参考资料</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E9%93%81%E6%B0%B0%E5%8C%96%E9%92%BE&action=edit&section=10" title="编辑章节：参考资料"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <div class="reflist" style="list-style-type: decimal;"> <ol class="references"> <li id="cite_note-1"><span 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Paquette, L. (编). Encyclopedia of Reagents for Organic Synthesis. New York: J. Wiley & Sons. 2004 <span class="reference-accessdate"> [<span class="nowrap">2022-03-12</span>]</span>. <a href="/wiki/Special:%E7%BD%91%E7%BB%9C%E4%B9%A6%E6%BA%90/9780471936237" title="Special:网络书源/9780471936237"><span title="国际标准书号">ISBN</span> 9780471936237</a>. <a rel="nofollow" class="external text" href="https://doi.org/10.1002%2F047084289X"><span title="數位物件識別號">doi:10.1002/047084289X</span></a>. <span class="plainlinks"><a rel="nofollow" class="external text" href="//hdl.handle.net/10261%2F236866"><span title="Handle System">hdl:10261/236866</span></a> <span typeof="mw:File"><span title="可免费查阅"><img alt="可免费查阅" src="//upload.wikimedia.org/wikipedia/commons/thumb/6/65/Lock-green.svg/9px-Lock-green.svg.png" decoding="async" width="9" height="14" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/6/65/Lock-green.svg/14px-Lock-green.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/6/65/Lock-green.svg/18px-Lock-green.svg.png 2x" data-file-width="512" data-file-height="813" /></span></span></span>. （<a rel="nofollow" class="external text" href="https://hal.archives-ouvertes.fr/hal-02922790">原始内容</a>存档于2022-03-12）.</cite><span title="ctx_ver=Z39.88-2004&rfr_id=info%3Asid%2Fzh.wikipedia.org%3A%E9%93%81%E6%B0%B0%E5%8C%96%E9%92%BE&rft.atitle=Potassium+Ferricyanide&rft.au=Kwong%2C+H.-L.&rft.btitle=Encyclopedia+of+Reagents+for+Organic+Synthesis&rft.date=2004&rft.genre=bookitem&rft.isbn=9780471936237&rft.place=New+York&rft.pub=J.+Wiley+%26+Sons&rft_id=https%3A%2F%2Fhal.archives-ouvertes.fr%2Fhal-02922790&rft_id=info%3Adoi%2F10.1002%2F047084289X&rft_id=info%3Ahdl%2F10261%2F236866&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook" class="Z3988"><span style="display:none;"> </span></span></span> </li> <li id="cite_note-2"><span class="mw-cite-backlink"><b><a href="#cite_ref-2">^</a></b></span> <span class="reference-text"><cite class="citation book">Sharpe, A. 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International Journal of Molecular Sciences. 2003, <b>4</b> (6): 362–370 <span class="reference-accessdate"> [<span class="nowrap">2008-05-11</span>]</span>. <span class="plainlinks"><a rel="nofollow" class="external text" href="https://doi.org/10.3390%2Fi4060362"><span title="數位物件識別號">doi:10.3390/i4060362</span></a> <span typeof="mw:File"><span title="可免费查阅"><img alt="可免费查阅" src="//upload.wikimedia.org/wikipedia/commons/thumb/6/65/Lock-green.svg/9px-Lock-green.svg.png" decoding="async" width="9" height="14" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/6/65/Lock-green.svg/14px-Lock-green.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/6/65/Lock-green.svg/18px-Lock-green.svg.png 2x" data-file-width="512" data-file-height="813" /></span></span></span>. （<a rel="nofollow" class="external text" href="http://www.mdpi.org/ijms/papers/i4060362.pdf">原始内容</a> <span style="font-size:85%;">(PDF)</span>存档于2008-05-28）.</cite><span title="ctx_ver=Z39.88-2004&rfr_id=info%3Asid%2Fzh.wikipedia.org%3A%E9%93%81%E6%B0%B0%E5%8C%96%E9%92%BE&rft.atitle=Comparative+Studies+on+Prussian+Blue+or+Diaquatetraamine-Cobalt%28III%29+Promoted+Hydrolysis+of+4-Nitrophenylphosphate+in+Microemulsions&rft.au=Tafesse%2C+F.&rft.date=2003&rft.genre=article&rft.issue=6&rft.jtitle=International+Journal+of+Molecular+Sciences&rft.pages=362-370&rft.volume=4&rft_id=http%3A%2F%2Fwww.mdpi.org%2Fijms%2Fpapers%2Fi4060362.pdf&rft_id=info%3Adoi%2F10.3390%2Fi4060362&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal" class="Z3988"><span style="display:none;"> </span></span></span> </li> <li id="cite_note-14"><span class="mw-cite-backlink"><b><a href="#cite_ref-14">^</a></b></span> <span class="reference-text"><cite class="citation journal">Verdaguer, M.; Galvez, N.; Garde, R.; Desplanches, C. <a rel="nofollow" class="external text" href="https://web.archive.org/web/20201023093915/https://www.electrochem.org/dl/interface/fal/fal02/IF8-02-Pages28-32.pdf">Electrons at Work in Prussian Blue Analogues</a> <span style="font-size:85%;">(PDF)</span>. Electrochemical Society Interface. 