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Available in 7 languages" > <label id="p-lang-btn-label" for="p-lang-btn-checkbox" class="vector-dropdown-label cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--action-progressive mw-portlet-lang-heading-7" aria-hidden="true" ><span class="vector-icon mw-ui-icon-language-progressive mw-ui-icon-wikimedia-language-progressive"></span> <span class="vector-dropdown-label-text">7 languages</span> </label> <div class="vector-dropdown-content"> <div class="vector-menu-content"> <ul class="vector-menu-content-list"> <li class="interlanguage-link interwiki-azb mw-list-item"><a href="https://azb.wikipedia.org/wiki/%DA%A9%D9%88%D9%84%D9%88%D8%B1%DB%8C%D8%AF_%D9%BE%D9%86%D8%AA%D8%A7%D8%A2%D9%85%DB%8C%D9%86_(%D9%86%DB%8C%D8%AA%D8%B1%D9%88%DA%98%D9%86)_%D8%B1%D9%88%D8%AA%D9%86%DB%8C%D9%88%D9%85_(II)" title="کولورید پنتاآمین (نیتروژن) روتنیوم (II) – South Azerbaijani" lang="azb" hreflang="azb" data-title="کولورید پنتاآمین (نیتروژن) روتنیوم (II)" data-language-autonym="تۆرکجه" data-language-local-name="South Azerbaijani" class="interlanguage-link-target"><span>تۆرکجه</span></a></li><li class="interlanguage-link interwiki-fa mw-list-item"><a href="https://fa.wikipedia.org/wiki/%DA%A9%D9%84%D8%B1%DB%8C%D8%AF_%D9%BE%D9%86%D8%AA%D8%A7%D8%A2%D9%85%DB%8C%D9%86_(%D9%86%DB%8C%D8%AA%D8%B1%D9%88%DA%98%D9%86)_%D8%B1%D9%88%D8%AA%D9%86%DB%8C%D9%85_(II)" title="کلرید پنتاآمین (نیتروژن) روتنیم (II) – Persian" lang="fa" hreflang="fa" data-title="کلرید پنتاآمین (نیتروژن) روتنیم (II)" data-language-autonym="فارسی" data-language-local-name="Persian" class="interlanguage-link-target"><span>فارسی</span></a></li><li class="interlanguage-link interwiki-fr mw-list-item"><a href="https://fr.wikipedia.org/wiki/Chlorure_de_pentaamine(diazote)ruth%C3%A9nium(II)" title="Chlorure de pentaamine(diazote)ruthénium(II) – French" lang="fr" hreflang="fr" data-title="Chlorure de pentaamine(diazote)ruthénium(II)" data-language-autonym="Français" data-language-local-name="French" class="interlanguage-link-target"><span>Français</span></a></li><li class="interlanguage-link interwiki-id mw-list-item"><a href="https://id.wikipedia.org/wiki/Pentaamina(dinitrogen)rutenium(II)_klorida" title="Pentaamina(dinitrogen)rutenium(II) klorida – Indonesian" lang="id" hreflang="id" data-title="Pentaamina(dinitrogen)rutenium(II) klorida" data-language-autonym="Bahasa Indonesia" data-language-local-name="Indonesian" class="interlanguage-link-target"><span>Bahasa Indonesia</span></a></li><li class="interlanguage-link interwiki-it mw-list-item"><a href="https://it.wikipedia.org/wiki/Cloruro_di_pentaammina(azoto)rutenio(II)" title="Cloruro di pentaammina(azoto)rutenio(II) – Italian" lang="it" hreflang="it" data-title="Cloruro di pentaammina(azoto)rutenio(II)" data-language-autonym="Italiano" data-language-local-name="Italian" class="interlanguage-link-target"><span>Italiano</span></a></li><li class="interlanguage-link interwiki-th mw-list-item"><a href="https://th.wikipedia.org/wiki/%E0%B9%80%E0%B8%9E%E0%B8%99%E0%B8%95%E0%B8%B2%E0%B9%80%E0%B8%AD%E0%B8%A1%E0%B8%B5%E0%B8%99(%E0%B9%84%E0%B8%94%E0%B9%84%E0%B8%99%E0%B9%82%E0%B8%95%E0%B8%A3%E0%B9%80%E0%B8%88%E0%B8%99)%E0%B8%A3%E0%B8%B9%E0%B8%97%E0%B8%B5%E0%B9%80%E0%B8%99%E0%B8%B5%E0%B8%A2%E0%B8%A1(II)_%E0%B8%84%E0%B8%A5%E0%B8%AD%E0%B9%84%E0%B8%A3%E0%B8%94%E0%B9%8C" title="เพนตาเอมีน(ไดไนโตรเจน)รูทีเนียม(II) คลอไรด์ – Thai" lang="th" hreflang="th" data-title="เพนตาเอมีน(ไดไนโตรเจน)รูทีเนียม(II) คลอไรด์" data-language-autonym="ไทย" data-language-local-name="Thai" class="interlanguage-link-target"><span>ไทย</span></a></li><li class="interlanguage-link interwiki-zh mw-list-item"><a href="https://zh.wikipedia.org/wiki/%E4%BA%8C%E6%B0%AF%E5%8C%96%E5%8F%8C%E6%B0%AE%E4%BA%94%E6%B0%A8%E5%90%88%E9%92%8C(II)" title="二氯化双氮五氨合钌(II) – Chinese" lang="zh" hreflang="zh" data-title="二氯化双氮五氨合钌(II)" data-language-autonym="中文" data-language-local-name="Chinese" 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#a2a9b1;width:40%}.mw-parser-output .ib-chembox td+td{width:60%}@media screen{html.skin-theme-clientpref-night .mw-parser-output .ib-chembox figure:not(.skin-invert-image):not(.skin-invert):not(.bg-transparent){background:var(--background-color-inverted,#f8f9fa)}}@media screen and (prefers-color-scheme:dark){html.skin-theme-clientpref-os .mw-parser-output .ib-chembox figure:not(.skin-invert-image):not(.skin-invert):not(.bg-transparent){background:var(--background-color-inverted,#f8f9fa)}}</style> <table class="infobox ib-chembox"> <caption>Pentaamine(dinitrogen)ruthenium(II) chloride </caption> <tbody><tr> <td colspan="2" style="text-align:center; padding:2px;"><figure class="mw-halign-center" typeof="mw:File"><a href="/wiki/File:RuA5N2.png" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/5/5b/RuA5N2.png/220px-RuA5N2.png" decoding="async" width="220" height="219" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/5/5b/RuA5N2.png/330px-RuA5N2.png 1.5x, //upload.wikimedia.org/wikipedia/commons/5/5b/RuA5N2.png 2x" data-file-width="391" data-file-height="389" /></a><figcaption></figcaption></figure> </td></tr> <tr> <th colspan="2" style="background: #f8eaba;color:inherit; text-align: center;">Names </th></tr> <tr> <td colspan="2" style="text-align:left;"><a href="/wiki/Chemical_nomenclature" title="Chemical nomenclature">IUPAC name</a> <div style="max-width:22em; word-wrap:break-word; padding-left:1.7em;">pentaamminedinitrogenruthenium (II) chloride</div> </td></tr> <tr> <th colspan="2" style="background: #f8eaba;color:inherit; text-align: center;">Identifiers </th></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/CAS_Registry_Number" title="CAS Registry Number">CAS Number</a></div> </td> <td><style data-mw-deduplicate="TemplateStyles:r1126788409">.mw-parser-output .plainlist ol,.mw-parser-output .plainlist ul{line-height:inherit;list-style:none;margin:0;padding:0}.mw-parser-output .plainlist ol li,.mw-parser-output .plainlist ul li{margin-bottom:0}</style><div class="plainlist"><ul><li><span title="commonchemistry.cas.org"><a rel="nofollow" class="external text" href="https://commonchemistry.cas.org/detail?cas_rn=15392-92-4">15392-92-4</a></span><sup> <span typeof="mw:File"><span><img alt="check" src="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/7px-Yes_check.svg.png" decoding="async" width="7" height="7" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/11px-Yes_check.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/14px-Yes_check.svg.png 2x" data-file-width="600" data-file-height="600" /></span></span><span style="display:none">Y</span></sup></li></ul></div> </td></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;">3D model (<a href="/wiki/JSmol" class="mw-redirect" title="JSmol">JSmol</a>)</div> </td> <td><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1126788409"><div class="plainlist"><ul><li><span title="chemapps.stolaf.edu (3D interactive model)"><a rel="nofollow" class="external text" href="https://chemapps.stolaf.edu/jmol/jmol.php?model=%5BCl-%5D.N%23%5BN%2B%5D%5BRu-4%5D%28%5BNH3%2B%5D%29%28%5BNH3%2B%5D%29%28%5BNH3%2B%5D%29%28%5BNH3%2B%5D%29%5BNH3%2B%5D.