CINXE.COM

<!DOCTYPE html><html><head><title>Advances in Inorganic Chemistry: Homogeneous Biomimetic Oxidation Catalysis - Rudi van Eldik, Jan Reedijk - Google Books</title><link rel="stylesheet" href="/books/css/_a33f2a89320471e58c940b9287b9d4eb/kl_viewport_kennedy_full_bundle.css" type="text/css" /><link rel="stylesheet"href="https://fonts.googleapis.com/css2?family=Product+Sans:wght@400"><script src="/books/javascript/v2_a33f2a89320471e58c940b9287b9d4eb__en.js"></script><script>_OC_Hooks = ["_OC_Page", "_OC_SearchReload", "_OC_TocReload", "_OC_EmptyFunc", "_OC_SearchPage", "_OC_QuotePage" ];for (var _OC_i = 0; _OC_i < _OC_Hooks.length; _OC_i++) {eval("var " + _OC_Hooks[_OC_i] + ";");}function _OC_InitHooks () {for (var i = 0; i < _OC_Hooks.length; i++) {var func = arguments[i];eval( _OC_Hooks[i] + " = func;");}}</script><link rel="canonical" href="https://books.google.com/books/about/Advances_in_Inorganic_Chemistry.html?id=UgNp8-wq-aAC"/><meta property="og:url" content="https://books.google.com/books/about/Advances_in_Inorganic_Chemistry.html?id=UgNp8-wq-aAC"/><meta name="title" content="Advances in Inorganic Chemistry"/><meta name="description" content="Advances in Inorganic Chemistry Volume 58 focuses on homogeneous biomimetic oxidation catalysis. Contributions by leading experts in the field cover important advances in inorganic and bioinorganic chemistry. Contributions include diversity-based approaches to selective biomimetic oxidation catalysis; the selective conversion of hydrocarbons with H2O2 using biomimetic non-heme iron and manganese oxidation catalysis; DNA oxidation by copper and manganese complexes; influences of the ligand in copper-dioxygen complex-formation and substrate oxidations; biomimetic oxidations by dinuclear and trinuclear copper complexes. In the final contribution the authors focus on green oxidation of alcohols using biomimetic copper complexes and enzymes as catalysts. Volume 58 provides another welcomed addition to the widely acclaimed series, Advances in Inorganic Chemistry.* Includes new information on the important advances in inorganic and bioinorganic chemistry * Each chapter is fully referenced * Contains comprehensive reviews written by leading experts in the field"/><meta property="og:title" content="Advances in Inorganic Chemistry"/><meta property="og:type" content="book"/><meta property="og:site_name" content="Google Books"/><meta property="og:image" content="https://books.google.com.sg/books/content?id=UgNp8-wq-aAC&printsec=frontcover&img=1&zoom=1&edge=curl&imgtk=AFLRE73VJeFEH57eOstFs4rToR-YSUxTngGsYV41S4e4uJpLCWLXJHUBWkQdCPp23ecl2Y76S3bnoB6Ufinze8FjPfHSKcgRG_499YmBZ3Qg1AV9pFdXiCjlM4YQW-f0luWy6RpAoOJp"/><link rel="image_src" href="https://books.google.com.sg/books/content?id=UgNp8-wq-aAC&printsec=frontcover&img=1&zoom=1&edge=curl&imgtk=AFLRE73VJeFEH57eOstFs4rToR-YSUxTngGsYV41S4e4uJpLCWLXJHUBWkQdCPp23ecl2Y76S3bnoB6Ufinze8FjPfHSKcgRG_499YmBZ3Qg1AV9pFdXiCjlM4YQW-f0luWy6RpAoOJp"/><script></script><style>#gbar,#guser{font-size:13px;padding-top:1px !important;}#gbar{height:22px}#guser{padding-bottom:7px !important;text-align:right}.gbh,.gbd{border-top:1px solid #c9d7f1;font-size:1px}.gbh{height:0;position:absolute;top:24px;width:100%}@media all{.gb1{height:22px;margin-right:.5em;vertical-align:top}#gbar{float:left}}a.gb1,a.gb4{text-decoration:underline !important}a.gb1,a.gb4{color:#00c !important}.gbi .gb4{color:#dd8e27 !important}.gbf .gb4{color:#900 !important} #gbar { padding:.3em .6em !important;}</style></head><body class=""><div id=gbar><nobr><a target=_blank class=gb1 href="https://www.google.com.sg/search?tab=pw">Search</a> <a target=_blank class=gb1 href="https://www.google.com.sg/imghp?hl=en&tab=pi">Images</a> <a target=_blank class=gb1 