2002, <b>11</b> (3): 28–32 <span class="reference-accessdate"> [<span class="nowrap">2022-03-12</span>]</span>. <a rel="nofollow" class="external text" href="https://doi.org/10.1002%2Fchin.200304218"><span title="數位物件識別號">doi:10.1002/chin.200304218</span></a>. （<a rel="nofollow" class="external text" href="http://www.electrochem.org/dl/interface/fal/fal02/IF8-02-Pages28-32.pdf">原始内容</a> <span style="font-size:85%;">(PDF)</span>存档于2020-10-23）.</cite><span title="ctx_ver=Z39.88-2004&rfr_id=info%3Asid%2Fzh.wikipedia.org%3A%E9%93%81%E6%B0%B0%E5%8C%96%E9%92%BE&rft.atitle=Electrons+at+Work+in+Prussian+Blue+Analogues&rft.au=Desplanches%2C+C.&rft.au=Galvez%2C+N.&rft.au=Garde%2C+R.&rft.au=Verdaguer%2C+M.&rft.date=2002&rft.genre=article&rft.issue=3&rft.jtitle=Electrochemical+Society+Interface&rft.pages=28-32&rft.volume=11&rft_id=http%3A%2F%2Fwww.electrochem.org%2Fdl%2Finterface%2Ffal%2Ffal02%2FIF8-02-Pages28-32.pdf&rft_id=info%3Adoi%2F10.1002%2Fchin.200304218&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal" class="Z3988"><span style="display:none;"> </span></span></span> </li> <li id="cite_note-15"><span class="mw-cite-backlink"><b><a href="#cite_ref-15">^</a></b></span> <span class="reference-text"><cite class="citation web"><a rel="nofollow" class="external text" href="https://web.archive.org/web/20160418075117/http://www.labchem.com/tools/msds/msds/LC19040.pdf">MSDS for potassium ferricyanide</a> <span style="font-size:85%;">(PDF)</span>. <span class="reference-accessdate"> [<span class="nowrap">2022-03-12</span>]</span>. （<a rel="nofollow" class="external text" href="http://www.labchem.com/tools/msds/msds/LC19040.pdf">原始内容</a> <span style="font-size:85%;">(PDF)</span>存档于2016-04-18）.</cite><span title="ctx_ver=Z39.88-2004&rfr_id=info%3Asid%2Fzh.wikipedia.org%3A%E9%93%81%E6%B0%B0%E5%8C%96%E9%92%BE&rft.btitle=MSDS+for+potassium+ferricyanide&rft.genre=unknown&rft_id=http%3A%2F%2Fwww.labchem.com%2Ftools%2Fmsds%2Fmsds%2FLC19040.pdf&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook" class="Z3988"><span style="display:none;"> </span></span></span> </li> </ol></div> <div class="mw-heading mw-heading2"><h2 id="外部链接"><span id=".E5.A4.96.E9.83.A8.E9.93.BE.E6.8E.A5"></span>外部链接</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E9%93%81%E6%B0%B0%E5%8C%96%E9%92%BE&action=edit&section=11" title="编辑章节：外部链接"><span>编辑</span></a><span 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href="/wiki/Template:%E9%89%80%E5%8C%96%E5%90%88%E7%89%A9" title="Template:鉀化合物"><abbr title="查看该模板">查</abbr></a></li><li class="nv-talk"><a href="/wiki/Template_talk:%E9%89%80%E5%8C%96%E5%90%88%E7%89%A9" title="Template talk:鉀化合物"><abbr title="讨论该模板">论</abbr></a></li><li class="nv-edit"><a href="/wiki/Special:%E7%BC%96%E8%BE%91%E9%A1%B5%E9%9D%A2/Template:%E9%89%80%E5%8C%96%E5%90%88%E7%89%A9" title="Special:编辑页面/Template:鉀化合物"><abbr title="编辑该模板">编</abbr></a></li></ul></div><div id="钾化合物" style="font-size:110%;margin:0 5em"><a href="/wiki/%E9%92%BE" title="钾">钾</a>化合物</div></th></tr><tr><th scope="row" class="navbox-group" style="width:1%">稀有氣體、IA、IIA</th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E6%B0%A2%E5%8C%96%E9%92%BE" title="氢化钾">KH</a></li> <li><a href="/wiki/%E9%92%BE%E9%92%A0%E5%90%88%E9%87%91" class="mw-redirect" title="钾钠合金">KNa</a></li> <li><a href="/wiki/%E9%AB%98%E6%B0%99%E9%85%B8%E9%92%BE" title="高氙酸钾">K<sub>4</sub>XeO<sub>6</sub></a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">硼族、碳族</th><td class="navbox-list-with-group navbox-list navbox-even hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E5%81%8F%E7%A1%BC%E9%85%B8%E9%92%BE" title="偏硼酸钾">KBO<sub>2</sub></a></li> <li><a href="/wiki/%E6%B0%9F%E7%A1%BC%E9%85%B8%E9%92%BE" title="氟硼酸钾">KBF<sub>4</sub></a></li> <li><a href="/wiki/%E7%A1%BC%E6%B0%A2%E5%8C%96%E9%92%BE" title="硼氢化钾">KBH<sub>4</sub></a></li> <li><a href="/wiki/%E4%B8%89%E5%90%A1%E5%94%91%E5%9F%BA%E7%A1%BC%E6%B0%A2%E5%8C%96%E9%92%BE" title="三吡唑基硼氢化钾">K[BHC<sub>9</sub>H<sub>9</sub>N<sub>6</sub>]</a></li> <li><a