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vector-pinnable-header-pinned" data-feature-name="toc-pinned" data-pinnable-element-id="vector-toc" > <h2 class="vector-pinnable-header-label">Sadržaj</h2> <button class="vector-pinnable-header-toggle-button vector-pinnable-header-pin-button" data-event-name="pinnable-header.vector-toc.pin">premjesti na bočnu traku</button> <button class="vector-pinnable-header-toggle-button vector-pinnable-header-unpin-button" data-event-name="pinnable-header.vector-toc.unpin">sakrij</button> </div> <ul class="vector-toc-contents" id="mw-panel-toc-list"> <li id="toc-mw-content-text" class="vector-toc-list-item vector-toc-level-1"> <a href="#" class="vector-toc-link"> <div class="vector-toc-text">Početak</div> </a> </li> <li id="toc-Historija" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#Historija"> <div class="vector-toc-text"> <span class="vector-toc-numb">1</span> <span>Historija</span> </div> </a> <ul id="toc-Historija-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-Svojstvba_agostičnih_veza" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#Svojstvba_agostičnih_veza"> <div class="vector-toc-text"> <span class="vector-toc-numb">2</span> <span>Svojstvba agostičnih veza</span> </div> </a> <button aria-controls="toc-Svojstvba_agostičnih_veza-sublist" class="cdx-button cdx-button--weight-quiet cdx-button--icon-only vector-toc-toggle"> <span class="vector-icon mw-ui-icon-wikimedia-expand"></span> <span>Uključi/isključi podsekciju Svojstvba agostičnih veza</span> </button> <ul id="toc-Svojstvba_agostičnih_veza-sublist" class="vector-toc-list"> <li id="toc-Jačina_veza" class="vector-toc-list-item vector-toc-level-2"> <a class="vector-toc-link" href="#Jačina_veza"> <div class="vector-toc-text"> <span class="vector-toc-numb">2.1</span> <span>Jačina veza</span> </div> </a> <ul id="toc-Jačina_veza-sublist" class="vector-toc-list"> </ul> </li> </ul> </li> <li id="toc-Interakcije_sličnih_veza" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#Interakcije_sličnih_veza"> <div class="vector-toc-text"> <span class="vector-toc-numb">3</span> <span>Interakcije sličnih veza</span> </div> </a> <button aria-controls="toc-Interakcije_sličnih_veza-sublist" class="cdx-button cdx-button--weight-quiet cdx-button--icon-only vector-toc-toggle"> <span class="vector-icon mw-ui-icon-wikimedia-expand"></span> <span>Uključi/isključi podsekciju Interakcije sličnih veza</span> </button> <ul id="toc-Interakcije_sličnih_veza-sublist" class="vector-toc-list"> <li id="toc-Anagostne_veze" class="vector-toc-list-item vector-toc-level-2"> <a class="vector-toc-link" href="#Anagostne_veze"> <div class="vector-toc-text"> <span class="vector-toc-numb">3.1</span> <span>Anagostne veze</span> </div> </a> <ul id="toc-Anagostne_veze-sublist" class="vector-toc-list"> </ul> </li> </ul> </li> <li id="toc-Funkcija" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#Funkcija"> <div class="vector-toc-text"> <span class="vector-toc-numb">4</span> <span>Funkcija</span> </div> </a> <ul id="toc-Funkcija-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-Također_pogledajte" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#Također_pogledajte"> <div class="vector-toc-text"> <span class="vector-toc-numb">5</span> <span>Također pogledajte</span> </div> </a> <ul id="toc-Također_pogledajte-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-Reference" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#Reference"> <div class="vector-toc-text"> <span class="vector-toc-numb">6</span> <span>Reference</span> </div> </a> <ul id="toc-Reference-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-Vanjski_linkovi" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#Vanjski_linkovi"> <div class="vector-toc-text"> <span class="vector-toc-numb">7</span> <span>Vanjski linkovi</span> </div> </a> <ul id="toc-Vanjski_linkovi-sublist" class="vector-toc-list"> </ul> </li> </ul> </div> </div> </nav> </div> </div> <div class="mw-content-container"> <main id="content" class="mw-body"> <header class="mw-body-header vector-page-titlebar"> <nav aria-label="Sadržaj" class="vector-toc-landmark"> <div id="vector-page-titlebar-toc" class="vector-dropdown vector-page-titlebar-toc vector-button-flush-left" title="Sadržaj" > <input type="checkbox" id="vector-page-titlebar-toc-checkbox" role="button" aria-haspopup="true" data-event-name="ui.dropdown-vector-page-titlebar-toc" class="vector-dropdown-checkbox " aria-label="Uključi/isključi sadržaj" > <label id="vector-page-titlebar-toc-label" for="vector-page-titlebar-toc-checkbox" class="vector-dropdown-label cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--icon-only " aria-hidden="true" ><span class="vector-icon mw-ui-icon-listBullet mw-ui-icon-wikimedia-listBullet"></span> <span class="vector-dropdown-label-text">Uključi/isključi sadržaj</span> </label> <div class="vector-dropdown-content"> <div id="vector-page-titlebar-toc-unpinned-container" class="vector-unpinned-container"> </div> </div> </div> </nav> <h1 id="firstHeading" class="firstHeading mw-first-heading"><span class="mw-page-title-main">Agostična interakcija</span></h1> <div id="p-lang-btn" class="vector-dropdown mw-portlet mw-portlet-lang" > <input type="checkbox" id="p-lang-btn-checkbox" role="button" aria-haspopup="true" data-event-name="ui.dropdown-p-lang-btn" class="vector-dropdown-checkbox mw-interlanguage-selector" aria-label="Idi na članak na drugom jeziku. Dostupno na 13 jezika" > <label id="p-lang-btn-label" for="p-lang-btn-checkbox" class="vector-dropdown-label cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--action-progressive mw-portlet-lang-heading-13" aria-hidden="true" ><span class="vector-icon mw-ui-icon-language-progressive mw-ui-icon-wikimedia-language-progressive"></span> <span class="vector-dropdown-label-text">13 jezika</span> </label> <div class="vector-dropdown-content"> <div class="vector-menu-content"> <ul class="vector-menu-content-list"> <li class="interlanguage-link interwiki-ar mw-list-item"><a href="https://ar.wikipedia.org/wiki/%D8%AA%D8%A2%D8%AB%D8%B1_%D8%B6%D8%A7%D9%85" title="تآثر ضام – arapski" lang="ar" hreflang="ar" data-title="تآثر ضام" data-language-autonym="العربية" data-language-local-name="arapski" class="interlanguage-link-target"><span>العربية</span></a></li><li