href="https://maps.google.com.sg/maps?hl=en&tab=pl">Maps</a> <a target=_blank class=gb1 href="https://play.google.com/?hl=en&tab=p8">Play</a> <a target=_blank class=gb1 href="https://www.youtube.com/?tab=p1">YouTube</a> <a target=_blank class=gb1 href="https://news.google.com/?tab=pn">News</a> <a target=_blank class=gb1 href="https://mail.google.com/mail/?tab=pm">Gmail</a> <a target=_blank class=gb1 href="https://drive.google.com/?tab=po">Drive</a> <a target=_blank class=gb1 style="text-decoration:none" href="https://www.google.com.sg/intl/en/about/products?tab=ph"><u>More</u> »</a></nobr></div><div id=guser width=100%><nobr><span id=gbn class=gbi></span><span id=gbf class=gbf></span><span id=gbe></span><a target=_top id=gb_70 href="https://www.google.com/accounts/Login?service=print&continue=https://books.google.com.sg/books%3Fid%3DUgNp8-wq-aAC%26q%3Dredox%26dq%3Dsubject:%2522Science%2BChemistry%2522%26source%3Dgbs_word_cloud_r%26hl%3Den&hl=en&ec=GAZACg" class=gb4>Sign in</a></nobr></div><div class=gbh style=left:0></div><div class=gbh style=right:0></div><div role="alert" style="position: absolute; left: 0; right: 0;"><a href="https://books.google.com.sg/books?id=UgNp8-wq-aAC&q=redox&dq=subject:%22Science+Chemistry%22&source=gbs_word_cloud_r&hl=en&output=html_text" title="Screen reader users: click this link for accessible mode. Accessible mode has the same essential features but works better with your reader."><img border="0" src="//www.google.com/images/cleardot.gif"alt="Screen reader users: click this link for accessible mode. Accessible mode has the same essential features but works better with your reader."></a></div><div class="kd-appbar"><h2 class="kd-appname"><a href="/books">Books</a></h2><div class="kd-buttonbar left" id="left-toolbar-buttons"><a id="appbar-view-print-sample-link" href="https://books.google.com.sg/books?id=UgNp8-wq-aAC&printsec=frontcover&vq=redox&source=gbs_vpt_read"></a><a id="appbar-view-ebook-sample-link" href="https://play.google.com/books/reader?id=UgNp8-wq-aAC&source=gbs_vpt_read"></a><a id="appbar-patents-prior-art-finder-link" href=""></a><a id="appbar-patents-discuss-this-link" href="" data-is-grant=""></a><a id="appbar-read-patent-link" href=""></a><a id="appbar-download-pdf-link" href=""></a></div><div class="kd-buttonbar right" id="right-toolbar-buttons"></div></div><div style="display: none"><ol id="ofe-gear-menu-contents" class="gbmcc"><li class="gbe gbmtc"><a class="gbmt goog-menuitem-content" id="" href="https://www.google.com/accounts/Login?service=print&continue=https://books.google.com.sg/books%3Fop%3Dlibrary&hl=en">My library</a></li><li class="gbe gbmtc"><a class="gbmt goog-menuitem-content" id="" href="http://books.google.com.sg/support/topic/4359341?hl=en-SG">Help</a></li><li class="gbe gbmtc"><a class="gbmt goog-menuitem-content" id="" href="https://books.google.com.sg/advanced_book_search?q=subject:%22Science+Chemistry%22">Advanced Book Search</a></li></ol></div><div id="volume-main"><div id="volume-left"><div id=menu_container ><div id="menu_scroll_wrapper"><div id="menu_scroll" role="navigation"><div id="gb-get-book-container"><a href="https://play.google.com/store/books/details?id=UgNp8-wq-aAC&rdid=book-UgNp8-wq-aAC&rdot=1&source=gbs_vpt_read&pcampaignid=books_booksearch_viewport" id="gb-get-book-content">Buy eBook - SGD 317.81</a></div><p id="gb-buy-options-trigger" class="gb-buy-options-link">Get this book in print</p><h3 class=about_title><a name="buy_anchor"></a></h3><div id=buy class=about_content><div id=buy_v><ul style="list-style-type: none; padding-left: 0; margin: 0;"><li><a style="white-space:normal" href="https://www.elsevier.com/books/advances-in-inorganic-chemistry/van-eldik/978-0-12-023658-9" dir=ltr