href="/wiki/%E4%B8%89(3,5-%E4%BA%8C%E7%94%B2%E5%9F%BA-1-%E5%90%A1%E5%94%91%E5%9F%BA)%E7%A1%BC%E6%B0%A2%E5%8C%96%E9%92%BE" title="三(3,5-二甲基-1-吡唑基)硼氢化钾">K[BHC<sub>15</sub>H<sub>21</sub>N<sub>6</sub>]</a></li> <li><span class="ilh-all" data-orig-title="硼酸铝钾" data-lang-code="en" data-lang-name="英语" data-foreign-title="Potassium aluminium borate"><span class="ilh-page"><a href="/w/index.php?title=%E7%A1%BC%E9%85%B8%E9%93%9D%E9%92%BE&action=edit&redlink=1" class="new" title="硼酸铝钾（页面不存在）">K<sub>2</sub>Al<sub>2</sub>B<sub>2</sub>O<sub>7</sub></a></span><span class="noprint ilh-comment">（<span class="ilh-lang">英语</span><span class="ilh-colon">：</span><span class="ilh-link"><a href="https://en.wikipedia.org/wiki/Potassium_aluminium_borate" class="extiw" title="en:Potassium aluminium borate"><span lang="en" dir="auto">Potassium aluminium borate</span></a></span>）</span></span></li> <li><a href="/wiki/%E9%93%9D%E9%85%B8%E9%92%BE" title="铝酸钾">KAlO<sub>2</sub></a></li> <li><a href="/wiki/%E5%85%AB%E7%A2%B3%E5%8C%96%E9%92%BE" title="八碳化钾">KC<sub>8</sub></a></li> <li><a href="/wiki/%E4%BA%8C%E5%8D%81%E5%9B%9B%E7%A2%B3%E5%8C%96%E9%92%BE" title="二十四碳化钾">KC<sub>24</sub></a></li> <li><a href="/wiki/%E7%94%B2%E5%9F%BA%E9%92%BE" title="甲基钾">KCH<sub>3</sub></a></li> <li><a href="/wiki/%E7%A2%B3%E9%85%B8%E9%92%BE" title="碳酸钾">K<sub>2</sub>CO<sub>3</sub></a></li> <li><a href="/wiki/%E7%A2%B3%E9%85%B8%E6%B0%A2%E9%92%BE" title="碳酸氢钾">KHCO<sub>3</sub></a></li> <li><a href="/wiki/%E7%A1%85%E4%B8%89%E6%B0%A2%E5%8C%96%E9%92%BE" title="硅三氢化钾">KSiH<sub>3</sub></a></li> <li><a href="/wiki/%E7%A1%85%E9%85%B8%E9%92%BE" title="硅酸钾">K<sub>2</sub>SiO<sub>3</sub></a></li> <li><a href="/wiki/%E6%B0%9F%E7%A1%85%E9%85%B8%E9%92%BE" title="氟硅酸钾">K<sub>2</sub>SiF<sub>6</sub></a></li> <li><a href="/wiki/%E5%85%AD%E6%B0%9F%E9%94%97%E9%85%B8%E9%92%BE" title="六氟锗酸钾">K<sub>2</sub>GeF<sub>6</sub></a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">氮族</th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E6%B0%AE%E5%8C%96%E9%92%BE" title="氮化钾">K<sub>3</sub>N</a></li> <li><a href="/wiki/%E7%96%8A%E6%B0%AE%E5%8C%96%E9%89%80" title="疊氮化鉀">KN<sub>3</sub></a></li> <li><a href="/wiki/%E6%B0%A8%E5%9F%BA%E9%89%80" title="氨基鉀">KNH<sub>2</sub></a></li> <li><a href="/wiki/%E4%BA%8C(%E4%B8%89%E7%94%B2%E5%9F%BA%E7%A1%85%E5%9F%BA)%E6%B0%A8%E5%9F%BA%E9%92%BE" title="二(三甲基硅基)氨基钾">K[N(SiMe<sub>3</sub>)<sub>2</sub>]</a></li> <li><a href="/wiki/%E4%BA%9A%E7%A1%9D%E9%85%B8%E9%92%BE" title="亚硝酸钾">KNO<sub>2</sub></a></li> <li><a href="/wiki/%E7%A1%9D%E9%85%B8%E9%92%BE" title="硝酸钾">KNO<sub>3</sub></a></li> <li><a href="/wiki/%E7%A3%B7%E5%8C%96%E9%92%BE" title="磷化钾">K<sub>3</sub>P</a></li> <li><span class="ilh-all" data-orig-title="亚磷酸钾" data-lang-code="ru" data-lang-name="俄语" data-foreign-title="Фосфит калия"><span class="ilh-page"><a href="/w/index.php?title=%E4%BA%9A%E7%A3%B7%E9%85%B8%E9%92%BE&action=edit&redlink=1" class="new" title="亚磷酸钾（页面不存在）">K<sub>2</sub>HPO<sub>3</sub></a></span><span class="noprint ilh-comment">（<span class="ilh-lang">俄语</span><span class="ilh-colon">：</span><span class="ilh-link"><a href="https://ru.wikipedia.org/wiki/%D0%A4%D0%BE%D1%81%D1%84%D0%B8%D1%82_%D0%BA%D0%B0%D0%BB%D0%B8%D1%8F" class="extiw" title="ru:Фосфит калия"><span lang="ru" dir="auto">Фосфит калия</span></a></span>）</span></span></li> <li><a href="/wiki/%E4%BA%9A%E7%A3%B7%E9%85%B8%E6%B0%A2%E9%92%BE" title="亚磷酸氢钾">KH<sub>2</sub>PO<sub>3</sub></a></li> <li><a href="/wiki/%E7%A3%B7%E9%85%B8%E9%89%80" title="磷酸鉀">K<sub>3</sub>PO<sub>4</sub></a></li> <li><a href="/wiki/%E7%A3%B7%E9%85%B8%E6%B0%AB%E4%BA%8C%E9%89%80" title="磷酸氫二鉀">K<sub>2</sub>HPO<sub>4</sub></a></li> <li><a href="/wiki/%E7%A3%B7%E9%85%B8%E4%BA%8C%E6%B0%A2%E9%92%BE" class="mw-redirect" title="磷酸二氢钾">KH<sub>2</sub>PO<sub>4</sub></a></li> <li><a href="/wiki/%E5%85%AD%E6%B0%9F%E7%A3%B7%E9%85%B8%E9%92%BE" title="六氟磷酸钾">KPF<sub>6</sub></a></li> <li><a href="/w/index.php?title=%E5%9B%9B%E7%A1%AB%E4%BB%A3%E7%A3%B7%E9%85%B8%E9%92%BE&action=edit&redlink=1" class="new" title="四硫代磷酸钾（页面不存在）">K<sub>3</sub>PS<sub>4</sub></a></li> <li><a href="/wiki/%E5%9B%9B%E7%A1%92%E4%BB%A3%E7%A3%B7%E9%85%B8%E9%92%BE" title="四硒代磷酸钾">K<sub>3</sub>PSe<sub>4</sub></a></li> <li><a