class="interlanguage-link interwiki-ca mw-list-item"><a href="https://ca.wikipedia.org/wiki/Interacci%C3%B3_ag%C3%B2stica" title="Interacció agòstica – katalonski" lang="ca" hreflang="ca" data-title="Interacció agòstica" data-language-autonym="Català" data-language-local-name="katalonski" class="interlanguage-link-target"><span>Català</span></a></li><li class="interlanguage-link interwiki-de mw-list-item"><a href="https://de.wikipedia.org/wiki/Agostische_Wechselwirkung" title="Agostische Wechselwirkung – njemački" lang="de" hreflang="de" data-title="Agostische Wechselwirkung" data-language-autonym="Deutsch" data-language-local-name="njemački" class="interlanguage-link-target"><span>Deutsch</span></a></li><li class="interlanguage-link interwiki-en mw-list-item"><a href="https://en.wikipedia.org/wiki/Agostic_interaction" title="Agostic interaction – engleski" lang="en" hreflang="en" data-title="Agostic interaction" data-language-autonym="English" data-language-local-name="engleski" class="interlanguage-link-target"><span>English</span></a></li><li class="interlanguage-link interwiki-es mw-list-item"><a href="https://es.wikipedia.org/wiki/Interacci%C3%B3n_ag%C3%B3stica" title="Interacción agóstica – španski" lang="es" hreflang="es" data-title="Interacción agóstica" data-language-autonym="Español" data-language-local-name="španski" class="interlanguage-link-target"><span>Español</span></a></li><li class="interlanguage-link interwiki-fr mw-list-item"><a href="https://fr.wikipedia.org/wiki/Interaction_agostique" title="Interaction agostique – francuski" lang="fr" hreflang="fr" data-title="Interaction agostique" data-language-autonym="Français" data-language-local-name="francuski" class="interlanguage-link-target"><span>Français</span></a></li><li class="interlanguage-link interwiki-id mw-list-item"><a href="https://id.wikipedia.org/wiki/Interaksi_agostik" title="Interaksi agostik – indonezijski" lang="id" hreflang="id" data-title="Interaksi agostik" data-language-autonym="Bahasa Indonesia" data-language-local-name="indonezijski" class="interlanguage-link-target"><span>Bahasa Indonesia</span></a></li><li class="interlanguage-link interwiki-it mw-list-item"><a href="https://it.wikipedia.org/wiki/Interazione_agostica" title="Interazione agostica – italijanski" lang="it" hreflang="it" data-title="Interazione agostica" data-language-autonym="Italiano" data-language-local-name="italijanski" class="interlanguage-link-target"><span>Italiano</span></a></li><li class="interlanguage-link interwiki-ja mw-list-item"><a href="https://ja.wikipedia.org/wiki/%E3%82%A2%E3%82%B4%E3%82%B9%E3%83%86%E3%82%A3%E3%83%83%E3%82%AF%E7%9B%B8%E4%BA%92%E4%BD%9C%E7%94%A8" title="アゴスティック相互作用 – japanski" lang="ja" hreflang="ja" data-title="アゴスティック相互作用" data-language-autonym="日本語" data-language-local-name="japanski" class="interlanguage-link-target"><span>日本語</span></a></li><li class="interlanguage-link interwiki-sh mw-list-item"><a href="https://sh.wikipedia.org/wiki/Agosti%C4%8Dka_interakcija" title="Agostička interakcija – srpskohrvatski" lang="sh" hreflang="sh" data-title="Agostička interakcija" data-language-autonym="Srpskohrvatski / српскохрватски" data-language-local-name="srpskohrvatski" class="interlanguage-link-target"><span>Srpskohrvatski / српскохрватски</span></a></li><li class="interlanguage-link interwiki-sr mw-list-item"><a href="https://sr.wikipedia.org/wiki/Agosti%C4%8Dka_interakcija" title="Agostička interakcija – srpski" lang="sr" hreflang="sr" data-title="Agostička interakcija" data-language-autonym="Српски / srpski" data-language-local-name="srpski" class="interlanguage-link-target"><span>Српски / srpski</span></a></li><li class="interlanguage-link interwiki-uk mw-list-item"><a href="https://uk.wikipedia.org/wiki/%D0%90%D0%B3%D0%BE%D1%81%D1%82%D0%B8%D1%87%D0%BD%D0%B0_%D0%B2%D0%B7%D0%B0%D1%94%D0%BC%D0%BE%D0%B4%D1%96%D1%8F" title="Агостична взаємодія – ukrajinski" lang="uk" hreflang="uk" data-title="Агостична взаємодія" data-language-autonym="Українська" data-language-local-name="ukrajinski" class="interlanguage-link-target"><span>Українська</span></a></li><li class="interlanguage-link interwiki-zh mw-list-item"><a href="https://zh.wikipedia.org/wiki/%E6%8A%93%E6%B0%A2%E9%94%AE" title="抓氢键 – kineski" lang="zh" hreflang="zh" data-title="抓氢键" data-language-autonym="中文" data-language-local-name="kineski" class="interlanguage-link-target"><span>中文</span></a></li> </ul> <div class="after-portlet after-portlet-lang"><span class="wb-langlinks-edit wb-langlinks-link"><a href="https://www.wikidata.org/wiki/Special:EntityPage/Q395765#sitelinks-wikipedia" title="Uredi međujezičke linkove" class="wbc-editpage">Uredi veze</a></span></div> </div> </div> </div> </header> <div class="vector-page-toolbar"> <div class="vector-page-toolbar-container"> <div id="left-navigation"> <nav aria-label="Imenski prostori"> <div id="p-associated-pages" class="vector-menu vector-menu-tabs mw-portlet mw-portlet-associated-pages" > <div class="vector-menu-content"> <ul class="vector-menu-content-list"> <li id="ca-nstab-main" class="selected vector-tab-noicon mw-list-item"><a href="/wiki/Agosti%C4%8Dna_interakcija" title="Prikaži stranicu sa sadržajem [c]" accesskey="c"><span>Stranica</span></a></li><li id="ca-talk" class="new vector-tab-noicon mw-list-item"><a href="/w/index.php?title=Razgovor:Agosti%C4%8Dna_interakcija&action=edit&redlink=1" rel="discussion" class="new" title="Razgovor o sadržaju (stranica ne postoji) [r]" accesskey="r"><span>Razgovor</span></a></li> </ul> </div> </div> <div id="vector-variants-dropdown" class="vector-dropdown emptyPortlet" > <input type="checkbox" id="vector-variants-dropdown-checkbox" role="button" aria-haspopup="true" data-event-name="ui.dropdown-vector-variants-dropdown" class="vector-dropdown-checkbox " aria-label="Promijeni varijantu jezika" > <label id="vector-variants-dropdown-label" for="vector-variants-dropdown-checkbox" class="vector-dropdown-label cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet" aria-hidden="true" ><span class="vector-dropdown-label-text">bosanski</span> </label> <div class="vector-dropdown-content"> <div id="p-variants" class="vector-menu mw-portlet mw-portlet-variants emptyPortlet" > <div class="vector-menu-content"> <ul