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functionalization</title> <meta name="description" content="Search results for: covalent functionalization"> <meta name="keywords" content="covalent functionalization"> <meta name="viewport" content="width=device-width, initial-scale=1, minimum-scale=1, maximum-scale=1, user-scalable=no"> <meta charset="utf-8"> <link href="https://cdn.waset.org/favicon.ico" type="image/x-icon" rel="shortcut icon"> <link href="https://cdn.waset.org/static/plugins/bootstrap-4.2.1/css/bootstrap.min.css" rel="stylesheet"> <link href="https://cdn.waset.org/static/plugins/fontawesome/css/all.min.css" rel="stylesheet"> <link href="https://cdn.waset.org/static/css/site.css?v=150220211555" rel="stylesheet"> </head> <body> <header> <div class="container"> <nav class="navbar navbar-expand-lg navbar-light"> <a class="navbar-brand" href="https://waset.org"> <img src="https://cdn.waset.org/static/images/wasetc.png" alt="Open Science Research Excellence" title="Open Science Research Excellence" /> </a> <button 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action="https://publications.waset.org/abstracts/search"> <div id="custom-search-input"> <div class="input-group"> <i class="fas fa-search"></i> <input type="text" class="search-query" name="q" placeholder="Author, Title, Abstract, Keywords" value="covalent functionalization"> <input type="submit" class="btn_search" value="Search"> </div> </div> </form> </div> </div> <div class="row mt-3"> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Commenced</strong> in January 2007</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Frequency:</strong> Monthly</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Edition:</strong> International</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Paper Count:</strong> 240</div> </div> </div> </div> <h1 class="mt-3 mb-3 text-center" style="font-size:1.6rem;">Search results for: covalent functionalization</h1> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">150</span> Very First Synthesis of Carbazole Conjugates with Efflux Pump Inhibitor as Dual Action Hybrids</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Ghazala%20Yaqub">Ghazala Yaqub</a>, <a href="https://publications.waset.org/abstracts/search?q=Zubi%20Sadiq"> Zubi Sadiq</a>, <a href="https://publications.waset.org/abstracts/search?q=Almas%20Hamid"> Almas Hamid</a>, <a href="https://publications.waset.org/abstracts/search?q=Saira%20Iqbal"> Saira Iqbal </a> </p> <p class="card-text"><strong>Abstract:</strong></p> This paper is the very first report of three dual action hybrids synthesized by covalent linkage of carbazole based novel antibacterial compounds with efflux pump inhibitors i.e., indole acetic acid/gallic acid. Novel carbazole based antibacterial compounds were prepared first and then these were covalently linked with efflux pump inhibitors which leads to the successful formation of hybrids. All prepared compounds were evaluated for their bacterial cell killing capability against Escherichia coli, Staphylococcus aureus, Pasteurella multocida and Bacillus subtilis. Compound were effective against all tested bacterial strains at different concentrations. But when these compounds were linked with efflux pump inhibitors they showed dramatic enhancement in their bacterial cell killing potential and minimum inhibitory concentration of all hybrids ranges from 7.250 µg/mL to 0.0283 µg/mL. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=antimicrobial%20assay" title="antimicrobial assay">antimicrobial assay</a>, <a href="https://publications.waset.org/abstracts/search?q=carbazole" title=" carbazole"> carbazole</a>, <a href="https://publications.waset.org/abstracts/search?q=dual%20action%20hybrids" title=" dual action hybrids"> dual action hybrids</a>, <a href="https://publications.waset.org/abstracts/search?q=efflux%20pump%20inhibitors" title=" efflux pump inhibitors"> efflux pump inhibitors</a> </p> <a href="https://publications.waset.org/abstracts/11746/very-first-synthesis-of-carbazole-conjugates-with-efflux-pump-inhibitor-as-dual-action-hybrids" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/11746.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">2104</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">149</span> Nanotechnology-Based Treatment of Klebsiella pneumoniae Infections</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Lucian%20Mocan">Lucian Mocan</a>, <a href="https://publications.waset.org/abstracts/search?q=Teodora%20Mocan"> Teodora Mocan</a>, <a href="https://publications.waset.org/abstracts/search?q=Matea%20Cristian"> Matea Cristian</a>, <a href="https://publications.waset.org/abstracts/search?q=Cornel%20Iancu"> Cornel Iancu</a> </p> <p class="card-text"><strong>Abstract:</strong></p> We present method of nanoparticle enhanced laser thermal ablation of Klebsiella pneumoniae infections, using gold nanoparticles combined with a specific growth factor and demonstrate its selective therapeutic efficacy. Ab (antibody solution) bound to GNPs (gold nanoparticles) was administered in vitro and determined the specific delivery of the nano-bioconjugate into the microorganism. The extent of necrosis was considerable following laser therapy, and at the same time, normal cells were not seriously affected. The selective photothermal ablation of the infected tissue was obtained after the selective accumulation of Ab bound to GNPs into bacteria following perfusion. These results may represent a major step in antibiotherapy treatment using nanolocalized thermal ablation by laser heating. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=gold%20nanoparticles" title="gold nanoparticles">gold nanoparticles</a>, <a href="https://publications.waset.org/abstracts/search?q=Klebsiella%20pneumoniae" title=" Klebsiella pneumoniae"> Klebsiella pneumoniae</a>, <a href="https://publications.waset.org/abstracts/search?q=nanoparticle%20functionalization" title=" nanoparticle functionalization"> nanoparticle functionalization</a>, <a href="https://publications.waset.org/abstracts/search?q=laser%20irradiation" title=" laser irradiation"> laser irradiation</a>, <a href="https://publications.waset.org/abstracts/search?q=antibody" title=" antibody"> antibody</a> </p> <a href="https://publications.waset.org/abstracts/84088/nanotechnology-based-treatment-of-klebsiella-pneumoniae-infections" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/84088.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">424</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">148</span> Papain Immobilized Polyurethane Film as an Antimicrobial Food Package </h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=M.%20Cynthya">M. Cynthya</a>, <a href="https://publications.waset.org/abstracts/search?q=V.%20Prabhawathi"> V. Prabhawathi</a>, <a href="https://publications.waset.org/abstracts/search?q=D.%20Mukesh"> D. Mukesh </a> </p> <p class="card-text"><strong>Abstract:</strong></p> Food contamination occurs during post process handling. This leads to spoilage and growth of pathogenic microorganisms in the food, thereby reducing its shelf life or spreading of food borne diseases. Several methods are tried and one of which is use of antimicrobial packaging. Here, papain, a protease enzyme, is covalently immobilized with the help of glutarldehyde on polyurethane and used as a food wrap to protect food from microbial contamination. Covalent immobilization of papain was achieved at a pH of 7.4; temperature of 4°C; glutaraldehyde concentration of 0.5%; incubation time of 24 h; and 50 mg of papain. The formation of -C=N- observed in the Fourier transform infrared spectrum confirmed the immobilization of the enzyme on the polymer. Immobilized enzyme retained higher activity than the native free enzyme. The efficacy of this was studied by wrapping it over S. aureus contaminated cottage cheese (paneer) and cheese and stored at a temperature of 4°C for 7 days. The modified film reduced the bacterial contamination by eight folds when compared to the bare film. FTIR also indicates reduction in lipids, sugars and proteins in the biofilm. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=cheese" title="cheese">cheese</a>, <a href="https://publications.waset.org/abstracts/search?q=papain" title=" papain"> papain</a>, <a href="https://publications.waset.org/abstracts/search?q=polyurethane" title=" polyurethane"> polyurethane</a>, <a href="https://publications.waset.org/abstracts/search?q=Staphylococcus%20aureus" title=" Staphylococcus aureus"> Staphylococcus aureus</a> </p> <a href="https://publications.waset.org/abstracts/15912/papain-immobilized-polyurethane-film-as-an-antimicrobial-food-package" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/15912.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">475</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">147</span> Influence of Iron Content in Carbon Nanotubes on the Intensity of Hyperthermia in the Cancer Treatment</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=S.%20Wiak">S. Wiak</a>, <a href="https://publications.waset.org/abstracts/search?q=L.%20Szymanski"> L. Szymanski</a>, <a href="https://publications.waset.org/abstracts/search?q=Z.%20Kolacinski"> Z. Kolacinski</a>, <a href="https://publications.waset.org/abstracts/search?q=G.%20Raniszewski"> G. Raniszewski</a>, <a href="https://publications.waset.org/abstracts/search?q=L.%20Pietrzak"> L. Pietrzak</a>, <a href="https://publications.waset.org/abstracts/search?q=Z.