href="/w/index.php?title=%E7%A0%B7%E5%8C%96%E9%92%BE&action=edit&redlink=1" class="new" title="砷化钾（页面不存在）">K<sub>3</sub>As</a></li> <li><a href="/wiki/%E4%BA%9A%E7%A0%B7%E9%85%B8%E9%92%BE" title="亚砷酸钾">KAsO<sub>2</sub></a></li> <li><a href="/wiki/%E7%A0%B7%E9%85%B8%E4%BA%8C%E6%B0%A2%E9%92%BE" title="砷酸二氢钾">KH<sub>2</sub>AsO<sub>4</sub></a></li> <li><a href="/w/index.php?title=%E9%94%91%E5%8C%96%E9%92%BE&action=edit&redlink=1" class="new" title="锑化钾（页面不存在）">K<sub>3</sub>Sb</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">氧族</th><td class="navbox-list-with-group navbox-list navbox-even hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E6%B0%A7%E5%8C%96%E9%89%80" title="氧化鉀">K<sub>2</sub>O</a></li> <li><a href="/wiki/%E6%B0%A2%E6%B0%A7%E5%8C%96%E9%92%BE" title="氢氧化钾">KOH</a></li> <li><a href="/wiki/%E8%BF%87%E6%B0%A7%E5%8C%96%E9%92%BE" title="过氧化钾">K<sub>2</sub>O<sub>2</sub></a></li> <li><a href="/wiki/%E8%B6%85%E6%B0%A7%E5%8C%96%E9%92%BE" title="超氧化钾">KO<sub>2</sub></a></li> <li><a href="/wiki/%E8%87%AD%E6%B0%A7%E5%8C%96%E9%92%BE" title="臭氧化钾">KO<sub>3</sub></a></li> <li><a href="/wiki/%E7%A1%AB%E6%B0%A2%E5%8C%96%E9%92%BE" title="硫氢化钾">KHS</a></li> <li><a href="/wiki/%E4%BA%9A%E7%A1%AB%E9%85%B8%E6%B0%A2%E9%92%BE" title="亚硫酸氢钾">KHSO<sub>3</sub></a></li> <li><a href="/wiki/%E7%A1%AB%E9%85%B8%E6%B0%A2%E9%92%BE" title="硫酸氢钾">KHSO<sub>4</sub></a></li> <li><a href="/wiki/%E7%A1%AB%E5%8C%96%E9%92%BE" title="硫化钾">K<sub>2</sub>S</a></li> <li><a href="/wiki/%E4%BA%9A%E7%A1%AB%E9%85%B8%E9%92%BE" title="亚硫酸钾">K<sub>2</sub>SO<sub>3</sub></a></li> <li><a href="/wiki/%E7%A1%AB%E9%85%B8%E9%92%BE" title="硫酸钾">K<sub>2</sub>SO<sub>4</sub></a></li> <li><a href="/wiki/%E8%BF%87%E4%B8%80%E7%A1%AB%E9%85%B8%E9%92%BE" class="mw-redirect" title="过一硫酸钾">K<sub>2</sub>SO<sub>5</sub></a></li> <li><a href="/wiki/%E7%A1%AB%E4%BB%A3%E7%A1%AB%E9%85%B8%E9%92%BE" title="硫代硫酸钾">K<sub>2</sub>S<sub>2</sub>O<sub>3</sub></a></li> <li><a href="/wiki/%E7%84%A6%E4%BA%9A%E7%A1%AB%E9%85%B8%E9%92%BE" title="焦亚硫酸钾">K<sub>2</sub>S<sub>2</sub>O<sub>5</sub></a></li> <li><a href="/wiki/%E7%84%A6%E7%A1%AB%E9%85%B8%E9%92%BE" title="焦硫酸钾">K<sub>2</sub>S<sub>2</sub>O<sub>7</sub></a></li> <li><a href="/wiki/%E8%BF%87%E7%A1%AB%E9%85%B8%E9%92%BE" title="过硫酸钾">K<sub>2</sub>S<sub>2</sub>O<sub>8</sub></a></li> <li><a href="/wiki/%E4%BA%9A%E7%A1%92%E9%85%B8%E9%92%BE" title="亚硒酸钾">K<sub>2</sub>SeO<sub>3</sub></a></li> <li><a href="/wiki/%E7%A1%92%E9%85%B8%E9%92%BE" title="硒酸钾">K<sub>2</sub>SeO<sub>4</sub></a></li> <li><a href="/wiki/%E7%A2%B2%E5%8C%96%E9%89%80" title="碲化鉀"><span class="chemf nowrap">K<span style="line-height:1.2em;text-indent:0em;display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;font-size:70%;text-align:left"><br />2</span>Te</span></a></li> <li><a href="/wiki/%E4%BA%9A%E7%A2%B2%E9%85%B8%E9%92%BE" title="亚碲酸钾"><span class="chemf nowrap">K<span style="line-height:1.2em;text-indent:0em;display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;font-size:70%;text-align:left"><br />2</span>TeO<span style="line-height:1.2em;text-indent:0em;display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;font-size:70%;text-align:left"><br />3</span></span></a></li> <li><a href="/wiki/%E7%A2%B2%E9%85%B8%E9%92%BE" title="碲酸钾"><span class="chemf nowrap">K<span style="line-height:1.2em;text-indent:0em;display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;font-size:70%;text-align:left"><br />2</span>TeO<span style="line-height:1.2em;text-indent:0em;display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;font-size:70%;text-align:left"><br />4</span></span></a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">卤素、拟卤素</th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E6%B0%9F%E5%8C%96%E9%92%BE" title="氟化钾">KF</a></li> <li><a href="/wiki/%E6%B0%9F%E5%8C%96%E6%B0%A2%E9%92%BE" title="氟化氢钾">KHF<sub>2</sub></a></li> <li><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%92%BE" title="氯化钾">KCl</a></li> <li><a href="/wiki/%E6%AC%A1%E6%B0%AF%E9%85%B8%E9%92%BE" title="次氯酸钾">KClO</a></li> <li><a href="/wiki/%E4%BA%9A%E6%B0%AF%E9%85%B8%E9%92%BE" title="亚氯酸钾">KClO<sub>2</sub></a></li> <li><a