class="vector-menu-content-list"> </ul> </div> </div> </div> </div> </nav> </div> <div id="right-navigation" class="vector-collapsible"> <nav aria-label="Pregledi"> <div id="p-views" class="vector-menu vector-menu-tabs mw-portlet mw-portlet-views" > <div class="vector-menu-content"> <ul class="vector-menu-content-list"> <li id="ca-view" class="selected vector-tab-noicon mw-list-item"><a href="/wiki/Agosti%C4%8Dna_interakcija"><span>Čitaj</span></a></li><li id="ca-ve-edit" class="vector-tab-noicon mw-list-item"><a href="/w/index.php?title=Agosti%C4%8Dna_interakcija&veaction=edit" title="Uredite ovu stranicu [v]" accesskey="v"><span>Uredi</span></a></li><li id="ca-edit" class="collapsible vector-tab-noicon mw-list-item"><a href="/w/index.php?title=Agosti%C4%8Dna_interakcija&action=edit" title="Uredite izvorni kod ove stranice [e]" accesskey="e"><span>Uredi izvor</span></a></li><li id="ca-history" class="vector-tab-noicon mw-list-item"><a href="/w/index.php?title=Agosti%C4%8Dna_interakcija&action=history" title="Prethodne izmjene ove stranice [h]" accesskey="h"><span>Historija</span></a></li> </ul> </div> </div> </nav> <nav class="vector-page-tools-landmark" aria-label="Page tools"> <div id="vector-page-tools-dropdown" class="vector-dropdown vector-page-tools-dropdown" > <input type="checkbox" id="vector-page-tools-dropdown-checkbox" role="button" aria-haspopup="true" data-event-name="ui.dropdown-vector-page-tools-dropdown" class="vector-dropdown-checkbox " aria-label="Alati" > <label id="vector-page-tools-dropdown-label" for="vector-page-tools-dropdown-checkbox" class="vector-dropdown-label cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet" aria-hidden="true" ><span class="vector-dropdown-label-text">Alati</span> </label> <div class="vector-dropdown-content"> <div id="vector-page-tools-unpinned-container" class="vector-unpinned-container"> <div id="vector-page-tools" class="vector-page-tools vector-pinnable-element"> <div class="vector-pinnable-header vector-page-tools-pinnable-header vector-pinnable-header-unpinned" data-feature-name="page-tools-pinned" data-pinnable-element-id="vector-page-tools" data-pinned-container-id="vector-page-tools-pinned-container" data-unpinned-container-id="vector-page-tools-unpinned-container" > <div class="vector-pinnable-header-label">Alati</div> <button class="vector-pinnable-header-toggle-button vector-pinnable-header-pin-button" data-event-name="pinnable-header.vector-page-tools.pin">premjesti na bočnu traku</button> <button class="vector-pinnable-header-toggle-button vector-pinnable-header-unpin-button" data-event-name="pinnable-header.vector-page-tools.unpin">sakrij</button> </div> <div id="p-cactions" class="vector-menu mw-portlet mw-portlet-cactions emptyPortlet vector-has-collapsible-items" title="More options" > <div class="vector-menu-heading"> Radnje </div> <div class="vector-menu-content"> <ul class="vector-menu-content-list"> <li id="ca-more-view" class="selected vector-more-collapsible-item mw-list-item"><a href="/wiki/Agosti%C4%8Dna_interakcija"><span>Čitaj</span></a></li><li id="ca-more-ve-edit" class="vector-more-collapsible-item mw-list-item"><a href="/w/index.php?title=Agosti%C4%8Dna_interakcija&veaction=edit" title="Uredite ovu stranicu [v]" accesskey="v"><span>Uredi</span></a></li><li id="ca-more-edit" class="collapsible vector-more-collapsible-item mw-list-item"><a href="/w/index.php?title=Agosti%C4%8Dna_interakcija&action=edit" title="Uredite izvorni kod ove stranice [e]" accesskey="e"><span>Uredi izvor</span></a></li><li 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class="noprint">S Wikipedije, slobodne enciklopedije</div> </div> <div id="contentSub"><div id="mw-content-subtitle"></div></div> <div id="mw-content-text" class="mw-body-content"><div class="mw-content-ltr mw-parser-output" lang="bs" dir="ltr"><p><b>Agostična interakcija</b> je termin <a href="/w/index.php?title=Organometalna_hemija&action=edit&redlink=1" class="new" title="Organometalna hemija (stranica ne postoji)">organometalne hemije</a> za međudjejstvo koordinativno nezasićenih <a href="/wiki/Prelazni_metal" title="Prelazni metal">tranzicijskih metala</a> sa <a href="/w/index.php?title=Ugljik-vodikova_vez&action=edit&redlink=1" class="new" title="Ugljik-vodikova vez (stranica ne postoji)">CH vezom</a> Kad se dva elektrona uključe u CH vezui, ulaze u prazan D-orbitalni tranzicijski metal, što dovodi do formiranja <a href="/w/index.php?title=Trocentarska_dvoelektronska_veza&action=edit&redlink=1" class="new" title="Trocentarska dvoelektronska veza (stranica ne postoji)">trocentarske elektronske veze</a>. Mnoge se katalitske transformacije, tj. <a href="/w/index.php?title=Oksidacijska_adicija&action=edit&redlink=1" class="new" title="Oksidacijska adicija (stranica ne postoji)">oksidacijska adicija</a> i <a href="/w/index.php?title=Redukcijska_eliminacija&action=edit&redlink=1" class="new" title="Redukcijska eliminacija (stranica ne postoji)">redukcijska eliminacija</a>, nastavljaju preko međuprodukata koje agostičke interakcije. Agostička interakcije su posmatrane u <a href="/w/index.php?title=Organometal&action=edit&redlink=1" class="new" title="Organometal (stranica ne postoji)">organometalnoj</a> hemiji u <a href="/wiki/Alkil" title="Alkil">alkil</a>, alkilidenskim i polienil <a href="/wiki/Ligand" title="Ligand">ligandima</a>.<sup id="cite_ref-<“Atkins“_1-0" class="reference"><a href="#cite_note-<“Atkins“-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup> <sup id="cite_ref-<“Whitten“_2-0" class="reference"><a href="#cite_note-<“Whitten“-2"><span class="cite-bracket">[</span>2<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-<“Petrucci“_3-0" class="reference"><a href="#cite_note-<“Petrucci“-3"><span class="cite-bracket">[</span>3<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-<“Laider“_4-0" class="reference"><a href="#cite_note-<“Laider“-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-<“Weast“_5-0" class="reference"><a href="#cite_note-<“Weast“-5"><span class="cite-bracket">[</span>5<span class="cite-bracket">]</span></a></sup> </p> <meta property="mw:PageProp/toc" /> <div class="mw-heading mw-heading2"><h2 id="Historija">Historija</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Agosti%C4%8Dna_interakcija&veaction=edit&section=1" title="Uredi odlomak "Historija"" class="mw-editsection-visualeditor"><span>uredi</span></a><span class="mw-editsection-divider"> | </span><a href="/w/index.php?title=Agosti%C4%8Dna_interakcija&action=edit&section=1" title="Edit section's source code: Historija"><span>uredi izvor</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Termin agostična, izveden je iz grčke riječi koja znači "držati blizu sebe", a skovali su ga <a href="/w/index.php?title=Maurice_Brookhart&action=edit&redlink=1" class="new" title="Maurice Brookhart (stranica ne postoji)">Maurice Brookhart</a> i <a href="/w/index.php?title=Malcolm_Green_(hemi%C4%8Dar)&action=edit&redlink=1" class="new" title="Malcolm Green (hemičar) (stranica ne postoji)">Malcolm Green</a>, na prijedlog klasicistički orijentiranog <a href="/w/index.php?title=Jasper_Griffin&action=edit&redlink=1" class="new" title="Jasper Griffin (stranica ne postoji)">Jaspera Griffina</a>, u opisivnju ove i mnogih drugih interakcija između prelaznih metala i <a href="/w/index.php?title=Ugljik-vodikova_veza&action=edit&redlink=1" class="new" title="Ugljik-vodikova veza (stranica ne postoji)">CH veza</a>. Često takve agostička interakcije uključuju alkil ili aril grupe koje se održavaju u neposrednoj blizini metalnih centara putem dodatne σ-veze.<sup id="cite_ref-Brook_6-0" class="reference"><a href="#cite_note-Brook-6"><span class="cite-bracket">[</span>6<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-7" class="reference"><a href="#cite_note-7"><span class="cite-bracket">[</span>7<span class="cite-bracket">]</span></a></sup> </p><p>Krate interakcije između ugljikovodikovih supstituenata i koordinativno nezasićenih metalnih kompleksa su primijećene od 1960-ih. Naprimjer, u tris (<a href="/w/index.php?title=Trifenilfosfin&action=edit&redlink=1" class="new" title="Trifenilfosfin (stranica ne postoji)">trifenilfosfin</a>) rutenij dihloridu kratka interakcija je uočena između centra <a href="/wiki/Rutenij" title="Rutenij">rutenija</a> (II) i atoma vodika na orto položaju jednog od devet fenil prstenova. Kristalografski su opisani brojni <a href="/w/index.php?title=Borohidrid&action=edit&redlink=1" class="new" title="Borohidrid (stranica ne postoji)">borohidridni</a> kompleksi, pomoću <a href="/w/index.php?title=Trocentarska_dvoelektroska_veza&action=edit&redlink=1" class="new" title="Trocentarska dvoelektroska veza (stranica ne postoji)">trocentarskog dvoelektronskog veznog</a> modela. </p> <figure class="mw-halign-right" typeof="mw:File/Thumb"><a href="/wiki/Datoteka:AgostKubas.png" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/c/cf/AgostKubas.png/200px-AgostKubas.png" decoding="async" width="200" height="218" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/c/cf/AgostKubas.png/300px-AgostKubas.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/c/cf/AgostKubas.png/400px-AgostKubas.png 2x" data-file-width="410" data-file-height="446" /></a><figcaption>Mo(<a href="/w/index.php?title=Tricikloheksilfosfin&action=edit&redlink=1" class="new" title="Tricikloheksilfosfin (stranica ne postoji)">PCy<sub>3</sub></a>)<sub>2</sub>(CO)<sub>3</sub> oblik agostične interakcije</figcaption></figure><p>.<sup id="cite_ref-8" class="reference"><a href="#cite_note-8"><span class="cite-bracket">[</span>8<span class="cite-bracket">]</span></a></sup> </p><div class="mw-heading mw-heading2"><h2 id="Svojstvba_agostičnih_veza"><span id="Svojstvba_agosti.C4.8Dnih_veza"></span>Svojstvba agostičnih veza</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Agosti%C4%8Dna_interakcija&veaction=edit&section=2" title="Uredi odlomak "Svojstvba agostičnih veza"" class="mw-editsection-visualeditor"><span>uredi</span></a><span class="mw-editsection-divider"> | </span><a href="/w/index.php?title=Agosti%C4%8Dna_interakcija&action=edit&section=2" title="Edit section's source code: Svojstvba agostičnih veza"><span>uredi izvor</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Agostične interakcije se najbolje ispoljavaju <a href="/wiki/Kristalografija" title="Kristalografija">kristalografski</a>. <a href="/w/index.php?title=Difrakcija_neutrona&action=edit&redlink=1" class="new" title="Difrakcija neutrona (stranica ne postoji)">Difrakcija neutrona</a> je pokazala da je udaljenosti veza C-H i M-H iznose 5-20% više nego što se očekivalo za izolirane metalne hidride i <a href="/wiki/Ugljikovodik" title="Ugljikovodik">ugljikovodik</a>. Udaljenost između metala i vodika je obično 1,8-2,3 Ǻ, a M-H-C ugao pada u rasponu 90 - 140 °. Prisustvo <sup>1</sup>H<a href="/wiki/NMR" class="mw-redirect" title="NMR">NMR</a> signala za pomjeranje gornjeg polja normalnog arila ili alkan, često u regiji normalno dobijenih <a href="/wiki/Hidrid" title="Hidrid">hidridnih</a> <a href="/wiki/Ligand" title="Ligand">liganada</a>. Spojna konstanta <sup>1</sup> J<sub>CH</sub> je obično smanjena na 70–100 Hz naspram očekivanih 125 Hz za normalnu sp<sup>3</sup> ugljik-vodonik vezu </p> <div class="mw-heading mw-heading3"><h3 id="Jačina_veza"><span id="Ja.C4.8Dina_veza"></span>Jačina veza</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Agosti%C4%8Dna_interakcija&veaction=edit&section=3" title="Uredi odlomak "Jačina veza"" class="mw-editsection-visualeditor"><span>uredi</span></a><span class="mw-editsection-divider"> | </span><a href="/w/index.php?title=Agosti%C4%8Dna_interakcija&action=edit&section=3" title="Edit section's source code: Jačina veza"><span>uredi izvor</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Na osnovu eksperimentalnih i <a href="/w/index.php?title=Ra%C4%8Dunarska_hemija&action=edit&redlink=1" class="new" title="Računarska hemija (stranica ne postoji)">računarskih</a> studija, stabilizacija koja proizilazi iz agostična interakcije se procjenjuje na oko 10-15 kcal / mol. Nedavni proračuni pomoću tački konstante, ukazuju na slabiju stabilizaciju (<10 kcal/mol). Agostične interakcije su, dakle, jači od većine <a href="/wiki/Vodikova_veza" title="Vodikova veza">vodikovih veza</a>. One ponekad imaju ulogu u katalizi povećanjem 'krutosti' u tranziciji. Naprimjer, u <a href="/w/index.php?title=Ziegler-Natta_kataliza&action=edit&redlink=1" class="new" title="Ziegler-Natta kataliza (stranica ne postoji)">Ziegler-Natta katalizui</a> vrlo <a href="/wiki/Elektrofil" title="Elektrofil">elektrofilni</a> metalni centar ima agostičnu interakciju s lancem rastućeg polimera. Ova povećana krutost utiče na stereo-orijentaciju i fakultativnost izbora u procesu polimerizacije.