%20Staniszewska"> Z. Staniszewska</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The term ‘cancer’ is given to a collection of related diseases that may affect any part of the human body. It is a pathological behaviour of cells with the potential to undergo abnormal breakdown in the processes that control cell proliferation, differentiation, and death of particular cells. Although cancer is commonly considered as modern disease, there are beliefs that drastically growing number of new cases can be linked to the extensively prolonged life expectancy and enhanced techniques for cancer diagnosis. Magnetic hyperthermia therapy is a novel approach to cancer treatment, which may greatly contribute to higher efficiency of the therapy. Employing carbon nanotubes as nanocarriers for magnetic particles, it is possible to decrease toxicity and invasiveness of the treatment by surface functionalisation. Despite appearing in recent years, magnetic particle hyperthermia has already become of the highest interest in the scientific and medical environment. The reason why hyperthermia therapy brings so much hope for future treatment of cancer lays in the effect that it produces in malignant cells. Subjecting them to thermal shock results in activation of numerous degradation processes inside and outside the cell. The heating process initiates mechanisms of DNA destruction, protein denaturation and induction of cell apoptosis, which may lead to tumour shrinkage, and in some cases, it may even cause complete disappearance of cancer. The factors which have the major impact on the final efficiency of the treatment include temperatures generated inside the tissues, time of exposure to the heating process, and the character of an individual cancer cell type. The vast majority of cancer cells is characterised by lower pH, persistent hypoxia and lack of nutrients, which can be associated to abnormal microvasculature. Since in healthy tissues we cannot observe presence of these conditions, they should not be seriously affected by elevation of the temperature. The aim of this work is to investigate the influence of iron content in iron filled Carbon Nanotubes on the desired nanoparticles for cancer therapy. In the article, the development and demonstration of the method and the model device for hyperthermic selective destruction of cancer cells are presented. This method was based on the synthesis and functionalization of carbon nanotubes serving as ferromagnetic material nanocontainers. The methodology of the production carbon- ferromagnetic nanocontainers (FNCs) includes the synthesis of carbon nanotubes, chemical, and physical characterization, increasing the content of a ferromagnetic material and biochemical functionalization involving the attachment of the key addresses. The ferromagnetic nanocontainers were synthesised in CVD and microwave plasma system. The research work has been financed from the budget of science as a research project No. PBS2/A5/31/2013. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=hyperthermia" title="hyperthermia">hyperthermia</a>, <a href="https://publications.waset.org/abstracts/search?q=carbon%20nanotubes" title=" carbon nanotubes"> carbon nanotubes</a>, <a href="https://publications.waset.org/abstracts/search?q=cancer%20colon%20cells" title=" cancer colon cells"> cancer colon cells</a>, <a href="https://publications.waset.org/abstracts/search?q=radio%20frequency%20field" title=" radio frequency field"> radio frequency field</a> </p> <a href="https://publications.waset.org/abstracts/77667/influence-of-iron-content-in-carbon-nanotubes-on-the-intensity-of-hyperthermia-in-the-cancer-treatment" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/77667.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">122</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">146</span> In situ One-Step Synthesis of Graphene Quantum Dots-Metal Free and Zinc Phthalocyanines Conjugates: Investigation of Photophysicochemical Properties</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=G.%20Fomo">G. Fomo</a>, <a href="https://publications.waset.org/abstracts/search?q=O.%20J.%20Achadu"> O. J. Achadu</a>, <a href="https://publications.waset.org/abstracts/search?q=T.%20Nyokong"> T. Nyokong</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Nanoconjugates of graphene quantum dots (GQDs) and 4-(tetrakis-5-(trifluoromethyl)-2-mercaptopyridinephthalocyanine (H₂Pc(OPyF₃)₄) or 4-(tetrakis-5-(trifluoromethyl)-2-mercaptopyridinephthalocyaninato) zinc (II) (ZnPc(OPyF₃)₄) were synthesized via a novel in situ one-step route. The bottom-up approach for the prepared conjugates could ensure the intercalation of the phthalocyanines (Pcs) directly onto the edges or surface of the GQDs and or non-covalent coordination using the π-electron systems of both materials. The as-synthesized GQDs and their Pcs conjugates were characterized using different spectroscopic techniques and their photophysicochemical properties evaluated. The singlet oxygen quantum yields of the Pcs in the presence of GQDs were enhanced due to Förster resonance energy transfer (FRET) occurrence within the conjugated hybrids. Hence, these nanoconjugates are potential materials for photodynamic therapy (PDT) and photocatalysis applications. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=graphene%20quantum%20dots" title="graphene quantum dots">graphene quantum dots</a>, <a href="https://publications.waset.org/abstracts/search?q=metal%20free%20fluorinated%20phthalocyanine" title=" metal free fluorinated phthalocyanine"> metal free fluorinated phthalocyanine</a>, <a href="https://publications.waset.org/abstracts/search?q=zinc%20fluorinated%20phthalocyanine" title=" zinc fluorinated phthalocyanine"> zinc fluorinated phthalocyanine</a>, <a href="https://publications.waset.org/abstracts/search?q=photophysicochemical%20properties" title=" photophysicochemical properties "> photophysicochemical properties </a> </p> <a href="https://publications.waset.org/abstracts/73210/in-situ-one-step-synthesis-of-graphene-quantum-dots-metal-free-and-zinc-phthalocyanines-conjugates-investigation-of-photophysicochemical-properties" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/73210.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">182</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">145</span> Co₂Fe LDH on Aromatic Acid Functionalized N Doped Graphene: Hybrid Electrocatalyst for Oxygen Evolution Reaction</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Biswaranjan%20D.%20Mohapatra">Biswaranjan D. Mohapatra</a>, <a href="https://publications.waset.org/abstracts/search?q=Ipsha%20Hota"> Ipsha Hota</a>, <a href="https://publications.waset.org/abstracts/search?q=Swarna%20P.%20Mantry"> Swarna P. Mantry</a>, <a href="https://publications.waset.org/abstracts/search?q=Nibedita%20Behera"> Nibedita Behera</a>, <a href="https://publications.waset.org/abstracts/search?q=Kumar%20S.%20K.%20Varadwaj"> Kumar S. K. Varadwaj</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Designing highly active and low-cost oxygen evolution (2H₂O → 4H⁺ + 4e⁻ + O₂) electrocatalyst is one of the most active areas of advanced energy research. Some precious metal-based electrocatalysts, such as IrO₂ and RuO₂, have shown excellent performance for oxygen evolution reaction (OER); however, they suffer from high-cost and low abundance which limits their applications. Recently, layered double hydroxides (LDHs), composed of layers of divalent and trivalent transition metal cations coordinated to hydroxide anions, have gathered attention as an alternative OER catalyst. However, LDHs are insulators and coupled with carbon materials for the electrocatalytic applications. Graphene covalently doped with nitrogen has been demonstrated to be an excellent electrocatalyst for energy conversion technologies such as; oxygen reduction reaction (ORR), oxygen evolution reaction (OER) & hydrogen evolution reaction (HER). However, they operate at high overpotentials, significantly above the thermodynamic standard potentials. Recently, we reported remarkably enhanced catalytic activity of benzoate or 1-pyrenebutyrate functionalized N-doped graphene towards the ORR in alkaline medium. The molecular and heteroatom co-doping on graphene is expected to tune the electronic structure of graphene. Therefore, an innovative catalyst architecture, in which LDHs are anchored on aromatic acid functionalized ‘N’ doped graphene may presumably boost the OER activity to a new benchmark. Herein, we report fabrication of Co₂Fe-LDH on aromatic acid (AA) functionalized ‘N’ doped reduced graphene oxide (NG) and studied their OER activities in alkaline medium. In the first step, a novel polyol method is applied for synthesis of AA functionalized NG, which is well dispersed in aqueous medium. In the second step, Co₂Fe LDH were grown on AA functionalized NG by co-precipitation method. The hybrid samples are abbreviated as Co₂Fe LDH/AA-NG, where AA is either Benzoic acid or 1, 3-Benzene dicarboxylic acid (BDA) or 1, 3, 5 Benzene tricarboxylic acid (BTA). The crystal structure and morphology of the samples were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM) and transmission electron microscope (TEM). These studies confirmed the growth of layered single phase LDH. The electrocatalytic OER activity of these hybrid materials was investigated by rotating disc electrode (RDE) technique on a glassy carbon electrode. The linear sweep voltammetry (LSV) on these catalyst samples were taken at 1600rpm. We observed significant OER performance enhancement in terms of onset potential and current density on Co₂Fe LDH/BTA-NG hybrid, indicating the synergic effect. This exploration of molecular functionalization effect in doped graphene and LDH system may provide an excellent platform for innovative design of OER catalysts. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=%CF%80-%CF%80%20functionalization" title="π-π functionalization">π-π functionalization</a>, <a href="https://publications.waset.org/abstracts/search?q=layered%20double%20hydroxide" title=" layered double hydroxide"> layered double hydroxide</a>, <a href="https://publications.waset.org/abstracts/search?q=oxygen%20evolution%20reaction" title=" oxygen evolution reaction"> oxygen evolution reaction</a>, <a href="https://publications.waset.org/abstracts/search?q=reduced%20graphene%20oxide" title=" reduced graphene oxide"> reduced graphene oxide</a> </p> <a href="https://publications.waset.org/abstracts/80658/co2fe-ldh-on-aromatic-acid-functionalized-n-doped-graphene-hybrid-electrocatalyst-for-oxygen-evolution-reaction" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/80658.