href="/wiki/%E6%B0%AF%E9%85%B8%E9%92%BE" title="氯酸钾">KClO<sub>3</sub></a></li> <li><a href="/wiki/%E9%AB%98%E6%B0%AF%E9%85%B8%E9%92%BE" title="高氯酸钾">KClO<sub>4</sub></a></li> <li><a href="/wiki/%E6%BA%B4%E5%8C%96%E9%92%BE" title="溴化钾">KBr</a></li> <li><a href="/wiki/%E6%BA%B4%E9%85%B8%E9%92%BE" title="溴酸钾">KBrO<sub>3</sub></a></li> <li><a href="/wiki/%E7%A2%98%E5%8C%96%E9%92%BE" title="碘化钾">KI</a></li> <li><a href="/wiki/%E7%A2%98%E9%85%B8%E9%92%BE" title="碘酸钾">KIO<sub>3</sub></a></li> <li><a href="/w/index.php?title=%E7%A2%98%E9%85%B8%E6%B0%A2%E9%92%BE&action=edit&redlink=1" class="new" title="碘酸氢钾（页面不存在）">KH(IO<sub>3</sub>)<sub>2</sub></a></li> <li><a href="/wiki/%E9%AB%98%E7%A2%98%E9%85%B8%E9%89%80" title="高碘酸鉀">KIO<sub>4</sub></a></li> <li><a href="/wiki/%E6%B0%B0%E5%8C%96%E9%92%BE" title="氰化钾">KCN</a></li> <li><a href="/wiki/%E6%B0%B0%E9%85%B8%E9%92%BE" title="氰酸钾">KOCN</a></li> <li><a href="/wiki/%E9%9B%B7%E9%85%B8%E9%92%BE" title="雷酸钾">KCNO</a></li> <li><a href="/wiki/%E7%A1%AB%E6%B0%B0%E9%85%B8%E9%92%BE" title="硫氰酸钾">KSCN</a></li> <li><a href="/wiki/%E7%A1%92%E6%B0%B0%E9%85%B8%E9%92%BE" title="硒氰酸钾">KSeCN</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">副族金属</th><td class="navbox-list-with-group navbox-list navbox-even hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E6%B0%9F%E9%94%86%E9%85%B8%E9%92%BE" title="氟锆酸钾">K<sub>2</sub>ZrF<sub>6</sub></a></li> <li><a href="/wiki/%E4%BA%8C%E7%A1%AB%E4%BB%A3%E4%BA%9A%E9%93%AC%E9%85%B8%E9%92%BE" title="二硫代亚铬酸钾">KCrS<sub>2</sub></a></li> <li><a href="/wiki/%E4%BA%8C%E7%A1%92%E4%BB%A3%E4%BA%9A%E9%93%AC%E9%85%B8%E9%92%BE" title="二硒代亚铬酸钾">KCrSe<sub>2</sub></a></li> <li><a href="/wiki/%E9%93%AC%E9%85%B8%E9%92%BE" title="铬酸钾">K<sub>2</sub>CrO<sub>4</sub></a></li> <li><a href="/wiki/%E5%9B%9B%E8%BF%87%E6%B0%A7%E9%93%AC(V)%E9%85%B8%E9%92%BE" title="四过氧铬(V)酸钾">K<sub>3</sub>Cr(O<sub>2</sub>)<sub>4</sub></a></li> <li><a href="/wiki/%E9%87%8D%E9%93%AC%E9%85%B8%E9%92%BE" title="重铬酸钾">K<sub>2</sub>Cr<sub>2</sub>O<sub>7</sub></a></li> <li><a href="/wiki/%E5%85%AD%E6%B0%B0%E5%90%88%E9%93%AC(III)%E9%85%B8%E9%92%BE" title="六氰合铬(III)酸钾">K<sub>3</sub>[Cr(CN)<sub>6</sub>]</a></li> <li><a href="/wiki/%E9%AB%98%E9%93%81%E9%85%B8%E9%92%BE" title="高铁酸钾">K<sub>2</sub>FeO<sub>4</sub></a></li> <li><a href="/wiki/%E4%BA%9A%E9%93%81%E6%B0%B0%E5%8C%96%E9%92%BE" title="亚铁氰化钾">K<sub>4</sub>[Fe(CN)<sub>6</sub>]</a></li> <li><a class="mw-selflink selflink">K<sub>3</sub>[Fe(CN)<sub>6</sub>]</a></li> <li><a href="/wiki/%E5%85%AD%E6%B0%B0%E5%90%88%E9%92%B4(III)%E9%85%B8%E9%92%BE" title="六氰合钴(III)酸钾">K<sub>3</sub>[Co(CN)<sub>6</sub>]</a></li> <li><a href="/wiki/%E5%9B%9B%E6%B0%B0%E5%90%88%E9%95%8D(II)%E9%85%B8%E9%92%BE" title="四氰合镍(II)酸钾">K<sub>2</sub>[Ni(CN)<sub>4</sub>]</a></li> <li><a href="/wiki/%E5%9B%9B%E6%B0%B0%E5%90%88%E9%95%8D(I)%E9%85%B8%E9%92%BE" title="四氰合镍(I)酸钾">K<sub>3</sub>[Ni(CN)<sub>4</sub>]</a></li> <li><a href="/wiki/%E5%9B%9B%E6%B0%B0%E5%90%88%E9%95%8D(0)%E9%85%B8%E9%92%BE" title="四氰合镍(0)酸钾">K<sub>4</sub>[Ni(CN)<sub>4</sub>]</a></li> <li><a href="/wiki/%E5%85%AD%E6%B0%B0%E5%90%88%E4%BA%8C%E9%95%8D(I)%E9%85%B8%E9%92%BE" title="六氰合二镍(I)酸钾">K<sub>4</sub>[Ni<sub>2</sub>(CN)<sub>6</sub>]</a></li> <li><a href="/wiki/%E9%94%B0%E9%85%B8%E9%92%BE" title="锰酸钾">K<sub>2</sub>MnO<sub>4</sub></a></li> <li><a href="/wiki/%E9%AB%98%E9%94%B0%E9%85%B8%E9%92%BE" title="高锰酸钾">KMnO<sub>4</sub></a></li> <li><a href="/wiki/%E9%AB%98%E9%93%81%E9%85%B8%E9%92%BE" title="高铁酸钾">K<sub>2</sub>FeO<sub>4</sub></a></li> <li><a href="/wiki/%E5%85%AD%E6%B0%9F%E5%90%88%E9%93%9C(III)%E9%85%B8%E9%92%BE" title="六氟合铜(III)酸钾">K<sub>3</sub>CuF<sub>6</sub></a></li> <li><a href="/wiki/%E5%85%AB%E6%B0%AF%E5%90%88%E4%BA%8C%E9%92%BC%E9%85%B8%E9%92%BE" title="八氯合二钼酸钾">K<sub>4</sub>Mo<sub>2</sub>Cl<sub>8</sub></a></li> <li><a href="/wiki/%E6%B0%AF%E4%BA%9A%E9%93%82%E9%85%B8%E9%92%BE" title="氯亚铂酸钾">K<sub>2</sub>PtCl<sub>4</sub></a></li> <li><a href="/wiki/%E6%B0%AF%E9%93%82%E9%85%B8%E9%92%BE" title="氯铂酸钾">K<sub>2</sub>PtCl<sub>6</sub></a></li> <li><a href="/wiki/%E6%B0%B0%E5%8C%96%E9%8A%80%E9%89%80" title="氰化銀鉀">K[Ag(CN)<sub>2</sub>]</a></li> <li><a href="/wiki/%E5%85%AB%E6%B0%AF%E5%90%88%E4%BA%8C%E9%93%BC%E9%85%B8%E9%92%BE" title="八氯合二铼酸钾">K<sub>2</sub>Re<sub>2</sub>Cl<sub>8</sub></a></li> <li><a