<sup id="cite_ref-9" class="reference"><a href="#cite_note-9"><span class="cite-bracket">[</span>9<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading2"><h2 id="Interakcije_sličnih_veza"><span id="Interakcije_sli.C4.8Dnih_veza"></span>Interakcije sličnih veza</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Agosti%C4%8Dna_interakcija&veaction=edit&section=4" title="Uredi odlomak "Interakcije sličnih veza"" class="mw-editsection-visualeditor"><span>uredi</span></a><span class="mw-editsection-divider"> | </span><a href="/w/index.php?title=Agosti%C4%8Dna_interakcija&action=edit&section=4" title="Edit section's source code: Interakcije sličnih veza"><span>uredi izvor</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Termin agostična je rezerviran za opisivanje potencijala dvoelektronske, trocentarske interakcije između ugljika, vodika, i metala. Dvaoelektronski trooentarski potencijal je jasno umiješan u kompleksiranja H<sub>2</sub>, npr. i W(CO)<sub>3</sub>(PCY<sub>3</sub>) <sub>2</sub>H<sub>2</sub>, koje je usko povezano sa agostičnim kompleksom, što je je prikazano na slici. <a href="/w/index.php?title=Silan&action=edit&redlink=1" class="new" title="Silan (stranica ne postoji)">Silan</a> se veže za metalne centre, često preko veze koja liči na agostične, trocentarsku Si-H-M interakcije. Kako ove interakcije ne uključuju ugljik, one se ne svrstavaju kao agostične.<sup id="cite_ref-10" class="reference"><a href="#cite_note-10"><span class="cite-bracket">[</span>10<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading3"><h3 id="Anagostne_veze">Anagostne veze</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Agosti%C4%8Dna_interakcija&veaction=edit&section=5" title="Uredi odlomak "Anagostne veze"" class="mw-editsection-visualeditor"><span>uredi</span></a><span class="mw-editsection-divider"> | </span><a href="/w/index.php?title=Agosti%C4%8Dna_interakcija&action=edit&section=5" title="Edit section's source code: Anagostne veze"><span>uredi izvor</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Određeni M --- H-C interakcije nisu klasificirane kao "agostične", ali su opisane pod pojmom "anagostne". Te interakcije su elektrostatičkog karaktera. U pogledu strukture, anagostne interakcija, udaljenosti i uglova M --- H i M-H-C nalaze se u rasponima oko 2,3-2,9 Ǻ i 110-170°.<sup id="cite_ref-Brook_6-1" class="reference"><a href="#cite_note-Brook-6"><span class="cite-bracket">[</span>6<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-11" class="reference"><a href="#cite_note-11"><span class="cite-bracket">[</span>11<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading2"><h2 id="Funkcija">Funkcija</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Agosti%C4%8Dna_interakcija&veaction=edit&section=6" title="Uredi odlomak "Funkcija"" class="mw-editsection-visualeditor"><span>uredi</span></a><span class="mw-editsection-divider"> | </span><a href="/w/index.php?title=Agosti%C4%8Dna_interakcija&action=edit&section=6" title="Edit section's source code: Funkcija"><span>uredi izvor</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Agostične interakcije imaju ključnu funkciju u olefinskoj polimerizaciji i <a href="/wiki/Stereohemija" title="Stereohemija">stereohemiji</a>, kao i <a href="/w/index.php?title=Migracijska_insercija&action=edit&redlink=1" class="new" title="Migracijska insercija (stranica ne postoji)">migracijskom umetanju</a>. </p> <div class="mw-heading mw-heading2"><h2 id="Također_pogledajte"><span id="Tako.C4.91er_pogledajte"></span>Također pogledajte</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Agosti%C4%8Dna_interakcija&veaction=edit&section=7" title="Uredi odlomak "Također pogledajte"" class="mw-editsection-visualeditor"><span>uredi</span></a><span class="mw-editsection-divider"> | </span><a href="/w/index.php?title=Agosti%C4%8Dna_interakcija&action=edit&section=7" title="Edit section's source code: Također pogledajte"><span>uredi izvor</span></a><span class="mw-editsection-bracket">]</span></span></div> <ul><li><a href="/wiki/Hemijska_veza" title="Hemijska veza">Hemijska veza</a></li></ul> <div class="mw-heading mw-heading2"><h2 id="Reference">Reference</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Agosti%C4%8Dna_interakcija&veaction=edit&section=8" title="Uredi odlomak "Reference"" class="mw-editsection-visualeditor"><span>uredi</span></a><span class="mw-editsection-divider"> | </span><a href="/w/index.php?title=Agosti%C4%8Dna_interakcija&action=edit&section=8" title="Edit section's source code: Reference"><span>uredi izvor</span></a><span class="mw-editsection-bracket">]</span></span></div> <style data-mw-deduplicate="TemplateStyles:r3312388">.mw-parser-output .reflist{font-size:90%;margin-bottom:0.5em;list-style-type:decimal}.mw-parser-output .reflist .references{font-size:100%;margin-bottom:0;list-style-type:inherit}.mw-parser-output .reflist-columns-2{column-width:30em}.mw-parser-output .reflist-columns-3{column-width:25em}.mw-parser-output .reflist-columns{margin-top:0.3em}.mw-parser-output .reflist-columns ol{margin-top:0}.mw-parser-output .reflist-columns li{page-break-inside:avoid;break-inside:avoid-column}.mw-parser-output .reflist-upper-alpha{list-style-type:upper-alpha}.mw-parser-output .reflist-upper-roman{list-style-type:upper-roman}.mw-parser-output .reflist-lower-alpha{list-style-type:lower-alpha}.mw-parser-output .reflist-lower-greek{list-style-type:lower-greek}.mw-parser-output .reflist-lower-roman{list-style-type:lower-roman}</style><div class="reflist reflist-columns references-column-width reflist-columns-2" style=""> <ol class="references"> <li id="cite_note-<“Atkins“-1"><span class="mw-cite-backlink"><b><a href="#cite_ref-<“Atkins“_1-0">^</a></b></span> <span class="reference-text"><style data-mw-deduplicate="TemplateStyles:r3303350">.mw-parser-output cite.citation{font-style:inherit}.mw-parser-output .citation q{quotes:"\"""\"""'""'"}.mw-parser-output .id-lock-free a,.mw-parser-output .citation .cs1-lock-free a{background:linear-gradient(transparent,transparent),url("//upload.wikimedia.org/wikipedia/commons/6/65/Lock-green.svg")right 0.1em center/9px no-repeat}.mw-parser-output .id-lock-limited a,.mw-parser-output .id-lock-registration a,.mw-parser-output .citation .cs1-lock-limited a,.mw-parser-output .citation .cs1-lock-registration a{background:linear-gradient(transparent,transparent),url("//upload.wikimedia.org/wikipedia/commons/d/d6/Lock-gray-alt-2.svg")right 0.1em center/9px no-repeat}.mw-parser-output .id-lock-subscription a,.mw-parser-output .citation .cs1-lock-subscription a{background:linear-gradient(transparent,transparent),url("//upload.wikimedia.org/wikipedia/commons/a/aa/Lock-red-alt-2.svg")right 0.1em center/9px no-repeat}.mw-parser-output .cs1-subscription,.mw-parser-output .cs1-registration{color:#555}.mw-parser-output .cs1-subscription span,.mw-parser-output .cs1-registration span{border-bottom:1px dotted;cursor:help}.mw-parser-output .cs1-ws-icon a{background:linear-gradient(transparent,transparent),url("//upload.wikimedia.org/wikipedia/commons/4/4c/Wikisource-logo.svg")right 0.1em center/12px no-repeat}.mw-parser-output code.cs1-code{color:inherit;background:inherit;border:none;padding:inherit}.mw-parser-output .cs1-hidden-error{display:none;font-size:100%}.mw-parser-output .cs1-visible-error{font-size:100%}.mw-parser-output .cs1-maint{display:none;color:#33aa33;margin-left:0.3em}.mw-parser-output .cs1-format{font-size:95%}.mw-parser-output .cs1-kern-left,.mw-parser-output .cs1-kern-wl-left{padding-left:0.2em}.mw-parser-output .cs1-kern-right,.mw-parser-output .cs1-kern-wl-right{padding-right:0.2em}.mw-parser-output .citation .mw-selflink{font-weight:inherit}</style><cite id="CITEREFAtkins_P.,_de_Paula_J.2006" class="citation book cs1">Atkins P., de Paula J. (2006). <span class="cs1-lock-registration" title="Potrebna besplatna registracija"><a rel="nofollow" class="external text" href="https://archive.org/details/atkinsphysicalch00pwat"><i>Physical chemistry, 8th Ed</i></a></span>. San Francisco: W. H. Freeman. <a href="/wiki/ISBN_(identifikator)" class="mw-redirect" title="ISBN (identifikator)">ISBN</a> <a href="/wiki/Posebno:Knji%C5%BEni_izvori/0-7167-8759-8" title="Posebno:Knjižni izvori/0-7167-8759-8"><bdi>0-7167-8759-8</bdi></a>.</cite><span title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook&rft.genre=book&rft.btitle=Physical+chemistry%2C+8th+Ed.&rft.place=San+Francisco&rft.pub=W.+H.+Freeman&rft.date=2006&rft.isbn=0-7167-8759-8&rft.au=Atkins+P.%2C+de+Paula+J.&rft_id=https%3A%2F%2Farchive.org%2Fdetails%2Fatkinsphysicalch00pwat&rfr_id=info%3Asid%2Fbs.wikipedia.org%3AAgosti%C4%8Dna+interakcija" class="Z3988"></span></span> </li> <li id="cite_note-<“Whitten“-2"><span class="mw-cite-backlink"><b><a href="#cite_ref-<“Whitten“_2-0">^</a></b></span> <span class="reference-text"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r3303350"><cite id="CITEREFWhitten_K.W.,_Gailey_K._D._and_Davis_R._E.1992" class="citation book cs1">Whitten K.W., Gailey K. D. and Davis R. E. (1992). <a rel="nofollow" class="external text" href="https://archive.org/details/generalchemistry0000whit_e3n4"><i>General chemistry, 4th Ed</i></a>. Philadelphia: Saunders College Publishing. <a href="/wiki/ISBN_(identifikator)" class="mw-redirect" title="ISBN (identifikator)">ISBN</a> <a href="/wiki/Posebno:Knji%C5%BEni_izvori/0-03-072373-6" title="Posebno:Knjižni izvori/0-03-072373-6"><bdi>0-03-072373-6</bdi></a>.</cite><span title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook&rft.genre=book&rft.btitle=General+chemistry%2C+4th+Ed.&rft.place=Philadelphia&rft.pub=Saunders+College+Publishing&rft.date=1992&rft.isbn=0-03-072373-6&rft.au=Whitten+K.W.%2C+Gailey+K.+D.+and+Davis+R.+E.&rft_id=https%3A%2F%2Farchive.org%2Fdetails%2Fgeneralchemistry0000whit_e3n4&rfr_id=info%3Asid%2Fbs.wikipedia.org%3AAgosti%C4%8Dna+interakcija" class="Z3988"></span></span> </li> <li id="cite_note-<“Petrucci“-3"><span class="mw-cite-backlink"><b><a href="#cite_ref-<“Petrucci“_3-0">^</a></b></span> <span class="reference-text"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r3303350"><cite id="CITEREFPetrucci_R._H.,_Harwood_W._S.,_Herring_F._G.2002" class="citation book cs1">Petrucci R. H., Harwood W. S., Herring F. G. (2002). <a rel="nofollow" class="external text" href="https://archive.org/details/generalchemistry0008petr"><i>General Chemistry, 8th Ed</i></a>. New York: Prentice-Hall. <a href="/wiki/ISBN_(identifikator)" class="mw-redirect" title="ISBN (identifikator)">ISBN</a> <a href="/wiki/Posebno:Knji%C5%BEni_izvori/0-13-014329-4" title="Posebno:Knjižni izvori/0-13-014329-4"><bdi>0-13-014329-4</bdi></a>.</cite><span title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook&rft.genre=book&rft.btitle=General+Chemistry%2C+8th+Ed.&rft.place=New+York&rft.pub=Prentice-Hall&rft.date=2002&rft.isbn=0-13-014329-4&rft.au=Petrucci+R.+H.%2C+Harwood+W.+S.%2C+Herring+F.+G.&rft_id=https%3A%2F%2Farchive.org%2Fdetails%2Fgeneralchemistry0008petr&rfr_id=info%3Asid%2Fbs.wikipedia.org%3AAgosti%C4%8Dna+interakcija" class="Z3988"></span><span class="cs1-maint citation-comment">CS1 održavanje: više imena: authors list (<a href="/wiki/Kategorija:CS1_odr%C5%BEavanje:_vi%C5%A1e_imena:_authors_list" title="Kategorija:CS1 održavanje: više imena: authors list">link</a>)</span></span> </li> <li id="cite_note-<“Laider“-4"><span class="mw-cite-backlink"><b><a href="#cite_ref-<“Laider“_4-0">^</a></b></span> <span class="reference-text"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r3303350"><cite id="CITEREFLaidler_K._J.1978" class="citation book cs1">Laidler K. J. (1978). <i>Physical chemistry with biological applications. Benjamin/Cummings</i>. Menlo Park. <a href="/wiki/ISBN_(identifikator)" class="mw-redirect" title="ISBN (identifikator)">ISBN</a> <a href="/wiki/Posebno:Knji%C5%BEni_izvori/0-8053-5680-0" title="Posebno:Knjižni izvori/0-8053-5680-0"><bdi>0-8053-5680-0</bdi></a>.</cite><span title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook&rft.genre=book&rft.btitle=Physical+chemistry+with+biological+applications.+Benjamin%2FCummings&rft.place=Menlo+Park&rft.date=1978&rft.isbn=0-8053-5680-0&rft.au=Laidler+K.+J.