%5BCl-%5D">Interactive image</a></span></li></ul></div> </td></tr> <tr> <td colspan="2"><div class="collapsible-list mw-collapsible mw-collapsed" style="text-align: left;"> <div style="line-height: 1.6em; font-weight: bold; text-align:left; font-weight:normal;"><div><a href="/wiki/International_Chemical_Identifier" title="International Chemical Identifier">InChI</a></div></div> <ul class="mw-collapsible-content" style="margin-top: 0; margin-bottom: 0; line-height: inherit; list-style: none; margin-left: 0; word-break:break-all;"><li style="line-height: inherit; margin: 0"><div style="border-top:1px solid #ccc; padding:0.2em 0 0.2em 1.5em; text-align:left;"><div style="word-wrap:break-word; text-indent:-1.5em; font-size:97%; line-height:120%;">InChI=1S/2ClH.N2.5H3N.Ru/c;;1-2;;;;;;/h2*1H;;5*1H3;/q;;;;;;;;+2/p-2</div><div style="word-wrap:break-word; text-indent:-1.5em; font-size:97%; line-height:120%;">Key: VLZPOOHIDLPMKN-UHFFFAOYSA-L</div></div></li></ul> </div> </td></tr> <tr> <td colspan="2"><div class="collapsible-list mw-collapsible mw-collapsed" style="text-align: left;"> <div style="line-height: 1.6em; font-weight: bold; text-align:left; font-weight:normal;"><div><a href="/wiki/Simplified_molecular-input_line-entry_system" class="mw-redirect" title="Simplified molecular-input line-entry system">SMILES</a></div></div> <ul class="mw-collapsible-content" style="margin-top: 0; margin-bottom: 0; line-height: inherit; list-style: none; margin-left: 0; word-break:break-all;"><li style="line-height: inherit; margin: 0"><div style="border-top:1px solid #ccc; padding:0.2em 0 0.2em 1.6em; word-wrap:break-word; text-indent:-1.5em; text-align:left; font-size:97%; line-height:120%;">[Cl-].N#[N+][Ru-4]([NH3+])([NH3+])([NH3+])([NH3+])[NH3+].[Cl-]</div></li></ul> </div> </td></tr> <tr> <th colspan="2" style="background: #f8eaba;color:inherit; text-align: center;">Properties </th></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/Chemical_formula" title="Chemical formula">Chemical formula</a></div> </td> <td>H<sub>15</sub>N<sub>7</sub>Cl<sub>2</sub>Ru  </td></tr> <tr> <td><a href="/wiki/Molar_mass" title="Molar mass">Molar mass</a> </td> <td>285.14 g/mol    </td></tr> <tr> <td>Appearance </td> <td>colorless solid </td></tr> <tr> <td colspan="2" style="text-align:left; background:#f8eaba; color:inherit; border:1px solid #a2a9b1;"><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;">Except where otherwise noted, data are given for materials in their <a href="/wiki/Standard_state" title="Standard state">standard state</a> (at 25 °C [77 °F], 100 kPa).</div> <div style="margin-top: 0.3em;"><div style="text-align:center;"><span typeof="mw:File"><span><img alt="☒" src="//upload.wikimedia.org/wikipedia/commons/thumb/a/a2/X_mark.svg/12px-X_mark.svg.png" decoding="async" width="12" height="14" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/a/a2/X_mark.svg/18px-X_mark.