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">207</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">144</span> Smart Multifunctionalized and Responsive Polymersomes as Targeted and Selective Recognition Systems</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Silvia%20Moreno">Silvia Moreno</a>, <a href="https://publications.waset.org/abstracts/search?q=Banu%20Iyisan"> Banu Iyisan</a>, <a href="https://publications.waset.org/abstracts/search?q=Hannes%20Gumz"> Hannes Gumz</a>, <a href="https://publications.waset.org/abstracts/search?q=Brigitte%20Voit"> Brigitte Voit</a>, <a href="https://publications.waset.org/abstracts/search?q=Dietmar%20Appelhans"> Dietmar Appelhans</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Polymersomes are materials which are considered as artificial counterparts of natural vesicles. The nanotechnology of such smart nanovesicles is very useful to enhance the efficiency of many therapeutic and diagnostic drugs. Those compounds show a higher stability, flexibility, and mechanical strength to the membrane compared to natural liposomes. In addition, they can be designed in detail, the permeability of the membrane can be controlled by different stimuli, and the surface can be functionalized with different biological molecules to facilitate monitoring and target. For this purpose, this study demonstrates the formation of multifunctional and pH sensitive polymersomes and their functionalization with different reactive groups or biomolecules inside and outside of polymersomes´ membrane providing by crossing the membrane and docking/undocking processes for biomedical applications. Overall, they are highly versatile and thus present new opportunities for the design of targeted and selective recognition systems, for example, in mimicking cell functions and in synthetic biology. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=multifunctionalized" title="multifunctionalized">multifunctionalized</a>, <a href="https://publications.waset.org/abstracts/search?q=pH%20stimulus" title=" pH stimulus"> pH stimulus</a>, <a href="https://publications.waset.org/abstracts/search?q=controllable%20release" title=" controllable release"> controllable release</a>, <a href="https://publications.waset.org/abstracts/search?q=cellular%20uptake" title=" cellular uptake"> cellular uptake</a> </p> <a href="https://publications.waset.org/abstracts/67024/smart-multifunctionalized-and-responsive-polymersomes-as-targeted-and-selective-recognition-systems" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/67024.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">320</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">143</span> Synthesis and Functionalization of MnFe₂O₄ Nano−Hollow Spheres for Optical and Catalytic Properties</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Indranil%20Chakraborty">Indranil Chakraborty</a>, <a href="https://publications.waset.org/abstracts/search?q=Kalyan%20Mandal"> Kalyan Mandal</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Herein, we synthesize MnFe₂O₄ nano−hollow spheres (NHSs) of average diameter 100 nm through a facile template free solvothermal process and carry out a time dependent morphological study to investigate their process of core excavation. Further, a surface engineering of as−synthesized MnFe₂O₄ NHSs has been executed with organic disodium tartrate dihydrate ligand and interestingly, the surface modified MnFe₂O₄ NHSs are found to capable of emerging multicolor fluorescence starting from blue, green to red. The magnetic measurements through vibrating sample magnetometer demonstrate that room temperature superparamagnetic nature of MnFe₂O₄ NHSs remains unaltered after surface modification. Moreover, functionalized MnFe₂O₄ NHSs are found to exhibit excellent reusable photocatalytic efficiency in the degradation of cationic dye, methylene blue with rate constant of 2.64×10−2 min. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=nano%20hollow%20sphere" title="nano hollow sphere">nano hollow sphere</a>, <a href="https://publications.waset.org/abstracts/search?q=tartrate%20modification" title=" tartrate modification"> tartrate modification</a>, <a href="https://publications.waset.org/abstracts/search?q=multiple%20fluorescence" title=" multiple fluorescence"> multiple fluorescence</a>, <a href="https://publications.waset.org/abstracts/search?q=catalytic%20property" title=" catalytic property"> catalytic property</a> </p> <a href="https://publications.waset.org/abstracts/78895/synthesis-and-functionalization-of-mnfe2o4-nanohollow-spheres-for-optical-and-catalytic-properties" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/78895.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">186</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">142</span> Chitosan Functionalized Fe3O4@Au Core-Shell Nanomaterials for Targeted Drug Delivery</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=S.%20S.%20Pati">S. S. Pati</a>, <a href="https://publications.waset.org/abstracts/search?q=L.%20Herojit%20Singh"> L. Herojit Singh</a>, <a href="https://publications.waset.org/abstracts/search?q=A.%20C.%20Oliveira"> A. C. Oliveira</a>, <a href="https://publications.waset.org/abstracts/search?q=V.%20K.%20Garg"> V. K. Garg</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Chitosan functionalized Fe3O4-Au core shell nanoparticles have been prepared using a two step wet chemical approach using NaBH4 as reducing agent for formation of Au inethylene glycol. X-ray diffraction studies shows individual phases of Fe3O4 and Au in the as prepared samples with crystallite size of 5.9 and 11.4 nm respectively. The functionalization of the core-shell nanostructure with Chitosan has been confirmed using Fourier transform infrared spectroscopy along with signatures of octahedral and tetrahedral sites of Fe3O4 below 600cm-1. Mössbauer spectroscopy shows decrease in particle-particle interaction in presence of Au shell (72% sextet) than pure oleic coated Fe3O4 nanoparticles (88% sextet) at room temperature. At 80K, oleic acid coated Fe3O4 shows only sextets whereas the Chitosan functionalized Fe3O4 and Chitosan functionalized Fe3O4@Au core shell show presence of 5 and 11% doublet, respectively. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=core%20shell" title="core shell">core shell</a>, <a href="https://publications.waset.org/abstracts/search?q=drug%20delivery" title=" drug delivery"> drug delivery</a>, <a href="https://publications.waset.org/abstracts/search?q=gold%20nanoparticles" title=" gold nanoparticles"> gold nanoparticles</a>, <a href="https://publications.waset.org/abstracts/search?q=magnetic%20nanoparticles" title=" magnetic nanoparticles"> magnetic nanoparticles</a> </p> <a href="https://publications.waset.org/abstracts/28882/chitosan-functionalized-fe3o4-at-au-core-shell-nanomaterials-for-targeted-drug-delivery" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/28882.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">375</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">141</span> Magnetite Nanoparticles Immobilized Pectinase: Preparation, Characterization and Application for the Fruit Juices Clarification</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Leila%20Mosafa">Leila Mosafa</a>, <a href="https://publications.waset.org/abstracts/search?q=Majid%20Moghadam"> Majid Moghadam</a>, <a href="https://publications.waset.org/abstracts/search?q=Mohammad%20Shahedi"> Mohammad Shahedi</a> </p> <p class="card-text"><strong>Abstract:</strong></p> In this work, pectinase was immobilized on the surface of silica-coated magnetite nanoparticles via covalent attachment. The magnetite-immobilized enzyme was characterized by Fourier transform infrared spectroscopy, X-ray powder diffraction, scanning electron microscopy and vibrating sample magnetometry techniques. Response surface methodology using Minitab Software was applied for statistical designing of operating conditions in order to immobilize pectinase on magnetic nanoparticles. The optimal conditions were obtained at 30°C and pH 5.5 with 42.97 µl pectinase for 2 h. The immobilization yield was 50.6% at optimized conditions. Compared to the free pectinase, the immobilized pectinase was found to exhibit enhanced enzyme activity, better tolerance to the variation of pH and temperature, and improved storage stability. Both free and immobilized samples reduced the viscosity of apple juice from 1.12 to 0.88 and 0.92 mm2s-1, respectively, after 30 min at their optimum temperature. Furthermore, the immobilized enzyme could be reused six consecutive cycles and the efficiency loss in viscosity reduction was found to be only 8.16%. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=magnetite%20nanoparticles" title="magnetite nanoparticles">magnetite nanoparticles</a>, <a href="https://publications.waset.org/abstracts/search?q=pectinase%20enzyme" title=" pectinase enzyme"> pectinase enzyme</a>, <a href="https://publications.waset.org/abstracts/search?q=immobilization" title=" immobilization"> immobilization</a>, <a href="https://publications.waset.org/abstracts/search?q=juice%20clarification" title=" juice clarification"> juice clarification</a>, <a href="https://publications.waset.org/abstracts/search?q=enzyme%20activity" title=" enzyme activity "> enzyme activity </a> </p> <a href="https://publications.waset.org/abstracts/6143/magnetite-nanoparticles-immobilized-pectinase-preparation-characterization-and-application-for-the-fruit-juices-clarification" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/6143.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">407</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">140</span> Direct Palladium-Catalyzed Selective N-Allylation of 2,3-Disubstituted Indoles with Allylic Alcohols in Water</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Bai-Jing%20Peng">Bai-Jing Peng</a>, <a href="https://publications.waset.org/abstracts/search?q=Shyh-Chyun%20Yang"> Shyh-Chyun Yang</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Organic reactions in water have recently attracted much attention, not only because unique reactivity is often observed in water but also because water is a safe and economical substitute for conventional organic solvents. Thus, development of environmental safe, atom-economical reactions in water is one of the most important goals of synthetic chemistry. The recent paper has documented renewed interest in the use of allylic substrates in the synthesis of new C−C, C−N, and C−O bonds. We have reported our attempts and some successful applications of a process involving the C-O bond cleavage catalyzed by palladium or platinum complexes in water. Because of the importance of heterocycle indole derivatives, much effort has been directed toward the development of methods for functionalization of the indole nucleus at N1 site. In our research, the palladium-catalyzed 2,3-disubstitued indoles with allylic alcohols was investigated under different conditions. Herein, we will establish a simple, convenient, and efficient method, which affords high yields of allylated indoles. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=palladium-catalyzed" title="palladium-catalyzed">palladium-catalyzed</a>, <a href="https://publications.waset.org/abstracts/search?q=allylic%20alcohols" title=" allylic alcohols"> allylic alcohols</a>, <a href="https://publications.waset.org/abstracts/search?q=indoles" title=" indoles"> indoles</a>, <a href="https://publications.waset.org/abstracts/search?q=water" title=" water"> water</a>, <a href="https://publications.waset.org/abstracts/search?q=allylation" title=" allylation"> allylation</a> </p> <a href="https://publications.waset.org/abstracts/71957/direct-palladium-catalyzed-selective-n-allylation-of-23-disubstituted-indoles-with-allylic-alcohols-in-water" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/71957.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">238</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">139</span> Chemical Functionalization of Graphene Oxide for Improving Mechanical and Thermal Properties of Polyurethane Composites</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Qifei%20Jing">Qifei Jing</a>, <a href="https://publications.waset.org/abstracts/search?q=Vadim%20V.%20Silberschmidt"> Vadim V. Silberschmidt</a>, <a href="https://publications.waset.org/abstracts/search?q=Lin%20Li"> Lin Li</a>, <a href="https://publications.waset.org/abstracts/search?q=ZhiLi%20Dong"> ZhiLi Dong</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Graphene oxide (GO) was chemically functionalized to prepare polyurethane (PU) composites with improved mechanical and thermal properties. In order to achieve a well exfoliated and stable GO suspension in an organic solvent (dimethylformamide, DMF), 4, 4′- methylenebis(phenyl isocyanate) and polycaprolactone diol, which were the two monomers for synthesizing PU, were selectively used to functionalize GO. The obtained functionalized GO (FGO) could form homogeneous dispersions in DMF solvent and the PU matrix, as well as provide a good compatibility with the PU matrix. The most efficient improvement of mechanical properties was achieved when 0.4 wt% FGO was added into the PU matrix, showing increases in the tensile stress, elongation at break and toughness by 34.2%, 27.6% and 64.5%, respectively, compared with those of PU. Regarding the thermal stability, PU filled with 1 wt% FGO showed the largest extent of improvement with T2% and T50% (the temperatures at which 2% and 50% weight-loss happened) 16 °C and 21 °C higher than those of PU, respectively. The significant improvement in both mechanical properties and thermal stability of FGO/PU composites should be attributed to the homogeneous dispersion of FGO in the PU matrix and strong interfacial interaction between them. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=composite" title="composite">composite</a>, <a href="https://publications.waset.org/abstracts/search?q=dispersion" title=" dispersion"> dispersion</a>, <a href="https://publications.waset.org/abstracts/search?q=graphene%20oxide" title=" graphene oxide"> graphene oxide</a>, <a href="https://publications.waset.org/abstracts/search?q=polyurethane" title=" polyurethane"> polyurethane</a> </p> <a href="https://publications.waset.org/abstracts/38464/chemical-functionalization-of-graphene-oxide-for-improving-mechanical-and-thermal-properties-of-polyurethane-composites" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/38464.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">263</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">138</span> Rheological Properties of Thermoresponsive Poly(N-Vinylcaprolactam)-g-Collagen Hydrogel</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Serap%20Durkut">Serap Durkut</a>, <a href="https://publications.waset.org/abstracts/search?q=A.%20Eser%20Elcin"> A. Eser Elcin</a>, <a href="https://publications.waset.org/abstracts/search?q=Y.%20Murat%20Elcin"> Y. Murat Elcin</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Stimuli-sensitive polymeric hydrogels have received extensive attention in the biomedical field due to their sensitivity to physical and chemical stimuli (temperature, pH, ionic strength, light, etc.). This study describes the rheological properties of a novel thermoresponsive poly(N-vinylcaprolactam)-g-collagen hydrogel. In the study, we first synthesized a facile and novel synthetic carboxyl group-terminated thermo-responsive poly(N-vinylcaprolactam)-COOH (PNVCL-COOH) via free radical polymerization. Further, this compound was effectively grafted with native collagen, by utilizing the covalent bond between the carboxylic acid groups at the end of the chains and amine groups of the collagen using cross-linking agent (EDC/NHS), forming PNVCL-g-Col. Newly-formed hybrid hydrogel displayed novel properties, such as increased mechanical strength and thermoresponsive characteristics. PNVCL-g-Col showed low critical solution temperature (LCST) at 38ºC, which is very close to the body temperature. Rheological studies determine structural–mechanical properties of the materials and serve as a valuable tool for characterizing. The rheological properties of hydrogels are described in terms of two dynamic mechanical properties: the elastic modulus G′ (also known as dynamic rigidity) representing the reversible stored energy of the system, and the viscous modulus G″, representing the irreversible energy loss. In order to characterize the PNVCL-g-Col, the rheological properties were measured in terms of the function of temperature and time during phase transition. Below the LCST, favorable interactions allowed the dissolution of the polymer in water via hydrogen bonding. At temperatures above the LCST, PNVCL molecules within PNVCL-g-Col aggregated due to dehydration, causing the hydrogel structure to become dense. When the temperature reached ~36ºC, both the G′ and G″ values crossed over. This indicates that PNVCL-g-Col underwent a sol-gel transition, forming an elastic network. Following temperature plateau at 38ºC, near human body temperature the sample displayed stable elastic network characteristics. The G′ and G″ values of the PNVCL-g-Col solutions sharply increased at 6-9 minute interval, due to rapid transformation into gel-like state and formation of elastic networks. Copolymerization with collagen leads to an increase in G′, as collagen structure contains a flexible polymer chain, which bestows its elastic properties. Elasticity of the proposed structure correlates with the number of intermolecular cross-links in the hydrogel network, increasing viscosity. However, at 8 minutes, G′ and G″ values sharply decreased for pure collagen solutions due to the decomposition of the elastic and viscose network. Complex viscosity is related to the mechanical performance and resistance opposing deformation of the hydrogel. Complex viscosity of PNVCL-g-Col hydrogel was drastically changed with temperature and the mechanical performance of PNVCL-g-Col hydrogel network increased, exhibiting lesser deformation. Rheological assessment of the novel thermo-responsive PNVCL-g-Col hydrogel, exhibited that the network has stronger mechanical properties due to both permanent stable covalent bonds and physical interactions, such as hydrogen- and hydrophobic bonds depending on temperature. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=poly%28N-vinylcaprolactam%29-g-collagen" title="poly(N-vinylcaprolactam)-g-collagen">poly(N-vinylcaprolactam)-g-collagen</a>, <a href="https://publications.waset.org/abstracts/search?q=thermoresponsive%20polymer" title=" thermoresponsive polymer"> thermoresponsive polymer</a>, <a href="https://publications.waset.org/abstracts/search?q=rheology" title=" rheology"> rheology</a>, <a href="https://publications.waset.org/abstracts/search?q=elastic%20modulus" title=" elastic modulus"> elastic modulus</a>, <a href="https://publications.waset.org/abstracts/search?q=stimuli-sensitive" title=" stimuli-sensitive"> stimuli-sensitive</a> </p> <a href="https://publications.waset.org/abstracts/56756/rheological-properties-of-thermoresponsive-polyn-vinylcaprolactam-g-collagen-hydrogel" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/56756.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">243</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">137</span> Synthesis and Functionalization of Gold Nanostars for ROS Production </h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=H.%20D.%20Duong">H. D. Duong</a>, <a href="https://publications.waset.org/abstracts/search?q=J.%20I.%20Rhee"> J. I. Rhee</a> </p> <p class="card-text"><strong>Abstract:</strong></p> In this work, gold nanoparticles in star shape (called gold nanostars, GNS) were synthesized and coated by N-(3-aminopropyl) methacrylamide hydrochloride (PA) and mercaptopropionic acid (MPA) for functionalizing their surface by amine and carboxyl groups and then investigated for ROS production. The GNS with big size and multi-tips seem to be superior in singlet oxygen production as compared with that of small GNS and less tips. However, the functioned GNS in small size could also enhance efficiency of singlet oxygen production about double as compared with that of the intact GNS. In combination with methylene blue (MB+), the functioned GNS could enhance the singlet oxygen production of MB+ after 1h of LED750 irradiation and no difference between small size and big size in this reaction was observed. In combination with 5-aminolevulinic acid (ALA), only GNS coated PA could enhance the singlet oxygen production of ALA and the small size of GNS coated PA was a little higher effect than that of the bigger size. However, GNS coated MPA with small size had strong effect on hydroxyl radical production of ALA. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=5-aminolevulinic%20acid" title="5-aminolevulinic acid">5-aminolevulinic acid</a>, <a href="https://publications.waset.org/abstracts/search?q=gold%20nanostars" title=" gold nanostars"> gold nanostars</a>, <a href="https://publications.waset.org/abstracts/search?q=methylene%20blue" title=" methylene blue"> methylene blue</a>, <a href="https://publications.waset.org/abstracts/search?q=ROS%20production" title=" ROS production"> ROS production</a> </p> <a href="https://publications.waset.org/abstracts/36355/synthesis-and-functionalization-of-gold-nanostars-for-ros-production" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/36355.