&rfr_id=info%3Asid%2Fbs.wikipedia.org%3AAgosti%C4%8Dna+interakcija" class="Z3988"></span></span> </li> <li id="cite_note-<“Weast“-5"><span class="mw-cite-backlink"><b><a href="#cite_ref-<“Weast“_5-0">^</a></b></span> <span class="reference-text"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r3303350"><cite id="CITEREFWeast_R._C.,_Ed.1990" class="citation book cs1">Weast R. C., Ed. (1990). <a rel="nofollow" class="external text" href="https://archive.org/details/crchandbookofche70edunse"><i>CRC Handbook of chemistry and physics</i></a>. Boca Raton: Chemical Rubber Publishing Company. <a href="/wiki/ISBN_(identifikator)" class="mw-redirect" title="ISBN (identifikator)">ISBN</a> <a href="/wiki/Posebno:Knji%C5%BEni_izvori/0-8493-0470-9" title="Posebno:Knjižni izvori/0-8493-0470-9"><bdi>0-8493-0470-9</bdi></a>.</cite><span title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook&rft.genre=book&rft.btitle=CRC+Handbook+of+chemistry+and+physics&rft.place=Boca+Raton&rft.pub=Chemical+Rubber+Publishing+Company&rft.date=1990&rft.isbn=0-8493-0470-9&rft.au=Weast+R.+C.%2C+Ed.&rft_id=https%3A%2F%2Farchive.org%2Fdetails%2Fcrchandbookofche70edunse&rfr_id=info%3Asid%2Fbs.wikipedia.org%3AAgosti%C4%8Dna+interakcija" class="Z3988"></span></span> </li> <li id="cite_note-Brook-6"><span class="mw-cite-backlink">^ <a href="#cite_ref-Brook_6-0"><sup><i><b>a</b></i></sup></a> <a href="#cite_ref-Brook_6-1"><sup><i><b>b</b></i></sup></a></span> <span class="reference-text"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r3303350"><cite id="CITEREFMaurice_BrookhartMalcolm_L._H._Green1983" class="citation journal cs1">Maurice Brookhart; Malcolm L. H. Green (1983). "Carbon-hydrogen-transition metal bonds". <i>J. Organomet. Chem</i>. <b>250</b>: 395. <a href="/wiki/Doi_(identifikator)" class="mw-redirect" title="Doi (identifikator)">doi</a>:<a rel="nofollow" class="external text" href="https://doi.org/10.1016%2F0022-328X%2883%2985065-7">10.1016/0022-328X(83)85065-7</a>.</cite><span title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.jtitle=J.+Organomet.+Chem.&rft.atitle=Carbon-hydrogen-transition+metal+bonds&rft.volume=250&rft.pages=395&rft.date=1983&rft_id=info%3Adoi%2F10.1016%2F0022-328X%2883%2985065-7&rft.au=Maurice+Brookhart&rft.au=Malcolm+L.+H.+Green&rfr_id=info%3Asid%2Fbs.wikipedia.org%3AAgosti%C4%8Dna+interakcija" class="Z3988"></span>.</span> </li> <li id="cite_note-7"><span class="mw-cite-backlink"><b><a href="#cite_ref-7">^</a></b></span> <span class="reference-text"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r3303350"><cite id="CITEREFMaurice_BrookhartMalcolm_L._H._GreenGerard_Parkin2007" class="citation journal cs1">Maurice Brookhart; Malcolm L. H. Green; Gerard Parkin (2007). <a rel="nofollow" class="external text" href="//www.ncbi.nlm.nih.gov/pmc/articles/PMC1855361">"Agostic interactions in transition metal compounds"</a>. <i>Proc. Nat. Acad. Sci</i>. <b>104</b> (17): 6908–14. <a href="/wiki/Bibcode_(identifikator)" class="mw-redirect" title="Bibcode (identifikator)">Bibcode</a>:<a rel="nofollow" class="external text" href="https://ui.adsabs.harvard.edu/abs/2007PNAS..104.6908B">2007PNAS..104.6908B</a>. <a href="/wiki/Doi_(identifikator)" class="mw-redirect" title="Doi (identifikator)">doi</a>:<a rel="nofollow" class="external text" href="https://doi.org/10.1073%2Fpnas.0610747104">10.1073/pnas.0610747104</a>. <a href="/wiki/PMC_(identifikator)" class="mw-redirect" title="PMC (identifikator)">PMC</a> <span class="cs1-lock-free" title="Slobodno dostupno"><a rel="nofollow" class="external text" href="//www.ncbi.nlm.nih.gov/pmc/articles/PMC1855361">1855361</a></span>. <a href="/wiki/PMID_(identifikator)" class="mw-redirect" title="PMID (identifikator)">PMID</a> <a rel="nofollow" class="external text" href="//pubmed.ncbi.nlm.nih.gov/17442749">17442749</a>.</cite><span title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.jtitle=Proc.+Nat.+Acad.+Sci.&rft.atitle=Agostic+interactions+in+transition+metal+compounds&rft.volume=104&rft.issue=17&rft.pages=6908-14&rft.date=2007&rft_id=%2F%2Fwww.ncbi.nlm.nih.gov%2Fpmc%2Farticles%2FPMC1855361%23id-name%3DPMC&rft_id=info%3Apmid%2F17442749&rft_id=info%3Adoi%2F10.1073%2Fpnas.0610747104&rft_id=info%3Abibcode%2F2007PNAS..104.6908B&rft.au=Maurice+Brookhart&rft.au=Malcolm+L.+H.+Green&rft.au=Gerard+Parkin&rft_id=%2F%2Fwww.ncbi.nlm.nih.gov%2Fpmc%2Farticles%2FPMC1855361&rfr_id=info%3Asid%2Fbs.wikipedia.org%3AAgosti%C4%8Dna+interakcija" class="Z3988"></span></span> </li> <li id="cite_note-8"><span class="mw-cite-backlink"><b><a href="#cite_ref-8">^</a></b></span> <span class="reference-text"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r3303350"><cite id="CITEREFSam_J._La_PlacaJames_A._Ibers" class="citation journal cs1">Sam J. La Placa; James A. Ibers. "A Five-Coordinated <i>d</i><sup>6</sup> Complex: Structure of Dichlorotris(triphenylphosphine)ruthenium (II)". <i>Inorg. Chem</i>. <a href="/wiki/Doi_(identifikator)" class="mw-redirect" title="Doi (identifikator)">doi</a>:<a rel="nofollow" class="external text" href="https://doi.org/10.1021%2Fic50028a002">10.1021/ic50028a002</a>.</cite><span title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.jtitle=Inorg.+Chem.&rft.atitle=A+Five-Coordinated+d%3Csup%3E6%3C%2Fsup%3E+Complex%3A+Structure+of+Dichlorotris%28triphenylphosphine%29ruthenium+%28II%29&rft_id=info%3Adoi%2F10.1021%2Fic50028a002&rft.au=Sam+J.+La+Placa&rft.au=James+A.+Ibers&rfr_id=info%3Asid%2Fbs.wikipedia.org%3AAgosti%C4%8Dna+interakcija" class="Z3988"></span></span> </li> <li id="cite_note-9"><span class="mw-cite-backlink"><b><a href="#cite_ref-9">^</a></b></span> <span class="reference-text"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r3303350"><cite id="CITEREFVon_FrantziusStreubelBrandhorstGrunenberg2006" class="citation journal cs1">Von Frantzius, Gerd; Streubel, Rainer; Brandhorst, Kai; Grunenberg, Jörg (2006). "How Strong is an Agostic Bond? Direct Assessment of Agostic Interactions Using the Generalized Compliance Matrix†". <i>Organometallics</i>. <b>25</b> (1): 118–121. <a href="/wiki/Doi_(identifikator)" class="mw-redirect" title="Doi (identifikator)">doi</a>:<a rel="nofollow" class="external text" href="https://doi.org/10.1021%2Fom050489a">10.1021/om050489a</a>.