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/a/a2/X_mark.svg/24px-X_mark.svg.png 2x" data-file-width="525" data-file-height="600" /></span></span><span style="display:none">N</span> (<a href="/wiki/Wikipedia:WikiProject_Chemicals/Chembox_validation" title="Wikipedia:WikiProject Chemicals/Chembox validation">what is</a> <sup><span typeof="mw:File"><span><img alt="check" src="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/7px-Yes_check.svg.png" decoding="async" width="7" height="7" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/11px-Yes_check.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/14px-Yes_check.svg.png 2x" data-file-width="600" data-file-height="600" /></span></span><span style="display:none">Y</span><span typeof="mw:File"><span><img alt="☒" src="//upload.wikimedia.org/wikipedia/commons/thumb/a/a2/X_mark.svg/7px-X_mark.svg.png" decoding="async" width="7" height="8" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/a/a2/X_mark.svg/11px-X_mark.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/a/a2/X_mark.svg/14px-X_mark.svg.png 2x" data-file-width="525" data-file-height="600" /></span></span><span style="display:none">N</span></sup> ?) </div></div> <div style="margin-top: 0.3em; text-align: center;"><a href="/wiki/Wikipedia:Chemical_infobox#References" title="Wikipedia:Chemical infobox">Infobox references</a></div> </td></tr> </tbody></table><div class="shortdescription nomobile noexcerpt noprint searchaux" style="display:none">Chemical compound</div> <p><b>Pentaamine(nitrogen)ruthenium(II) chloride</b> is an <a href="/wiki/Inorganic_compound" title="Inorganic compound">inorganic compound</a> with the formula [Ru(NH<sub>3</sub>)<sub>5</sub>(N<sub>2</sub>)]Cl<sub>2</sub>. It is a nearly white solid, but its solutions are yellow. The cationic complex is of historic significance as the first compound with N<sub>2</sub> bound to a metal center.<sup id="cite_ref-1" class="reference"><a href="#cite_note-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-2" class="reference"><a href="#cite_note-2"><span class="cite-bracket">[</span>2<span class="cite-bracket">]</span></a></sup> [Ru(NH<sub>3</sub>)<sub>5</sub>(N<sub>2</sub>)]<sup>2+</sup> adopts an <a href="/wiki/Octahedral_molecular_geometry" title="Octahedral molecular geometry">octahedral structure</a> with C<sub>4v</sub> symmetry.<sup id="cite_ref-3" class="reference"><a href="#cite_note-3"><span class="cite-bracket">[</span>3<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading2"><h2 id="Preparation_and_properties">Preparation and properties</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Pentaamine(dinitrogen)ruthenium(II)_chloride&action=edit&section=1" title="Edit section: Preparation and properties"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Pentaamine(nitrogen)ruthenium(II) chloride is synthesized in an aqueous solution from pentaamminechlororuthenium(III) chloride, <a href="/wiki/Sodium_azide" title="Sodium azide">sodium azide</a>, and <a href="/wiki/Methanesulfonic_acid" title="Methanesulfonic acid">methanesulfonic acid</a>:<sup id="cite_ref-Allen_4-0" class="reference"><a href="#cite_note-Allen-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup> </p> <dl><dd>[Ru(NH<sub>3</sub>)<sub>5</sub>Cl]Cl<sub>2</sub> + NaN<sub>3</sub> → [Ru(NH<sub>3</sub>)<sub>5</sub>N<sub>2</sub>]Cl<sub>2</sub> + ...</dd></dl> <p>If it is to be used <i>in situ</i>, the cation can be made more conveniently from ruthenium(III) chloride and hydrazine hydrate:<sup id="cite_ref-Allen_4-1" class="reference"><a href="#cite_note-Allen-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup> </p> <dl><dd>RuCl<sub>3</sub> + 4 N<sub>2</sub>H<sub>4</sub> → [Ru(NH<sub>3</sub>)<sub>5</sub>N<sub>2</sub>]<sup>2+</sup> + ...