onMouseOver="this.href='https://www.elsevier.com/books/advances-in-inorganic-chemistry/van-eldik/978-0-12-023658-9';return false" onMouseDown="this.href='/url?client\x3dca-print-elsevier-academic_press\x26format\x3dgoogleprint\x26num\x3d0\x26id\x3dUgNp8-wq-aAC\x26q\x3dhttps://www.elsevier.com/books/advances-in-inorganic-chemistry/van-eldik/978-0-12-023658-9\x26usg\x3dAOvVaw3t0n6E_aFSl4BwFIeW_SC9\x26source\x3dgbs_buy_r';return true"><span dir=ltr>Buy Direct from Elsevier</span></a></li><li><a style="white-space:normal" href="http://www.amazon.com/gp/search?index=books&linkCode=qs&keywords=9780080462172" dir=ltr onMouseOver="this.href='http://www.amazon.com/gp/search?index\x3dbooks\x26linkCode\x3dqs\x26keywords\x3d9780080462172';return false" onMouseDown="this.href='/url?client\x3dca-print-elsevier-academic_press\x26format\x3dgoogleprint\x26num\x3d0\x26id\x3dUgNp8-wq-aAC\x26q\x3dhttp://www.amazon.com/gp/search%3Findex%3Dbooks%26linkCode%3Dqs%26keywords%3D9780080462172\x26usg\x3dAOvVaw1zDPXY4buAsPqNIqWJvHq8\x26source\x3dgbs_buy_r';return true"><span dir=ltr>Amazon.com</span></a></li><li><a style="white-space:normal" href="http://www.mphonline.com/books/nsearch.aspx?do=detail&pcode=9780080462172" dir=ltr onMouseOver="this.href='http://www.mphonline.com/books/nsearch.aspx?do\x3ddetail\x26pcode\x3d9780080462172';return false" onMouseDown="this.href='/url?client\x3dca-print-elsevier-academic_press\x26format\x3dgoogleprint\x26num\x3d0\x26id\x3dUgNp8-wq-aAC\x26q\x3dhttp://www.mphonline.com/books/nsearch.aspx%3Fdo%3Ddetail%26pcode%3D9780080462172\x26usg\x3dAOvVaw2ex_OvBz-jZwZdrNm3b5Z6\x26source\x3dgbs_buy_r';return true"><span dir=ltr>MPH</span></a></li><li><a style="white-space:normal" href="https://www.popular.com.sg/catalogsearch/result/?q=9780080462172" dir=ltr onMouseOver="this.href='https://www.popular.com.sg/catalogsearch/result/?q\x3d9780080462172';return false" onMouseDown="this.href='/url?client\x3dca-print-elsevier-academic_press\x26format\x3dgoogleprint\x26num\x3d0\x26id\x3dUgNp8-wq-aAC\x26q\x3dhttps://www.popular.com.sg/catalogsearch/result/%3Fq%3D9780080462172\x26usg\x3dAOvVaw31RPIQA7d8S3dmU-l_v8sC\x26source\x3dgbs_buy_r';return true"><span dir=ltr>Popular</span></a></li><li><hr style="margin-right: 20%; color: #666;"></li><li><a style="white-space:normal" href="https://books.google.com.sg/url?id=UgNp8-wq-aAC&pg=PA95&q=http://www.worldcat.org/oclc/1113213446&clientid=librarylink&usg=AOvVaw0u7NgeMl_NjXLIbCqFHqA9&source=gbs_buy_r"><span dir=ltr>Find in a library</span></a></li><li><a class="secondary" style="white-space:normal" href="https://books.google.com.sg/books?id=UgNp8-wq-aAC&sitesec=buy&source=gbs_buy_r" id="get-all-sellers-link"><span dir=ltr>All sellers</span> »</a></li></ul></div></div><div class=menu id=menu><div class="menu_content" style="margin-bottom:6px"><div style="margin-bottom:4px"><div class="sidebarnav"><table border="0" cellpadding="0" cellspacing="0"><tr><td><div class="sidebarcover"><a href="https://books.google.com.sg/books?id=UgNp8-wq-aAC&printsec=frontcover&vq=redox" onclick="_OC_Page('PP1',this.href); return false;"><img src="https://books.google.com.sg/books/content?id=UgNp8-wq-aAC&printsec=frontcover&img=1&zoom=5&edge=curl&imgtk=AFLRE73WOAEvU6eHNzMHZ-npCqEodwPWxKFDI1tjCQg2vZrQ_jgi_42m-nixpCjtfr1oA77HzGlG_CyCSr99S34B3hQIplmvJ6ivpvzcxzA7trOe-eCaRC-Vy30nvPHUFmeCfUGNtTUI" alt="Front Cover" title="Front Cover" height=80 border=1 id=summary-frontcover ></a></div></td><td></td></tr></table></div><div style="clear:both"></div></div><div id="volume-info-sidebar"><h1 class="gb-volume-title" dir=ltr>Advances in Inorganic Chemistry: Homogeneous Biomimetic Oxidation Catalysis</h1><span class="addmd">By Rudi van Eldik, Jan Reedijk</span></div><div style="margin-bottom:3px"><form