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">351</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">136</span> Advanced Catechol-Modified Chitosan Hydrogels with the Inducement of Iron (III) Ion at Acidic Condition</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Ngoc%20Quang%20Nguyen">Ngoc Quang Nguyen</a>, <a href="https://publications.waset.org/abstracts/search?q=Daewon%20Sohn"> Daewon Sohn</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Chitosan (CS) is a natural polycationic polysaccharide and pH-sensitive polymer with incomplete deacetylation from claiming chitin. It is also a guaranteeing material in terms of pharmaceutical, chemical, and sustenance industry due to its exceptional structure (reactive –OH and –NH2 groups). In this study, a catechol-functionalized chitosan (CCS, for an eminent level for substitution) was synthesized and propelled by marine mussel cuticles in place on research those intricate connections between Fe³⁺ and catechol under acidic conditions. The ratios of catechol, chitosan and other reagents decide the structure of the hydrogel. The gel formation is then well-maintained by dual cross-linking through electrostatic interactions between Fe³⁺ and CCS and covalent catechol-coupling-based coordinate bonds. The hydrogels showed enhanced cohesiveness and shock-absorbing properties with increasing pH due to coordinate bonds inspired by mussel byssal threads. Thus, the gelation time, rheological properties, UV-vis and ¹H-Nuclear Magnetic Resonance spectroscopy, and the morphologic aspects were elucidated to describe those crosslinking components and the physical properties of the chitosan backbones and hydrogel frameworks. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=catechol" title="catechol">catechol</a>, <a href="https://publications.waset.org/abstracts/search?q=chitosan" title=" chitosan"> chitosan</a>, <a href="https://publications.waset.org/abstracts/search?q=iron%20ion" title=" iron ion"> iron ion</a>, <a href="https://publications.waset.org/abstracts/search?q=gelation" title=" gelation"> gelation</a>, <a href="https://publications.waset.org/abstracts/search?q=hydrogel" title=" hydrogel"> hydrogel</a> </p> <a href="https://publications.waset.org/abstracts/97228/advanced-catechol-modified-chitosan-hydrogels-with-the-inducement-of-iron-iii-ion-at-acidic-condition" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/97228.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">142</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">135</span> Improvement on the Specific Activities of Immobilized Enzymes by Poly(Ethylene Oxide) Surface Modification</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Shaohua%20Li">Shaohua Li</a>, <a href="https://publications.waset.org/abstracts/search?q=Aihua%20Zhang"> Aihua Zhang</a>, <a href="https://publications.waset.org/abstracts/search?q=Kelly%20Zatopek"> Kelly Zatopek</a>, <a href="https://publications.waset.org/abstracts/search?q=Saba%20Parvez"> Saba Parvez</a>, <a href="https://publications.waset.org/abstracts/search?q=Andrew%20F.%20Gardner"> Andrew F. Gardner</a>, <a href="https://publications.waset.org/abstracts/search?q=Ivan%20R.%20Corr%C3%AAa%20Jr."> Ivan R. Corrêa Jr.</a>, <a href="https://publications.waset.org/abstracts/search?q=Christopher%20J.%20Noren"> Christopher J. Noren</a>, <a href="https://publications.waset.org/abstracts/search?q=Ming-Qun%20Xu"> Ming-Qun Xu</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Covalent immobilization of enzymes on solid supports is an alternative approach to biocatalysis with the added benefits of simple enzyme removal, improved stability, and adaptability to automation and high-throughput applications. Nevertheless, immobilized enzymes generally suffer from reduced activities compared to their soluble counterparts. One major factor leading to activity loss is the intrinsic hydrophobic property of the supporting material surface, which could result in the conformational change/confinement of enzymes. We report a strategy of utilizing flexible poly (ethylene oxide) (PEO) moieties as to improve the surface hydrophilicity of solid supports used for enzyme immobilization. DNA modifying enzymes were covalently conjugated to PEO-coated magnetic-beads. Kinetics studies proved that the activities of the covalently-immobilized DNA modifying enzymes were greatly enhanced by the PEO modification on the bead surface. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=immobilized%20enzymes" title="immobilized enzymes">immobilized enzymes</a>, <a href="https://publications.waset.org/abstracts/search?q=biocatalysis" title=" biocatalysis"> biocatalysis</a>, <a href="https://publications.waset.org/abstracts/search?q=poly%28ethylene%20oxide%29" title=" poly(ethylene oxide)"> poly(ethylene oxide)</a>, <a href="https://publications.waset.org/abstracts/search?q=surface%20modification" title=" surface modification"> surface modification</a> </p> <a href="https://publications.waset.org/abstracts/79716/improvement-on-the-specific-activities-of-immobilized-enzymes-by-polyethylene-oxide-surface-modification" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/79716.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">308</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">134</span> Functionalizing Gold Nanostars with Ninhydrin as Vehicle Molecule for Biomedical Applications</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Swati%20Mishra">Swati Mishra</a> </p> <p class="card-text"><strong>Abstract:</strong></p> In recent years, there has been an explosion in Gold NanoParticle (GNP) research, with a rapid increase in publications in diverse fields, including imaging, bioengineering, and molecular biology. GNPs exhibit unique physicochemical properties, including surface plasmon resonance (SPR) and bind amine and thiol groups, allowing surface modification and use in biomedical applications. Nanoparticle functionalization is the subject of intense research at present, with rapid progress being made towards developing biocompatible, multi-functional particles. In the present study, the photochemical method has been done to functionalize various-shaped GNPs like nanostars by the molecules like ninhydrin. Ninhydrin is bactericidal, virucidal, fungicidal, antigen-antibody reactive, and used in fingerprint technology in forensics. The GNPs functionalized with ninhydrin efficiently will bind to the amino acids on the target protein, which is of eminent importance during the pandemic, especially where long-term treatments of COVID- 19 bring many side effects of the drugs. The photochemical method is adopted as it provides low thermal load, selective reactivity, selective activation, and controlled radiation in time, space, and energy. The GNPs exhibit their characteristic spectrum, but a distinctly blue or redshift in the peak will be observed after UV irradiation, ensuring efficient ninhydrin binding. Now, the bound ninhydrin in the GNP carrier, upon chemically reacting with any amino acid, will lead to the formation of Rhumann purple. A common method of GNP production includes citrate reduction of Au [III] derivatives such as aurochloric acid (HAuCl4) in water to Au [0] through a one-step synthesis of size-tunable GNPs. The following reagents are prepared to validate the approach. Reagent A solution 1 is0.0175 grams ninhydrin in 5 ml Millipore water Reagent B 30 µl of HAuCl₄.3H₂O in 3 ml of solution 1 Reagent C 1 µl of gold nanostars in 3 ml of solution 1 Reagent D 6 µl of cetrimonium bromide (CTAB) in 3 ml of solution1 ReagentE 1 µl of gold nanostars in 3 ml of ethanol ReagentF 30 µl of HAuCl₄.₃H₂O in 3 ml of ethanol ReagentG 30 µl of HAuCl₄.₃H₂O in 3 ml of solution 2 ReagentH solution 2 is0.0087 grams ninhydrin in 5 ml Millipore water ReagentI 30 µl of HAuCl₄.₃H₂O in 3 ml of water The reagents were irradiated at 254 nm for 15 minutes, followed by their UV Visible spectroscopy. The wavelength was selected based on the one reported for excitation of a similar molecule Pthalimide. It was observed that the solution B and G deviate around 600 nm, while C peaks distinctively at 567.25 nm and 983.9 nm. Though it is tough to say about the chemical reaction happening, butATR-FTIR of reagents will ensure that ninhydrin is not forming Rhumann purple in the absence of amino acids. Therefore, these experiments, we achieved the functionalization of gold nanostars with ninhydrin corroborated by the deviation in the spectrum obtained in a mixture of GNPs and ninhydrin irradiated with UV light. It prepares them as a carrier molecule totake up amino acids for targeted delivery or germicidal action. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=gold%20nanostars" title="gold nanostars">gold nanostars</a>, <a href="https://publications.waset.org/abstracts/search?q=ninhydrin" title=" ninhydrin"> ninhydrin</a>, <a href="https://publications.waset.org/abstracts/search?q=photochemical%20method" title=" photochemical method"> photochemical method</a>, <a href="https://publications.waset.org/abstracts/search?q=UV%20visible%20specgtroscopy" title=" UV visible specgtroscopy"> UV visible specgtroscopy</a> </p> <a href="https://publications.waset.org/abstracts/142305/functionalizing-gold-nanostars-with-ninhydrin-as-vehicle-molecule-for-biomedical-applications" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/142305.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">148</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">133</span> Ceramic Composites and Its Applications for Pb Adsorption</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=C.%20L.%20Popa">C. L. Popa</a>, <a href="https://publications.waset.org/abstracts/search?q=S.%20L.%20Iconaru"> S. L. Iconaru</a>, <a href="https://publications.waset.org/abstracts/search?q=A.%20Costescu"> A. Costescu</a>, <a href="https://publications.waset.org/abstracts/search?q=C.%20S.%20Ciobanu"> C. S. Ciobanu</a>, <a href="https://publications.waset.org/abstracts/search?q=M.%20Motelica%20Heino"> M. Motelica Heino</a>, <a href="https://publications.waset.org/abstracts/search?q=R.%20Guegan"> R. Guegan</a>, <a href="https://publications.waset.org/abstracts/search?q=D.