</dd></dl> <p>This N<sub>2</sub> complex is stable in aqueous solution and has a relatively low ligand exchange rate with water. Being a d<sup>6</sup> complex, the Ru-N bond is stabilized by the <a href="/wiki/Pi_backbonding" title="Pi backbonding">pi backbonding</a>, the donation of metal d-electrons into the N<sub>2</sub> π* orbitals.<sup id="cite_ref-5" class="reference"><a href="#cite_note-5"><span class="cite-bracket">[</span>5<span class="cite-bracket">]</span></a></sup> The related <a href="/wiki/Metal_ammine_complex" title="Metal ammine complex">metal ammine complex</a> [Os(NH<sub>3</sub>)<sub>5</sub>(N<sub>2</sub>)]<sup>2+</sup> is also known. </p> <div class="mw-heading mw-heading2"><h2 id="Reactions">Reactions</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Pentaamine(dinitrogen)ruthenium(II)_chloride&action=edit&section=2" title="Edit section: Reactions"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>The dinitrogen ligand is not reduced by aqueous sodium borohydride.<sup id="cite_ref-6" class="reference"><a href="#cite_note-6"><span class="cite-bracket">[</span>6<span class="cite-bracket">]</span></a></sup> Nearly all known reactions of this compound are displacement reactions. Pentaamine(halogen)ruthenium(II) halides can be synthesized by treating [Ru(NH<sub>3</sub>)<sub>5</sub>N<sub>2</sub>]<sup>2+</sup> with halide sources:<sup id="cite_ref-Allen_4-2" class="reference"><a href="#cite_note-Allen-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup> </p> <dl><dd>[Ru(NH<sub>3</sub>)<sub>5</sub>N<sub>2</sub>]<sup>2+</sup> + X<sup>−</sup> → [Ru(NH<sub>3</sub>)<sub>5</sub>X]<sup>+</sup> + N<sub>2</sub></dd></dl> <p>[Ru(NH<sub>3</sub>)<sub>5</sub>N<sub>2</sub>]<sup>2+</sup> forms the symmetrically bridging symmetrical <a href="/wiki/Transition_metal_dinitrogen_complex" title="Transition metal dinitrogen complex">dinitrogen complex</a> [(NH<sub>3</sub>)<sub>5</sub>Ru-NN-Ru(NH<sub>3</sub>)<sub>5</sub>]<sup>4+</sup>.<sup id="cite_ref-7" class="reference"><a href="#cite_note-7"><span class="cite-bracket">[</span>7<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-8" class="reference"><a href="#cite_note-8"><span class="cite-bracket">[</span>8<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading2"><h2 id="References">References</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Pentaamine(dinitrogen)ruthenium(II)_chloride&action=edit&section=3" title="Edit section: References"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <div class="mw-references-wrap"><ol class="references"> <li id="cite_note-1"><span class="mw-cite-backlink"><b><a href="#cite_ref-1">^</a></b></span> <span class="reference-text"><style data-mw-deduplicate="TemplateStyles:r1238218222">.mw-parser-output cite.citation{font-style:inherit;word-wrap:break-word}.mw-parser-output .citation q{quotes:"\"""\"""'""'"}.mw-parser-output .citation:target{background-color:rgba(0,127,255,0.133)}.mw-parser-output .id-lock-free.id-lock-free a{background:url("//upload.wikimedia.org/wikipedia/commons/6/65/Lock-green.svg")right 0.1em center/9px no-repeat}.mw-parser-output .id-lock-limited.id-lock-limited a,.mw-parser-output .id-lock-registration.id-lock-registration a{background:url("//upload.wikimedia.org/wikipedia/commons/d/d6/Lock-gray-alt-2.svg")right 0.1em center/9px no-repeat}.mw-parser-output .id-lock-subscription.id-lock-subscription