href="/wiki/%E5%9B%9B%E6%B0%AF%E5%90%88%E9%92%AF(II)%E9%85%B8%E9%92%BE" title="四氯合钯(II)酸钾">K<sub>2</sub>[PdCl<sub>4</sub>]</a></li> <li><a href="/wiki/%E5%85%AD%E6%B0%AF%E5%90%88%E9%92%AF(IV)%E9%85%B8%E9%92%BE" title="六氯合钯(IV)酸钾">K<sub>2</sub>[PdCl<sub>6</sub>]</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">有机酸盐</th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E7%94%B2%E9%85%B8%E9%92%BE" title="甲酸钾">KHCO<sub>2</sub></a></li> <li><a href="/wiki/%E9%85%92%E7%9F%B3%E9%85%B8%E9%94%91%E9%92%BE" title="酒石酸锑钾">K<sub>2</sub>Sb<sub>2</sub>(C<sub>4</sub>H<sub>2</sub>O<sub>6</sub>)<sub>2</sub></a></li> <li><a href="/wiki/%E4%B9%99%E9%85%B8%E9%92%BE" title="乙酸钾">KC<sub>2</sub>H<sub>3</sub>O<sub>2</sub></a></li> <li><a href="/wiki/%E4%B8%89%E6%B0%9F%E4%B9%99%E9%85%B8%E9%92%BE" title="三氟乙酸钾">KC<sub>2</sub>F<sub>3</sub>O<sub>2</sub></a></li> <li><a href="/w/index.php?title=%E4%B8%89%E6%B0%AF%E4%B9%99%E9%85%B8%E9%92%BE&action=edit&redlink=1" class="new" title="三氯乙酸钾（页面不存在）">KC<sub>2</sub>Cl<sub>3</sub>O<sub>2</sub></a></li> <li><a href="/wiki/%E4%BA%8C%E6%B0%9F%E6%BA%B4%E4%B9%99%E9%85%B8%E9%92%BE" title="二氟溴乙酸钾">KC<sub>2</sub>F<sub>2</sub>BrO<sub>2</sub></a></li> <li><a href="/wiki/%E4%B8%99%E9%85%B8%E9%92%BE" title="丙酸钾">KC<sub>3</sub>H<sub>5</sub>O<sub>2</sub></a></li> <li><a href="/w/index.php?title=%E4%B8%81%E9%85%B8%E9%92%BE&action=edit&redlink=1" class="new" title="丁酸钾（页面不存在）">KC<sub>4</sub>H<sub>7</sub>O<sub>2</sub></a></li> <li><a href="/w/index.php?title=%E8%8B%AF%E7%94%B2%E9%85%B8%E9%92%BE&action=edit&redlink=1" class="new" title="苯甲酸钾（页面不存在）">KC<sub>7</sub>H<sub>5</sub>O<sub>2</sub></a></li> <li><a href="/wiki/%E8%8D%89%E9%85%B8%E9%92%BE" title="草酸钾">K<sub>2</sub>C<sub>2</sub>O<sub>4</sub></a></li> <li><a href="/wiki/%E8%8D%89%E9%85%B8%E6%B0%A2%E9%92%BE" title="草酸氢钾">KHC<sub>2</sub>O<sub>4</sub></a></li> <li><a href="/wiki/%E8%8D%89%E9%85%B8%E9%93%81%E9%92%BE" title="草酸铁钾">K<sub>3</sub>[Fe(C<sub>2</sub>O<sub>4</sub>)<sub>3</sub>]</a></li></ul> </div></td></tr></tbody></table></div> <div class="navbox-styles"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r84265675"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r84261037"></div><div role="navigation" class="navbox" aria-labelledby="六氰合铁(II/III)酸盐" style="padding:3px"><table class="nowraplinks mw-collapsible mw-collapsed navbox-inner" style="border-spacing:0;background:transparent;color:inherit"><tbody><tr><th scope="col" class="collapsible-title navbox-title" colspan="2"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r84265675"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r84244141"><div class="navbar plainlinks hlist navbar-mini"><ul><li class="nv-view"><a href="/wiki/Template:%E9%93%81%E6%B0%B0%E9%85%B8%E7%9B%90" title="Template:铁氰酸盐"><abbr title="查看该模板">查</abbr></a></li><li class="nv-talk"><a href="/wiki/Template_talk:%E9%93%81%E6%B0%B0%E9%85%B8%E7%9B%90" title="Template talk:铁氰酸盐"><abbr title="讨论该模板">论</abbr></a></li><li class="nv-edit"><a href="/wiki/Special:%E7%BC%96%E8%BE%91%E9%A1%B5%E9%9D%A2/Template:%E9%93%81%E6%B0%B0%E9%85%B8%E7%9B%90" title="Special:编辑页面/Template:铁氰酸盐"><abbr title="编辑该模板">编</abbr></a></li></ul></div><div id="六氰合铁(II/III)酸盐" style="font-size:110%;margin:0 5em"><b>六氰合铁(II/III)酸盐</b></div></th></tr><tr><td colspan="2" class="navbox-list navbox-odd hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <table style="width:100%;margin:0 auto;"> <tbody><tr style="background-color:mistyrose;vertical-align:top"> <td><a href="/wiki/%E5%85%AD%E6%B0%B0%E5%90%88%E9%93%81(II)%E9%85%B8" title="六氰合铁(II)酸"><span class="nowrap">H<sub>4</sub>[HCF]</span></a><br /><a href="/wiki/%E5%85%AD%E6%B0%B0%E5%90%88%E9%93%81(III)%E9%85%B8" title="六氰合铁(III)酸"><span class="nowrap">H<sub>3</sub>[HCF]</span></a> </td> <td style="background-color:white;border:none"> </td> <td style="background-color:white;border:none" colspan="10" rowspan="3"> </td> <td style="background-color:white;border:none" colspan="5"> </td> <td>He </td></tr> <tr style="background-color:mistyrose;vertical-align:top"> <td><a href="/wiki/%E4%BA%9A%E9%93%81%E6%B0%B0%E9%85%B8%E9%94%82" title="亚铁氰酸锂"><span