%20Predoi"> D. Predoi</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Surface functionalization of ceramic composites with a special focus on tetraethyl orthosilicate (TEOS) and hydroxyapatite (HAp) is discoursed. Mesoporous ceramic HAp-TEOS composites were prepared by the incorporation of hydroxyapatite into tetraethyl orthosilicate by sol-gel method. The resulting samples were analysed by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared (FT-IR) spectroscopy, and Raman spectroscopy and nitrogen physisorption. The removal of Pb2+ ions from aqueous solutions was evaluated using Atomic Absorbtion Spectroscopy (AAS). Removal experiments of Pb2+ ions were carried out in aqueous solutions with controlled Pb2+ at pH ~ 3 and pH ~ 5. After removal experiment of Pb2+ at pH 3 and pH 5, porous hydroxyapatite nanoparticles is transformed into PbHAp_3 and PbHAp_5 via the adsorption of Pb2+ ions followed by the cation exchange reaction. The diffraction patterns show that THAp nanoparticles were successfully coated with teos without any structural changes. On the other, the AAS analysis showed that THAp can be useful in the removal Pb2+ from water contaminated. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=teos" title="teos">teos</a>, <a href="https://publications.waset.org/abstracts/search?q=hydroxyapatite" title=" hydroxyapatite"> hydroxyapatite</a>, <a href="https://publications.waset.org/abstracts/search?q=environment%20applications" title=" environment applications"> environment applications</a>, <a href="https://publications.waset.org/abstracts/search?q=biosystems%20engineering" title=" biosystems engineering"> biosystems engineering</a> </p> <a href="https://publications.waset.org/abstracts/2457/ceramic-composites-and-its-applications-for-pb-adsorption" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/2457.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">384</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">132</span> Preparation and Performance of Polyphenylene Oxide-Based Anion Exchange Membrane for Vanadium Redox Flow Battery</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Mi-Jung%20Park">Mi-Jung Park</a>, <a href="https://publications.waset.org/abstracts/search?q=Min-Hwa%20Lim"> Min-Hwa Lim</a>, <a href="https://publications.waset.org/abstracts/search?q=Ho-Young%20Jung"> Ho-Young Jung</a> </p> <p class="card-text"><strong>Abstract:</strong></p> A polyphenylene oxide (PPO)-based anion exchange membrane based on the functionalization of bromomethylated PPO using 1-methylimdazole was fabricated for vanadium redox flow application. The imidazolium-bromomethylated PPO (Im-bPPO) showed lower permeability VO2+ ions (2.9×10⁻¹⁴ m²/sec), compared to Nafion 212 (2.3×10⁻¹² m²/sec) and FAP-450 (7.9×10⁻¹⁴ m²/sec). Even though the Im-bPPO membrane has higher permeability, the energy efficiency of the VRFB with the Im-bPPO membrane was slightly lower than that of Nafion and FAP-450. The Im-bPPO membrane exhibits good voltage efficiency compared to FAP-450 and Nafion 212 because of its better ion conductivity. The Im-bPPo membrane showed up good performance, but a decline in performance at later cycles was observed. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=anion%20exchange%20membranes" title="anion exchange membranes">anion exchange membranes</a>, <a href="https://publications.waset.org/abstracts/search?q=vanadium%20redox%20flow%20battery" title=" vanadium redox flow battery"> vanadium redox flow battery</a>, <a href="https://publications.waset.org/abstracts/search?q=polyphenylene%20oxide" title=" polyphenylene oxide"> polyphenylene oxide</a>, <a href="https://publications.waset.org/abstracts/search?q=energy%20efficiency%20%28EE%29" title=" energy efficiency (EE)"> energy efficiency (EE)</a> </p> <a href="https://publications.waset.org/abstracts/49988/preparation-and-performance-of-polyphenylene-oxide-based-anion-exchange-membrane-for-vanadium-redox-flow-battery" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/49988.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">317</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">131</span> Kinetic Modeling of Transesterification of Triacetin Using Synthesized Ion Exchange Resin (SIERs) </h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Hafizuddin%20W.%20Yussof">Hafizuddin W. Yussof</a>, <a href="https://publications.waset.org/abstracts/search?q=Syamsutajri%20S.%20Bahri"> Syamsutajri S. Bahri</a>, <a href="https://publications.waset.org/abstracts/search?q=Adam%20P.%20Harvey"> Adam P. Harvey</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Strong anion exchange resins with QN+OH-, have the potential to be developed and employed as heterogeneous catalyst for transesterification, as they are chemically stable to leaching of the functional group. Nine different SIERs (SIER1-9) with QN+OH- were prepared by suspension polymerization of vinylbenzyl chloride-divinylbenzene (VBC-DVB) copolymers in the presence of n-heptane (pore-forming agent). The amine group was successfully grafted into the polymeric resin beads through functionalization with trimethylamine. These SIERs are then used as a catalyst for the transesterification of triacetin with methanol. A set of differential equations that represents the Langmuir-Hinshelwood-Hougen-Watson (LHHW) and Eley-Rideal (ER) models for the transesterification reaction were developed. These kinetic models of LHHW and ER were fitted to the experimental data. Overall, the synthesized ion exchange resin-catalyzed reaction were well-described by the Eley-Rideal model compared to LHHW models, with sum of square error (SSE) of 0.742 and 0.996, respectively. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=anion%20exchange%20resin" title="anion exchange resin">anion exchange resin</a>, <a href="https://publications.waset.org/abstracts/search?q=Eley-Rideal" title=" Eley-Rideal"> Eley-Rideal</a>, <a href="https://publications.waset.org/abstracts/search?q=Langmuir-Hinshelwood-Hougen-Watson" title=" Langmuir-Hinshelwood-Hougen-Watson"> Langmuir-Hinshelwood-Hougen-Watson</a>, <a href="https://publications.waset.org/abstracts/search?q=transesterification" title=" transesterification "> transesterification </a> </p> <a href="https://publications.waset.org/abstracts/13977/kinetic-modeling-of-transesterification-of-triacetin-using-synthesized-ion-exchange-resin-siers" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/13977.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">362</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">130</span> One-Step Synthesis of Fluorescent Carbon Dots in a Green Way as Effective Fluorescent Probes for Detection of Iron Ions and pH Value</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Mostafa%20Ghasemi">Mostafa Ghasemi</a>, <a href="https://publications.waset.org/abstracts/search?q=Andrew%20Urquhart"> Andrew Urquhart</a> </p> <p class="card-text"><strong>Abstract:</strong></p> In this study, fluorescent carbon dots (CDs) were synthesized in a green way using a one-step hydrothermal method. Carbon dots are carbon-based nanomaterials with a size of less than 10 nm, unique structure, and excellent properties such as low toxicity, good biocompatibility, tunable fluorescence, excellent photostability, and easy functionalization. These properties make them a good candidate to use in different fields such as biological sensing, photocatalysis, photodynamic, and drug delivery. Fourier transformed infrared (FTIR) spectra approved OH/NH groups on the surface of the as-synthesized CDs, and UV-vis spectra showed excellent fluorescence quenching effect of Fe (III) ion on the as-synthesized CDs with high selectivity detection compared with other metal ions. The probe showed a linear response concentration range (0–2.0 mM) to Fe (III) ion, and the limit of detection was calculated to be about 0.50 μM. In addition, CDs also showed good sensitivity to the pH value in the range from 2 to 14, indicating great potential as a pH sensor. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=carbon%20dots" title="carbon dots">carbon dots</a>, <a href="https://publications.waset.org/abstracts/search?q=fluorescence" title=" fluorescence"> fluorescence</a>, <a href="https://publications.waset.org/abstracts/search?q=pH%20sensing" title=" pH sensing"> pH sensing</a>, <a href="https://publications.waset.org/abstracts/search?q=metal%20ions%20sensor" title=" metal ions sensor"> metal ions sensor</a> </p> <a href="https://publications.waset.org/abstracts/176075/one-step-synthesis-of-fluorescent-carbon-dots-in-a-green-way-as-effective-fluorescent-probes-for-detection-of-iron-ions-and-ph-value" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/176075.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">75</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">129</span> Evaluation of Iron Oxide-Functionalized Multiwall Carbon Nanotube Self-Standing Electrode for Symmetric Supercapacitor Application</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=B.%20V.%20Bhaskara%20Rao">B. V. Bhaskara Rao</a>, <a href="https://publications.waset.org/abstracts/search?q=Rodrigo%20Espinoza"> Rodrigo Espinoza</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The rapid development of renewable energy sources has drawn great attention to energy storage devices, especially supercapacitors, because of their high power density and rate performance. This work focus on Fe₃O₄ nanoparticles synthesized by reverse co-precipitation and MWCNTs functionalized by –COOH acid functionalization. The results show that Optimized 25wt% Fe₃O₄@FMWCNT show high specific capacitance 100 mF/cm² at one mA/cm² whereas 15wt% Fe₃O₄@FMWCNT showed high stability (80% retention capacity) over 5000 cycles. The electrolyte used in the coin cell is LiPF6 and the thickness of the electrode is 30 microns. The optimized Fe₃O₄@FMWCNT bucky papers coin cell electrochemical studies suggest that 25wt% Fe₃O₄@FMWCNT could be a good candidate for high-capacity supercapacitor devices. This could be further tested for flexible and planar supercapacitor device application with gel electrolytes. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=self-standing%20electrode" title="self-standing electrode">self-standing electrode</a>, <a href="https://publications.waset.org/abstracts/search?q=Fe%E2%82%83O4%40FMWCNT" title=" Fe₃O4@FMWCNT"> Fe₃O4@FMWCNT</a>, <a href="https://publications.waset.org/abstracts/search?q=supercapacitor" title=" supercapacitor"> supercapacitor</a>, <a href="https://publications.waset.org/abstracts/search?q=symmetric%20coin-cell" title=" symmetric coin-cell"> symmetric coin-cell</a> </p> <a href="https://publications.waset.org/abstracts/143024/evaluation-of-iron-oxide-functionalized-multiwall-carbon-nanotube-self-standing-electrode-for-symmetric-supercapacitor-application" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/143024.