a{background:url("//upload.wikimedia.org/wikipedia/commons/a/aa/Lock-red-alt-2.svg")right 0.1em center/9px no-repeat}.mw-parser-output .cs1-ws-icon a{background:url("//upload.wikimedia.org/wikipedia/commons/4/4c/Wikisource-logo.svg")right 0.1em center/12px no-repeat}body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-free a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-limited a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-registration a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-subscription a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .cs1-ws-icon a{background-size:contain;padding:0 1em 0 0}.mw-parser-output .cs1-code{color:inherit;background:inherit;border:none;padding:inherit}.mw-parser-output .cs1-hidden-error{display:none;color:var(--color-error,#d33)}.mw-parser-output .cs1-visible-error{color:var(--color-error,#d33)}.mw-parser-output .cs1-maint{display:none;color:#085;margin-left:0.3em}.mw-parser-output .cs1-kern-left{padding-left:0.2em}.mw-parser-output .cs1-kern-right{padding-right:0.2em}.mw-parser-output .citation .mw-selflink{font-weight:inherit}@media screen{.mw-parser-output .cs1-format{font-size:95%}html.skin-theme-clientpref-night .mw-parser-output .cs1-maint{color:#18911f}}@media screen and (prefers-color-scheme:dark){html.skin-theme-clientpref-os .mw-parser-output .cs1-maint{color:#18911f}}</style><cite id="CITEREFAllenSenoff1965" class="citation journal cs1">Allen, A. D.; Senoff, C. V. (1965). "Nitrogenopentammineruthenium(II) Complexes". <i>Chemical Communications</i> (24): 621. <a href="/wiki/Doi_(identifier)" class="mw-redirect" title="Doi (identifier)">doi</a>:<a rel="nofollow" class="external text" href="https://doi.org/10.1039%2FC19650000621">10.1039/C19650000621</a>.</cite><span title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.jtitle=Chemical+Communications&rft.atitle=Nitrogenopentammineruthenium%28II%29+Complexes&rft.issue=24&rft.pages=621&rft.date=1965&rft_id=info%3Adoi%2F10.1039%2FC19650000621&rft.aulast=Allen&rft.aufirst=A.+D.&rft.au=Senoff%2C+C.+V.&rfr_id=info%3Asid%2Fen.wikipedia.org%3APentaamine%28dinitrogen%29ruthenium%28II%29+chloride" class="Z3988"></span></span> </li> <li id="cite_note-2"><span class="mw-cite-backlink"><b><a href="#cite_ref-2">^</a></b></span> <span class="reference-text"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1238218222"><cite id="CITEREFSenoff1990" class="citation journal cs1">Senoff, Caesar V. 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"The Discovery of [Ru(NH<sub>3</sub>)<sub>5</sub>N<sub>2</sub>]<sup>2+</sup>: A Case of Serendipity and the Scientific Method". <i>Journal of Chemical Education</i>. <b>67</b> (5): 368. <a href="/wiki/Bibcode_(identifier)" class="mw-redirect" title="Bibcode (identifier)">Bibcode</a>:<a rel="nofollow" class="external text" href="https://ui.adsabs.harvard.edu/abs/1990JChEd..67..368S">1990JChEd..67..368S</a>. <a href="/wiki/Doi_(identifier)" class="mw-redirect" title="Doi (identifier)">doi</a>:<a rel="nofollow" class="external text" href="https://doi.org/10.1021%2Fed067p368">10.1021/ed067p368</a>.</cite><span title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.jtitle=Journal+of+Chemical+Education&rft.atitle=The+Discovery+of+%5BRu%28NH%3Csub%3E3%3C%2Fsub%3E%29%3Csub%3E5%3C%2Fsub%3EN%3Csub%3E2%3C%2Fsub%3E%5D%3Csup%3E2%2B%3C%2Fsup%3E%3A+A+Case+of+Serendipity+and+the+Scientific+Method&rft.volume=67&rft.issue=5&rft.pages=368&rft.date=1990&rft_id=info%3Adoi%2F10.1021%2Fed067p368&rft_id=info%3Abibcode%2F1990JChEd..67..368S&rft.aulast=Senoff&rft.aufirst=Caesar+V.