class="nowrap">Li<sub>4</sub>[HCF]</span></a><br /><a href="/w/index.php?title=%E9%93%81%E6%B0%B0%E9%85%B8%E9%94%82&action=edit&redlink=1" class="new" title="铁氰酸锂（页面不存在）"><span class="nowrap">Li<sub>3</sub>[HCF]</span></a> </td> <td>Be </td> <td>B </td> <td>C </td> <td><a href="/wiki/%E4%BA%9A%E9%93%81%E6%B0%B0%E9%85%B8%E9%93%B5" title="亚铁氰酸铵"><span class="nowrap">(NH<sub>4</sub>)<sub>4</sub>[HCF]</span></a><br /><a href="/wiki/%E9%93%81%E6%B0%B0%E9%85%B8%E9%93%B5" title="铁氰酸铵"><span class="nowrap">(NH<sub>4</sub>)<sub>3</sub>[HCF]</span></a> </td> <td>O </td> <td>F </td> <td>Ne </td></tr> <tr style="background-color:mistyrose;vertical-align:top"> <td><a href="/wiki/%E4%BA%9A%E9%93%81%E6%B0%B0%E5%8C%96%E9%92%A0" title="亚铁氰化钠"><span class="nowrap">Na<sub>4</sub>[HCF]</span></a><br /><a href="/w/index.php?title=%E9%93%81%E6%B0%B0%E9%85%B8%E9%92%A0&action=edit&redlink=1" class="new" title="铁氰酸钠（页面不存在）"><span class="nowrap">Na<sub>3</sub>[HCF]</span></a> </td> <td>Mg </td> <td>Al </td> <td>Si </td> <td>P </td> <td>S </td> <td>Cl </td> <td>Ar </td></tr> <tr style="background-color:mistyrose;vertical-align:top"> <td><a href="/wiki/%E4%BA%9A%E9%93%81%E6%B0%B0%E5%8C%96%E9%92%BE" title="亚铁氰化钾"><span class="nowrap">K<sub>4</sub>[HCF]</span></a><br /><a class="mw-selflink selflink"><span class="nowrap">K<sub>3</sub>[HCF]</span></a> </td> <td><a href="/w/index.php?title=%E4%BA%9A%E9%93%81%E6%B0%B0%E9%85%B8%E9%92%99&action=edit&redlink=1" class="new" title="亚铁氰酸钙（页面不存在）"><span class="nowrap">Ca<sub>2</sub>[HCF]</span></a><br /><a href="/w/index.php?title=%E9%93%81%E6%B0%B0%E9%85%B8%E9%92%99&action=edit&redlink=1" class="new" title="铁氰酸钙（页面不存在）"><span class="nowrap">Ca<sub>3</sub>[HCF]<sub>2</sub></span></a> </td> <td><a href="/wiki/%E4%BA%9A%E9%93%81%E6%B0%B0%E9%85%B8%E9%92%AA" title="亚铁氰酸钪"><span class="nowrap">Sc<sub>4</sub>[HCF]<sub>3</sub></span></a><br /><a href="/w/index.php?title=%E9%93%81%E6%B0%B0%E9%85%B8%E9%92%AA&action=edit&redlink=1" class="new" title="铁氰酸钪（页面不存在）"><span class="nowrap">Sc[HCF]</span></a> </td> <td>Ti </td> <td><a href="/wiki/%E5%85%AD%E6%B0%B0%E5%90%88%E9%93%81(II)%E9%85%B8%E9%92%92(IV)%E9%85%B0" title="六氰合铁(II)酸钒(IV)酰"><span class="nowrap">(VO)<sub>2</sub>[HCF]</span></a> </td> <td>Cr </td> <td><a href="/wiki/%E4%BA%9A%E9%93%81%E6%B0%B0%E9%85%B8%E9%94%B0" title="亚铁氰酸锰"><span class="nowrap">Mn<sub>2</sub>[HCF]</span></a><br /><a href="/wiki/%E9%93%81%E6%B0%B0%E9%85%B8%E9%94%B0" title="铁氰酸锰"><span class="nowrap">Mn<sub>3</sub>[HCF]<sub>2</sub></span></a> </td> <td><a href="/wiki/%E6%99%AE%E9%B2%81%E5%A3%AB%E8%93%9D" title="普鲁士蓝"><span class="nowrap">KFe[Fe(CN)<sub>6</sub>]</span></a> </td> <td><a href="/wiki/%E4%BA%9A%E9%93%81%E6%B0%B0%E9%85%B8%E9%92%B4" title="亚铁氰酸钴"><span class="nowrap">Co<sub>2</sub>[HCF]</span></a><br /><a href="/w/index.php?title=%E9%93%81%E6%B0%B0%E9%85%B8%E9%92%B4&action=edit&redlink=1" class="new" title="铁氰酸钴（页面不存在）"><span class="nowrap">Co<sub>3</sub>[HCF]<sub>2</sub></span></a> </td> <td><a href="/wiki/%E4%BA%9A%E9%93%81%E6%B0%B0%E9%85%B8%E9%95%8D" title="亚铁氰酸镍"><span class="nowrap">Ni<sub>2</sub>[HCF]</span></a><br /><a href="/w/index.php?title=%E9%93%81%E6%B0%B0%E9%85%B8%E9%95%8D&action=edit&redlink=1" class="new" title="铁氰酸镍（页面不存在）"><span class="nowrap">Ni<sub>3</sub>[HCF]<sub>2</sub></span></a> </td> <td><a href="/wiki/%E4%BA%9A%E9%93%81%E6%B0%B0%E9%85%B8%E9%93%9C" title="亚铁氰酸铜"><span class="nowrap">Cu<sub>2</sub>[HCF]</span></a> </td> <td>Zn </td> <td>Ga </td> <td>Ge </td> <td>As </td> <td>Se </td> <td>Br </td> <td>Kr </td></tr> <tr style="background-color:mistyrose;vertical-align:top"> <td><a href="/w/index.php?title=%E4%BA%9A%E9%93%81%E6%B0%B0%E9%85%B8%E9%93%B7&action=edit&redlink=1" class="new" title="亚铁氰酸铷（页面不存在）"><span class="nowrap">Rb<sub>4</sub>[HCF]</span></a><br /><a href="/w/index.php?title=%E9%93%81%E6%B0%B0%E9%85%B8%E9%93%B7&action=edit&redlink=1" class="new" title="铁氰酸铷（页面不存在）"><span class="nowrap">Rb<sub>3</sub>[HCF]</span></a> </td> <td>Sr </td> <td>Y </td> <td>Zr </td> <td>Nb </td> <td>Mo </td> <td>Tc </td> <td>Ru </td> <td>Rh </td> <td>Pd </td> <td>Ag </td> <td>Cd </td> <td>In </td> <td>Sn </td> <td>Sb </td> <td>Te </td> <td>I </td> <td>Xe </td></tr> <tr style="background-color:mistyrose;vertical-align:top"> <td><a