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">156</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">128</span> Adsorption of Iodine from Aqueous Solution on Modified Silica Gel with Cyclodextrin Derivatives</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Raied">Raied</a>, <a href="https://publications.waset.org/abstracts/search?q=Badr%20Al-Fulaiti"> Badr Al-Fulaiti</a>, <a href="https://publications.waset.org/abstracts/search?q=E.%20I.%20El-Shafey"> E. I. El-Shafey</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Cyclodextrin (CD) derivatives (αCD, βCD, ϒCD and hp-βCD) were successfully immobilized on silica gel surface via epichlorohydrin as a cross linker. The ratio of silica to CD was optimized in preliminary experiments based on best performance of iodine adsorption capacity. Selected adsorbents with ratios of silica to CD derivatives, in this study, include Si-αCD (3:2), Si-βCD (4:1), Si-ϒCD (4:1) and Si-hp-βCD (4:1). The adsorption of iodine (I2/KI) solution was investigated in terms of initial pH, contact time, iodine concentration and temperature. No significant variations was noticed for iodine adsorption at different pH values, thus, initial pH 6 was selected for further studies. Equilibrium adsorption was reached faster on Si-hp-βCD than other adsorbents with kinetic adsorption data fitting well pseudo second order model. Activation energy (Ea) was found to be in the range of 12.7 - 23.4 kJ/mol. Equilibrium adsorption data were found to fit well the Langmuir adsorption model with lower uptake as temperature rises. Iodine uptake follows the order: Si-hp-βCD (714 mg/g) >Si-αCD (625 mg/g) >Si-βCD (555.6 mg/g)> Si-ϒCD (435 mg/g). Thermodynamic study showed that iodine adsorption is exothermic and spontaneous. Adsorbents reuse exhibited excellent performance for iodine adsorption with a decrease in iodine uptake of ~ 2- 4 % in the third adsorption cycle. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=adsorption" title="adsorption">adsorption</a>, <a href="https://publications.waset.org/abstracts/search?q=iodine" title=" iodine"> iodine</a>, <a href="https://publications.waset.org/abstracts/search?q=silica" title=" silica"> silica</a>, <a href="https://publications.waset.org/abstracts/search?q=cyclodextrin" title=" cyclodextrin"> cyclodextrin</a>, <a href="https://publications.waset.org/abstracts/search?q=functionalization" title=" functionalization"> functionalization</a>, <a href="https://publications.waset.org/abstracts/search?q=epichlorohydrin" title=" epichlorohydrin"> epichlorohydrin</a> </p> <a href="https://publications.waset.org/abstracts/144749/adsorption-of-iodine-from-aqueous-solution-on-modified-silica-gel-with-cyclodextrin-derivatives" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/144749.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">132</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">127</span> A Cheap Mesoporous Silica from Fly Ash as an Adsorbent for Sulfate in Water</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Ximena%20Castillo">Ximena Castillo</a>, <a href="https://publications.waset.org/abstracts/search?q=Jaime%20Pizarro"> Jaime Pizarro</a> </p> <p class="card-text"><strong>Abstract:</strong></p> This research describes the development of a very cheap mesoporous silica material similar to hexagonal mesoporous silica (HMS) and using a silicate extract as precursor. This precursor is obtained from cheap fly ash by an easy calcination process at 850 °C and a green extraction with water. The obtained mesoporous fly ash material had a surface area of 282 m2 g-1 and a pore size of 5.7 nm. It was functionalized with ethylene diamino moieties via the well-known SAMMS method, followed by a DRIFT analysis that clearly showed the successful functionalization. An excellent adsorbent was obtained for the adsorption of sulfate anions by the solid’s modification with copper forming a copper-ethylenediamine complex. The adsorption of sulfates was studied in a batch system ( experimental conditions: pH=8.0; 5 min). The kinetics data were adjusted according to a pseudo-second order model with a high coefficient of linear regression at different initial concentrations. The adsorption isotherm that best fitted the experimental data was the Freundlich model. The maximum sulfate adsorption capacity of this very cheap fly ash based adsorbent was 146.1 mg g-1, 3 times greater than the values reported in literature and commercial adsorbent materials. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=fly%20ash" title="fly ash">fly ash</a>, <a href="https://publications.waset.org/abstracts/search?q=mesoporous%20materials" title=" mesoporous materials"> mesoporous materials</a>, <a href="https://publications.waset.org/abstracts/search?q=SAMMS" title=" SAMMS"> SAMMS</a>, <a href="https://publications.waset.org/abstracts/search?q=sulfate" title=" sulfate"> sulfate</a> </p> <a href="https://publications.waset.org/abstracts/95487/a-cheap-mesoporous-silica-from-fly-ash-as-an-adsorbent-for-sulfate-in-water" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/95487.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">177</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">126</span> Chemical Stability and Characterization of Ion Exchange Membranes for Vanadium Redox Flow Batteries</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Min-Hwa%20Lim">Min-Hwa Lim</a>, <a href="https://publications.waset.org/abstracts/search?q=Mi-Jeong%20Park"> Mi-Jeong Park</a>, <a href="https://publications.waset.org/abstracts/search?q=Ho-Young%20Jung"> Ho-Young Jung</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Imidazolium-brominated polyphenylene oxide (Im-bPPO) is based on the functionalization of bromomethylated poly(2,6-dimethyl-1,4-phenylene oxide) (BPPO) using 1-Methylimdazole. For the purpose of long cycle life of vanadium redox battery (VRB), the chemical stability of Im-bPPO, sPPO (sulfonated 2,6-dimethyl-1,4-phenylene oxide) and Fumatech membranes were evaluated firstly in the 0.1M vanadium (V) solution dissolved in 3M sulfuric acid (H2SO4) for 72h, and UV analyses of the degradation products proved that ether bond in PPO backbone was vulnerable to be attacked by vanadium (V) ion. It was found that the membranes had slightly weight loss after soaking in 2 ml distilled water included in STS pressure vessel for 1 day at 200◦C. ATR-FT-IR data indicated before and after the degradation of the membranes. Further evaluation on the degradation mechanism of the menbranes were carried out in Fenton’s reagent solution for 72 h at 50 ◦C and analyses of the membranes before and after degradation confirmed the weight loss of the membranes. The Fumatech membranes exhibited better performance than AEM and CEM, but Nafion 212 still suffers chemical degradation. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=vanadium%20redox%20flow%20battery" title="vanadium redox flow battery">vanadium redox flow battery</a>, <a href="https://publications.waset.org/abstracts/search?q=ion%20exchange%20membrane" title=" ion exchange membrane"> ion exchange membrane</a>, <a href="https://publications.waset.org/abstracts/search?q=permeability" title=" permeability"> permeability</a>, <a href="https://publications.waset.org/abstracts/search?q=degradation" title=" degradation"> degradation</a>, <a href="https://publications.waset.org/abstracts/search?q=chemical%20stability" title=" chemical stability"> chemical stability</a> </p> <a href="https://publications.waset.org/abstracts/44968/chemical-stability-and-characterization-of-ion-exchange-membranes-for-vanadium-redox-flow-batteries" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/44968.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">300</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">125</span> Synthesis, Structural Characterization and Biological Activity of Bis{(E)-1-[(2,4,6-Tribromophenyl) Diazenyl] Naphthalen-2-Olato} Copper (II) Dimethyl Sulfoxide Monosolvate</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Hassiba%20Bougueria">Hassiba Bougueria</a>, <a href="https://publications.waset.org/abstracts/search?q=Nesrine%20Benarous"> Nesrine Benarous</a>, <a href="https://publications.waset.org/abstracts/search?q=Souheyla%20Chetioui"> Souheyla Chetioui</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Azo dyes are one of the most widely used compounds in organic chemistry, primarily due to their relatively simple preparation methods. They have therefore been widely used, in particular as colorants for textiles, printing inks, cosmetics, and food additives. In addition to their use as dyes, azo compounds have attracted much attention from chemists as their potential applications are important in coordination chemistry, metal-organic frameworks (MOF) structures, COF (covalent-organic frameworks), and catalysis. Moreover, they have found many applications in different fields, such as nonlinear optics, optical storage, photoluminescence, and magnetism. The compound bis{(E)-1-[(2,4,6-tribromophenyl)diazenyl]naphthalen-2-olato}copper(II) dimethyl sulfoxide monosolvate, the CuII atom is tetracoordinate with a square-planar geometry, surrounded by two bidentate (E)-1-[(2,4,6-tribromophenyl)diazenyl]naphthalene-2-olate ligands via two N atoms and two O atoms. The O-Cu-O angles and N-Cu-N are of the order of 177.90(16)° and 177.8(2)°, respectively. The distances Cu-O and Cu- N are 1.892(4) Å and 1.976(4) Å, respectively. The cohesion of the crystal is ensured by hydrogen bonds of the C—H…O type and by π=π staking interactions [centroid–centroid distance = 3.679(4)Å]. The DMSO solvent molecule is disordered at two positions with occupancy rates of 0.70 and 0.30. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=azo%20dyes" title="azo dyes">azo dyes</a>, <a href="https://publications.waset.org/abstracts/search?q=DRX" title=" DRX"> DRX</a>, <a href="https://publications.waset.org/abstracts/search?q=structural%20characterization" title=" structural characterization"> structural characterization</a>, <a href="https://publications.waset.org/abstracts/search?q=biological%20activity" title=" biological activity"> biological activity</a> </p> <a href="https://publications.waset.org/abstracts/158136/synthesis-structural-characterization-and-biological-activity-of-bise-1-246-tribromophenyl-diazenyl-naphthalen-2-olato-copper-ii-dimethyl-sulfoxide-monosolvate" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/158136.