&rfr_id=info%3Asid%2Fen.wikipedia.org%3APentaamine%28dinitrogen%29ruthenium%28II%29+chloride" class="Z3988"></span></span> </li> <li id="cite_note-3"><span class="mw-cite-backlink"><b><a href="#cite_ref-3">^</a></b></span> <span class="reference-text"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1238218222"><cite id="CITEREFFergussonLoveRobinson1972" class="citation journal cs1">Fergusson, J. 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"Binuclear Ion Containing Nitrogen as a Bridging Group". <i>Science</i>. <b>159</b> (3812): <span class="nowrap">320–</span>322. <a href="/wiki/Bibcode_(identifier)" class="mw-redirect" title="Bibcode (identifier)">Bibcode</a>:<a rel="nofollow" class="external text" href="https://ui.adsabs.harvard.edu/abs/1968Sci...159..320H">1968Sci...159..320H</a>. <a href="/wiki/Doi_(identifier)" class="mw-redirect" title="Doi (identifier)">doi</a>:<a rel="nofollow" class="external text" href="https://doi.org/10.1126%2Fscience.159.3812.320">10.1126/science.159.3812.320</a>. <a href="/wiki/PMID_(identifier)" class="mw-redirect" title="PMID (identifier)">PMID</a> <a rel="nofollow" class="external text" href="https://pubmed.ncbi.nlm.nih.gov/5634502">5634502</a>. <a href="/wiki/S2CID_(identifier)" class="mw-redirect" title="S2CID (identifier)">S2CID</a> <a rel="nofollow" class="external text" href="https://api.semanticscholar.org/CorpusID:39569679">39569679</a>.</cite><span title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.jtitle=Science&rft.atitle=Binuclear+Ion+Containing+Nitrogen+as+a+Bridging+Group&rft.volume=159&rft.issue=3812&rft.pages=%3Cspan+class%3D%22nowrap%22%3E320-%3C%2Fspan%3E322&rft.date=1968&rft_id=info%3Adoi%2F10.1126%2Fscience.159.3812.320&rft_id=https%3A%2F%2Fapi.semanticscholar.org%2FCorpusID%3A39569679%23id-name%3DS2CID&rft_id=info%3Apmid%2F5634502&rft_id=info%3Abibcode%2F1968Sci...159..320H&rft.aulast=Harrison&rft.aufirst=D.+F.&rft.au=Weissberger%2C+E.&rft.au=Taube%2C+H.&rfr_id=info%3Asid%2Fen.wikipedia.org%3APentaamine%28dinitrogen%29ruthenium%28II%29+chloride" class="Z3988"></span></span> </li> <li id="cite_note-8"><span class="mw-cite-backlink"><b><a href="#cite_ref-8">^</a></b></span> <span class="reference-text"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1238218222"><cite id="CITEREFChatt1970" class="citation journal cs1">Chatt, J. 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"Molecular Nitrogen as a Ligand". <i>Pure and Applied Chemistry</i>. <b>24</b> (2): <span class="nowrap">425–</span>442. <a href="/wiki/Doi_(identifier)" class="mw-redirect" title="Doi (identifier)">doi</a>:<a rel="nofollow" class="external text" href="https://doi.org/10.1351%2Fpac197024020425">10.1351/pac197024020425</a>.</cite><span title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.jtitle=Pure+and+Applied+Chemistry&rft.atitle=Molecular+Nitrogen+as+a+Ligand&rft.volume=24&rft.issue=2&rft.pages=%3Cspan+class%3D%22nowrap%22%3E425-%3C%2Fspan%3E442&rft.date=1970&rft_id=info%3Adoi%2F10.1351%2Fpac197024020425&rft.aulast=Chatt&rft.aufirst=J.