href="/wiki/%E4%BA%9A%E9%93%81%E6%B0%B0%E9%85%B8%E9%93%AF" title="亚铁氰酸铯">Cs<sub>4</sub>[HCF]</a><br /><a href="/wiki/%E9%93%81%E6%B0%B0%E9%85%B8%E9%93%AF" title="铁氰酸铯">Cs<sub>3</sub>[HCF]</a> </td> <td><a href="/w/index.php?title=%E4%BA%9A%E9%93%81%E6%B0%B0%E9%85%B8%E9%92%A1&action=edit&redlink=1" class="new" title="亚铁氰酸钡（页面不存在）"><span class="nowrap">Ba<sub>2</sub>[HCF]</span></a><br /><a href="/w/index.php?title=%E9%93%81%E6%B0%B0%E9%85%B8%E9%92%A1&action=edit&redlink=1" class="new" title="铁氰酸钡（页面不存在）"><span class="nowrap">Ba<sub>3</sub>[HCF]<sub>2</sub></span></a> </td> <td style="background-color:white;border:none"><span title="镧系元素" style="font-family: Courier, monospace;">镧系</span> </td> <td>Hf </td> <td>Ta </td> <td>W </td> <td>Re </td> <td>Os </td> <td>Ir </td> <td>Pt </td> <td>Au </td> <td>Hg </td> <td>Tl </td> <td>Pb </td> <td>Bi </td> <td>Po </td> <td>At </td> <td>Rn </td></tr> <tr style="background-color:mistyrose;vertical-align:top"> <td>Fr </td> <td>Ra </td> <td style="background-color:white;border:none"><span title="锕系元素" style="font-family: Courier, monospace;">锕系</span> </td> <td>Rf </td> <td>Db </td> <td>Sg </td> <td>Bh </td> <td>Hs </td> <td>Mt </td> <td>Ds </td> <td>Rg </td> <td>Cn </td> <td>Nh </td> <td>Fl </td> <td>Mc </td> <td>Lv </td> <td>Ts </td> <td>Og </td></tr> <tr> <td style="background-color:white;border:none" rowspan="3"> </td> <td style="background-color:white;border:none" colspan="1"> </td> <td style="background-color:white;border:none">↓ </td> <td style="background-color:white;border:none" colspan="14"> </td> <td style="background-color:white;border:none" rowspan="3"> </td></tr> <tr style="background-color:mistyrose;vertical-align:top"> <td style="background-color:white;border:none"><span title="镧系元素" style="font-family: Courier, monospace;">镧系</span> </td> <td><a href="/wiki/%E9%93%81%E6%B0%B0%E9%85%B8%E9%95%A7" title="铁氰酸镧"><span class="nowrap">La[HCF]</span></a> </td> <td><a href="/w/index.php?title=%E9%93%81%E6%B0%B0%E9%85%B8%E9%93%88(III)&action=edit&redlink=1" class="new" title="铁氰酸铈(III)（页面不存在）"><span class="nowrap">Ce[HCF]</span></a> </td> <td><a href="/wiki/%E4%BA%9A%E9%93%81%E6%B0%B0%E9%85%B8%E9%95%A8%E9%92%BE" title="亚铁氰酸镨钾"><span class="nowrap">KPr[HCF]</span></a><br /><a href="/wiki/%E9%93%81%E6%B0%B0%E9%85%B8%E9%95%A8" title="铁氰酸镨"><span class="nowrap">Pr[HCF]</span></a> </td> <td><a href="/wiki/%E9%93%81%E6%B0%B0%E9%85%B8%E9%92%95" title="铁氰酸钕"><span class="nowrap">Nd[HCF]</span></a> </td> <td>Pm </td> <td><a href="/wiki/%E9%93%81%E6%B0%B0%E9%85%B8%E9%92%90" title="铁氰酸钐"><span class="nowrap">Sm[HCF]</span></a> </td> <td><a href="/wiki/%E9%93%81%E6%B0%B0%E9%85%B8%E9%93%95" title="铁氰酸铕"><span class="nowrap">Eu[HCF]</span></a> </td> <td><a href="/wiki/%E9%93%81%E6%B0%B0%E9%85%B8%E9%92%86" title="铁氰酸钆"><span class="nowrap">Gd[HCF]</span></a> </td> <td><a href="/w/index.php?title=%E9%93%81%E6%B0%B0%E9%85%B8%E9%93%BD&action=edit&redlink=1" class="new" title="铁氰酸铽（页面不存在）"><span class="nowrap">Tb[HCF]</span></a> </td> <td><a href="/wiki/%E9%93%81%E6%B0%B0%E9%85%B8%E9%95%9D" title="铁氰酸镝"><span class="nowrap">Dy[HCF]</span></a> </td> <td><a href="/w/index.php?title=%E9%93%81%E6%B0%B0%E9%85%B8%E9%92%AC&action=edit&redlink=1" class="new" title="铁氰酸钬（页面不存在）"><span class="nowrap">Ho[HCF]</span></a> </td> <td><a href="/wiki/%E9%93%81%E6%B0%B0%E9%85%B8%E9%93%92" title="铁氰酸铒"><span class="nowrap">Er[HCF]</span></a> </td> <td><a href="/w/index.php?title=%E9%93%81%E6%B0%B0%E9%85%B8%E9%93%A5&action=edit&redlink=1" class="new" title="铁氰酸铥（页面不存在）"><span class="nowrap">Tm[HCF]</span></a> </td> <td><a href="/wiki/%E4%BA%9A%E9%93%81%E6%B0%B0%E9%85%B8%E9%95%B1%E9%92%BE" title="亚铁氰酸镱钾"><span class="nowrap">KYb[HCF]</span></a><br /><a href="/w/index.php?title=%E9%93%81%E6%B0%B0%E9%85%B8%E9%95%B1&action=edit&redlink=1" class="new" title="铁氰酸镱（页面不存在）"><span class="nowrap">Yb[HCF]</span></a> </td> <td><a href="/w/index.php?title=%E9%93%81%E6%B0%B0%E9%85%B8%E9%95%A5&action=edit&redlink=1" class="new" title="铁氰酸镥（页面不存在）"><span class="nowrap">Lu[HCF]</span></a> </td></tr> <tr style="background-color:mistyrose;vertical-align:top"> <td 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