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">87</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">124</span> Peptide Aptasensor for Electrochemical Detection of Rheumatoid Arthritis </h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Shah%20Abbas">Shah Abbas</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Rheumatoid arthritis is a systemic, inflammatory autoimmune disease, affecting an overall 1% of the global population. Despite being tremendous efforts by scientists, early diagnosis of RA still has not been achieved. In the current study, a Graphene oxide (GO) based electrochemical sensor has been developed for early diagnosis of RA through Cyclic voltammetry. Chitosan (CHI), a CPnatural polymer has also been incorporated along with GO in order to enhance the biocompatibility and functionalization potential of the biosensor. CCPs are known antigens for Anti Citrullinated Peptide Antibodies (ACPAs) which can be detected in serum even 14 years before the appearance of symptoms, thus they are believed to be an ideal target for the early diagnosis of RA. This study has yielded some promising results regarding the binding and detection of ACPAs through changes in the electrochemical properties of biosensing material. The cyclic voltammogram of this biosensor reflects the binding of ACPAs to the biosensor surface, due to its shifts observed in the current flow (cathodic current) as compared to the when no ACPAs bind as it is absent in RA negative patients. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=rheumatoid%20arthritis" title="rheumatoid arthritis">rheumatoid arthritis</a>, <a href="https://publications.waset.org/abstracts/search?q=peptide%20sensor" title=" peptide sensor"> peptide sensor</a>, <a href="https://publications.waset.org/abstracts/search?q=graphene%20oxide" title=" graphene oxide"> graphene oxide</a>, <a href="https://publications.waset.org/abstracts/search?q=anti%20citrullinated%20peptide%20antibodies" title=" anti citrullinated peptide antibodies"> anti citrullinated peptide antibodies</a>, <a href="https://publications.waset.org/abstracts/search?q=cyclic%20voltammetry" title=" cyclic voltammetry"> cyclic voltammetry</a> </p> <a href="https://publications.waset.org/abstracts/125129/peptide-aptasensor-for-electrochemical-detection-of-rheumatoid-arthritis" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/125129.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">143</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">123</span> Preparation of Superparamagnetic Functionalized Magnetite Nanoparticles for Magnetically Separable Catalysis </h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Priya%20Arora">Priya Arora</a>, <a href="https://publications.waset.org/abstracts/search?q=Jaspreet%20K.%20Rajput"> Jaspreet K. Rajput</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Superparamagnetism has accelerated the research and use of more economical and ecological magnetically separable catalysts due to their more efficient isolation by response to an applied magnetic field. Magnetite nanomaterials coated by SiO2 shell have received a great deal of focus in the last decades as it provides high stability and also easy further surface functionalization depending upon the application. In this protocol, Fe3O4 magnetic nanoparticles have been synthesized by co-precipitation combined with sonication method. Further, Fe3O4 superparamagnetic nanoparticles have been functionalized by various moieties to serve as efficient catalysts for multicomponent reactions. The functionalized nanoparticles were characterized by techniques like Fourier transform infrared spectroscopy (FT-IR), transmission electron microscopy (TEM), scanning electron microscopy (SEM), vibrating sample magnetometer (VSM), thermogravimetric analysis (TGA), Brunauer-Emmett-Teller (BET) surface area analysis. The as prepared nanocatalysts can be reused for several times without any significant loss in its activity. The utilization of magnetic nanoparticles as catalysts for this reaction is one approach i.e. green, inexpensive, facile and widely applicable. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=functionalized" title="functionalized">functionalized</a>, <a href="https://publications.waset.org/abstracts/search?q=magnetite" title=" magnetite"> magnetite</a>, <a href="https://publications.waset.org/abstracts/search?q=multicomponent%20reactions" title=" multicomponent reactions"> multicomponent reactions</a>, <a href="https://publications.waset.org/abstracts/search?q=superparamagnetic" title=" superparamagnetic"> superparamagnetic</a> </p> <a href="https://publications.waset.org/abstracts/55353/preparation-of-superparamagnetic-functionalized-magnetite-nanoparticles-for-magnetically-separable-catalysis" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/55353.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">340</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">122</span> First-Principles Study of Inter-Cage Interactions in Inorganic Molecular Crystals</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Abdul%20Majid">Abdul Majid</a>, <a href="https://publications.waset.org/abstracts/search?q=Alia%20Jabeen"> Alia Jabeen</a>, <a href="https://publications.waset.org/abstracts/search?q=Nimra%20Zulifqar"> Nimra Zulifqar</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The inorganic molecular crystal (IMCs) due to their unusual structure has grabbed a lot of attention due to anisotropy in crystal structure. The IMCs consist of the molecular structures joined together via weak forces. Therefore, a difference between the bonding between the inter-cage and intra-cage interactions exists. To look closely at the bonding and interactions, we investigated interactions between two cages of Sb2O3 structure. The interactions were characterized via Extended Transition State-Natural Orbital for Chemical Valence-method (ETS-NOCV), Natural Bond Orbitals (NBO) and Quantum Theory of Atoms in Molecules (QTAIM). The results revealed strong intra-cage covalent bonding while weak van der Waals (vdWs) interactions along inter-cages exits. This structure cannot be termed as layered material although they have anisotropy in bonding and presence of weak vdWs interactions but its bulk is termed as inorganic layered clusters. This is due to the fact that the free standing sheet/films with these materials are not possible. This type of structures may be the most feasible to be used for the system to deal with high pressures and stress bearing materials. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=inorganic%20molecular%20crystals" title="inorganic molecular crystals">inorganic molecular crystals</a>, <a href="https://publications.waset.org/abstracts/search?q=density%20functional%20theory" title=" density functional theory"> density functional theory</a>, <a href="https://publications.waset.org/abstracts/search?q=cages" title=" cages"> cages</a>, <a href="https://publications.waset.org/abstracts/search?q=interactions" title=" interactions"> interactions</a> </p> <a href="https://publications.waset.org/abstracts/161848/first-principles-study-of-inter-cage-interactions-in-inorganic-molecular-crystals" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/161848.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">95</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">121</span> Nanotechnology-Based Treatment of Liver Cancer</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Lucian%20Mocan">Lucian Mocan</a> </p> <p class="card-text"><strong>Abstract:</strong></p> We present method of Nanoparticle enhanced laser thermal ablation of HepG2 cells (Human hepatocellular liver carcinomacell line), using gold nanoparticles combuned with a specific growth factor and demonstrate its selective therapeutic efficacy usig ex vivo specimens. Ex vivo-perfused liver specimens were obtained from hepatocellular carcinoma patients similarly to the surgical technique of transplantation. Ab bound to GNPs was inoculated intra-arterially onto the resulting specimen and determined the specific delivery of the nano-bioconjugate into the malignant tissue by means of the capillary bed. The extent of necrosis was considerable following laser therapy and at the same time surrounding parenchyma was not seriously affected. The selective photothermal ablation of the malignant liver tissue was obtained after the selective accumulation of Ab bound to GNPs into tumor cells following ex-vivo intravascular perfusion. These unique results may represent a major step in liver cancer treatment using nanolocalized thermal ablation by laser heating. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=HepG2%20cells" title="HepG2 cells">HepG2 cells</a>, <a href="https://publications.waset.org/abstracts/search?q=gold%20nanoparticles" title=" gold nanoparticles"> gold nanoparticles</a>, <a href="https://publications.waset.org/abstracts/search?q=nanoparticle%20functionalization" title=" nanoparticle functionalization"> nanoparticle functionalization</a>, <a href="https://publications.waset.org/abstracts/search?q=laser%20irradiation" title=" laser irradiation"> laser irradiation</a> </p> <a href="https://publications.waset.org/abstracts/66957/nanotechnology-based-treatment-of-liver-cancer" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/66957.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">368</span> </span> </div> </div> <ul class="pagination"> <li class="page-item"><a class="page-link" href="https://publications.waset.org/abstracts/search?q=covalent%20functionalization&page=3" rel="prev">&lsaquo;</a></li> <li class="page-item"><a class="page-link" href="https://publications.waset.org/abstracts/search?q=covalent%20functionalization&page=1">1</a></li> <li class="page-item"><a class="page-link" href="https://publications.waset.org/abstracts/search?q=covalent%20functionalization&page=2">2</a></li> <li class="page-item"><a class="page-link" href="https://publications.waset.org/abstracts/search?q=covalent%20functionalization&page=3">3</a></li> <li class="page-item active"><span class="page-link">4</span></li> <li class="page-item"><a class="page-link" href="https://publications.waset.org/abstracts/search?q=covalent%20functionalization&page=5">5</a></li> <li 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