&rfr_id=info%3Asid%2Fen.wikipedia.org%3APentaamine%28dinitrogen%29ruthenium%28II%29+chloride" class="Z3988"></span></span> </li> </ol></div>    </div><noscript><img src="https://login.wikimedia.org/wiki/Special:CentralAutoLogin/start?useformat=desktop&type=1x1&usesul3=0" alt="" width="1" height="1" style="border: none; position: absolute;"></noscript> <div class="printfooter" data-nosnippet="">Retrieved from "<a dir="ltr" href="https://en.wikipedia.org/w/index.php?title=Pentaamine(dinitrogen)ruthenium(II)_chloride&oldid=1217740301">https://en.wikipedia.org/w/index.php?title=Pentaamine(dinitrogen)ruthenium(II)_chloride&oldid=1217740301</a>"</div></div> <div id="catlinks" class="catlinks" data-mw="interface"><div id="mw-normal-catlinks" class="mw-normal-catlinks"><a href="/wiki/Help:Category" title="Help:Category">Categories</a>: <ul><li><a href="/wiki/Category:Ruthenium_complexes" title="Category:Ruthenium complexes">Ruthenium complexes</a></li><li><a href="/wiki/Category:Chlorides" title="Category:Chlorides">Chlorides</a></li><li><a href="/wiki/Category:Coordination_complexes" title="Category:Coordination complexes">Coordination complexes</a></li><li><a href="/wiki/Category:Ammine_complexes" title="Category:Ammine complexes">Ammine complexes</a></li><li><a href="/wiki/Category:Ruthenium(II)_compounds" title="Category:Ruthenium(II) compounds">Ruthenium(II) compounds</a></li><li><a href="/wiki/Category:Nitrogen_compounds" title="Category:Nitrogen compounds">Nitrogen compounds</a></li></ul></div><div id="mw-hidden-catlinks" class="mw-hidden-catlinks mw-hidden-cats-hidden">Hidden categories: <ul><li><a href="/wiki/Category:Chemicals_without_a_PubChem_CID" title="Category:Chemicals without a PubChem CID">Chemicals without a PubChem CID</a></li><li><a href="/wiki/Category:Articles_without_InChI_source" title="Category:Articles without InChI source">Articles without InChI source</a></li><li><a href="/wiki/Category:Chemical_pages_without_ChemSpiderID" title="Category:Chemical pages without ChemSpiderID">Chemical pages without ChemSpiderID</a></li><li><a href="/wiki/Category:Articles_without_EBI_source" title="Category:Articles without EBI source">Articles without EBI source</a></li><li><a href="/wiki/Category:Articles_without_KEGG_source" title="Category:Articles without KEGG source">Articles without KEGG source</a></li><li><a href="/wiki/Category:Articles_without_UNII_source" title="Category:Articles without UNII source">Articles without UNII source</a></li><li><a href="/wiki/Category:Articles_containing_unverified_chemical_infoboxes" title="Category:Articles containing unverified chemical infoboxes">Articles containing unverified chemical infoboxes</a></li><li><a href="/wiki/Category:Articles_with_short_description" title="Category:Articles with short description">Articles with short description</a></li><li><a href="/wiki/Category:Short_description_matches_Wikidata" title="Category:Short description matches Wikidata">Short description matches Wikidata</a></li></ul></div></div> </div> </main> </div> <div class="mw-footer-container"> <footer id="footer" class="mw-footer" > <ul id="footer-info"> <li id="footer-info-lastmod"> This page was last edited on 7 April 2024, at 16:05<span class="anonymous-show"> (UTC)</span>.</li> <li id="footer-info-copyright">Text is available under the <a href="/wiki/Wikipedia:Text_of_the_Creative_Commons_Attribution-ShareAlike_4.0_International_License" title="Wikipedia:Text of the Creative Commons Attribution-ShareAlike 4.0 International License">Creative Commons Attribution-ShareAlike 4.0 License</a>; additional terms may apply. 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