</cite><span title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.jtitle=Organometallics&rft.atitle=How+Strong+is+an+Agostic+Bond%3F+Direct+Assessment+of+Agostic+Interactions+Using+the+Generalized+Compliance+Matrix%E2%80%A0&rft.volume=25&rft.issue=1&rft.pages=118-121&rft.date=2006&rft_id=info%3Adoi%2F10.1021%2Fom050489a&rft.aulast=Von+Frantzius&rft.aufirst=Gerd&rft.au=Streubel%2C+Rainer&rft.au=Brandhorst%2C+Kai&rft.au=Grunenberg%2C+J%C3%B6rg&rfr_id=info%3Asid%2Fbs.wikipedia.org%3AAgosti%C4%8Dna+interakcija" class="Z3988"></span></span> </li> <li id="cite_note-10"><span class="mw-cite-backlink"><b><a href="#cite_ref-10">^</a></b></span> <span class="reference-text"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r3303350"><cite id="CITEREFKubas,_Mr._J.2001" class="citation book cs1">Kubas, Mr. J. (2001). <i>Metal Dihydrogen and σ-Bond Complexes</i>. New York: Kluwer Academic.</cite><span title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook&rft.genre=book&rft.btitle=Metal+Dihydrogen+and+%CF%83-Bond+Complexes&rft.place=New+York&rft.pub=Kluwer+Academic&rft.date=2001&rft.au=Kubas%2C+Mr.+J.&rfr_id=info%3Asid%2Fbs.wikipedia.org%3AAgosti%C4%8Dna+interakcija" class="Z3988"></span> <span class="cs1-visible-error error citation-comment">Referenca sadrži prazan nepoznati parametar: <code class="cs1-code">|<a href="/wiki/Posebno:Knji%C5%BEni_izvori/9780306464652" class="internal mw-magiclink-isbn">ISBN 978-0-306-46465-2</a>=</code> (<a href="/w/index.php?title=Pomo%C4%87:CS1_gre%C5%A1ke&action=edit&redlink=1" class="new" title="Pomoć:CS1 greške (stranica ne postoji)">pomoć</a>)</span></span> </li> <li id="cite_note-11"><span class="mw-cite-backlink"><b><a href="#cite_ref-11">^</a></b></span> <span class="reference-text"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r3303350"><cite id="CITEREFBraga,_D.Grepioni,_F.Tedesco,_E.Biradha,_K.1997" class="citation journal cs1">Braga, D.; Grepioni, F.; Tedesco, E.; Biradha, K.; Desiraju, G. R. (1997). "Hydrogen Bonding in Organometallic Crystals. 6.†X−H---M Hydrogen Bonds and M---(H−X) Pseudo-Agostic Bonds". <i>Organometallics</i>. <b>16</b> (9): 1846–1856. <a href="/wiki/Doi_(identifikator)" class="mw-redirect" title="Doi (identifikator)">doi</a>:<a rel="nofollow" class="external text" href="https://doi.org/10.1021%2Fom9608364">10.1021/om9608364</a>.</cite><span title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.jtitle=Organometallics&rft.atitle=Hydrogen+Bonding+in+Organometallic+Crystals.+6.%E2%80%A0X%E2%88%92H---M+Hydrogen+Bonds+and+M---%28H%E2%88%92X%29+Pseudo-Agostic+Bonds&rft.volume=16&rft.issue=9&rft.pages=1846-1856&rft.date=1997&rft_id=info%3Adoi%2F10.1021%2Fom9608364&rft.au=Braga%2C+D.&rft.au=Grepioni%2C+F.&rft.au=Tedesco%2C+E.&rft.au=Biradha%2C+K.&rft.au=Desiraju%2C+G.+R.&rfr_id=info%3Asid%2Fbs.wikipedia.org%3AAgosti%C4%8Dna+interakcija" class="Z3988"></span></span> </li> </ol></div> <div class="mw-heading mw-heading2"><h2 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cdx-button--weight-quiet cdx-button--icon-only" id="ca-talk-sticky-header" tabindex="-1" data-event-name="talk-sticky-header"><span class="vector-icon mw-ui-icon-speechBubbles mw-ui-icon-wikimedia-speechBubbles"></span> <span></span> </a> <a href="#" class="cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--icon-only" id="ca-subject-sticky-header" tabindex="-1" data-event-name="subject-sticky-header"><span class="vector-icon mw-ui-icon-article mw-ui-icon-wikimedia-article"></span> <span></span> </a> <a href="#" class="cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--icon-only" id="ca-history-sticky-header" tabindex="-1" data-event-name="history-sticky-header"><span class="vector-icon mw-ui-icon-wikimedia-history mw-ui-icon-wikimedia-wikimedia-history"></span> <span></span> </a> <a href="#" class="cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--icon-only mw-watchlink" id="ca-watchstar-sticky-header" tabindex="-1" data-event-name="watch-sticky-header"><span class="vector-icon mw-ui-icon-wikimedia-star mw-ui-icon-wikimedia-wikimedia-star"></span> <span></span> </a> <a href="#" class="cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--icon-only" id="ca-ve-edit-sticky-header" tabindex="-1" data-event-name="ve-edit-sticky-header"><span class="vector-icon mw-ui-icon-wikimedia-edit mw-ui-icon-wikimedia-wikimedia-edit"></span> <span></span> </a> <a href="#" class="cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--icon-only" id="ca-edit-sticky-header" tabindex="-1" data-event-name="wikitext-edit-sticky-header"><span class="vector-icon mw-ui-icon-wikimedia-wikiText mw-ui-icon-wikimedia-wikimedia-wikiText"></span> <span></span> </a> <a href="#" class="cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--icon-only" id="ca-viewsource-sticky-header" tabindex="-1" data-event-name="ve-edit-protected-sticky-header"><span class="vector-icon mw-ui-icon-wikimedia-editLock mw-ui-icon-wikimedia-wikimedia-editLock"></span> <span></span> </a> </div> <div class="vector-sticky-header-buttons"> <button class="cdx-button cdx-button--weight-quiet mw-interlanguage-selector" id="p-lang-btn-sticky-header" tabindex="-1" data-event-name="ui.dropdown-p-lang-btn-sticky-header"><span class="vector-icon mw-ui-icon-wikimedia-language mw-ui-icon-wikimedia-wikimedia-language"></span> <span>13 jezika</span> </button> <a href="#" class="cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--action-progressive" id="ca-addsection-sticky-header" tabindex="-1" data-event-name="addsection-sticky-header"><span class="vector-icon mw-ui-icon-speechBubbleAdd-progressive mw-ui-icon-wikimedia-speechBubbleAdd-progressive"></span> <span>Dodaj temu</span> </a> </div> <div class="vector-sticky-header-icon-end"> <div class="vector-user-links"> </div> </div> </div> </div> </div> <div class="vector-settings" id="p-dock-bottom"> <ul></ul> </div><script>(RLQ=window.RLQ||[]).push(function(){mw.config.set({"wgHostname":"mw-web.codfw.main-8568cbfbb4-h792c","wgBackendResponseTime":116,"wgPageParseReport":{"limitreport":{"cputime":"0.222","walltime":"0.277","ppvisitednodes":{"value":2700,"limit":1000000},"postexpandincludesize":{"value":49493,"limit":2097152},"templateargumentsize":{"value":4683,"limit":2097152},"expansiondepth":{"value":11,"limit":100},"expensivefunctioncount":{"value":0,"limit":500},"unstrip-depth":{"value":1,"limit":20},"unstrip-size":{"value":40273,"limit":5000000},"entityaccesscount":{"value":0,"limit":400},"timingprofile":["100.00% 234.235 1 -total"," 68.30% 159.977 1 Šablon:Refspisak"," 48.49% 113.584 6 Šablon:Cite_book"," 23.86% 55.890 3 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