action=/books id=search_form style="margin:0px;padding:0px;" method=get> <input type=hidden name="id" value="UgNp8-wq-aAC"><input type=hidden name="dq" value="subject:"Science Chemistry""><table cellpadding=0 cellspacing=0 class="swv-table"><tr><td class="swv-td-search"><span><input id=search_form_input type=text maxlength=1024 class="text_flat swv-input-search" aria-label="Search in this book" name=q value="" title="Go" accesskey=i></span></td><td class="swv-td-space"><div> </div></td><td><input type=submit value="Go"></td></tr></table><script type="text/javascript">if (window['_OC_autoDir']) {_OC_autoDir('search_form_input');}</script></form></div><div><p><a id="sidebar-atb-link" href="https://books.google.com.sg/books?id=UgNp8-wq-aAC&vq=redox&dq=subject:%22Science+Chemistry%22&source=gbs_navlinks_s"><span dir=ltr>About this book</span></a></p></div></div></div><div><div id="navbarContainer" class="gb-navbar"></div><script>_OC_InitNavbar({"child_node":[{"title":"My library","url":"https://books.google.com.sg/books?uid=114584440181414684107\u0026source=gbs_lp_bookshelf_list","id":"my_library","collapsed":true},{"title":"My History","url":"","id":"my_history","collapsed":true}],"highlighted_node_id":""});</script><a href="/intl/en/googlebooks/tos.html" target="_blank">Terms of Service</a><h3 class=about_title><a name="pub_info_anchor"></a></h3><div id=pub_info class=about_content><div id=pub_info_v><table cellspacing=0><tr><td><a href="https://books.google.com.sg/url?id=UgNp8-wq-aAC&pg=PA95&q=https://www.elsevier.com/books-and-journals&clientid=ca-print-elsevier-academic_press&linkid=1&usg=AOvVaw1hufpoNvVr3WhSU8JGve-N&source=gbs_pub_info_r" style="text-decoration:none"><img width=25 height=35 border=0 src="https://pagead2.googlesyndication.com/pagead/imgad?id=CMSjweqOm5D25gEQJRgyMgj-lPFy73claA" alt="Elsevier"></a><tr><td style="font-size:84.6%;color:#666666">Pages displayed by permission of <a class=link_aux href="https://books.google.com.sg/url?id=UgNp8-wq-aAC&pg=PA95&q=https://www.elsevier.com/books-and-journals&clientid=ca-print-elsevier-academic_press&linkid=1&usg=AOvVaw1hufpoNvVr3WhSU8JGve-N&source=gbs_pub_info_r">Elsevier</a>. <a style="color:#7777cc;white-space:normal" href="https://books.google.com.sg/books?id=UgNp8-wq-aAC&printsec=copyright&vq=redox&source=gbs_pub_info_r">Copyright</a>. </table></div></div></div></div></div></div></div><div id="volume-center"><div id="scroll_atb" role="main"><div id="toolbar_container"><div style="float:left;white-space:nowrap"><table cellpadding=0 cellspacing=0><tr><td id="l_toolbar"></td><td class=toolbar-pc-cell><table cellpadding=0 cellspacing=0><tr><td class=no-jump-cell align=right><span id=page_label style="margin-right:.5em">Page 95</span></td><td class=arrow style="padding-right:2px"><a href="https://books.google.com.sg/books?id=UgNp8-wq-aAC&pg=PA94&lpg=PA95&focus=viewport&vq=redox&dq=subject:%22Science+Chemistry%22" onclick="_OC_EmptyFunc(this.href); return false;"><div class=pagination><div id=prev_btn alt="Previous Page" title="Previous Page" class="SPRITE_pagination_v2_left"></div></div></a></td><td class=arrow><a href="https://books.google.com.sg/books?id=UgNp8-wq-aAC&pg=PA96&lpg=PA95&focus=viewport&vq=redox&dq=subject:%22Science+Chemistry%22" onclick="_OC_EmptyFunc(this.href); return false;"><div class=pagination><div id=next_btn alt="Next Page" title="Next Page" class="SPRITE_pagination_v2_right"></div></div></a></td></tr></table></td><td>  </td><td id=view_toolbar></td><td id=view_new></td></tr></table></div><div style="float:right"><table cellpadding=0 cellspacing=0><tr><td></td><td id="r_toolbar" style="white-space:nowrap"></td></tr></table></div><div style="clear:both"></div></div><div id="search_bar"></div><div class="gback"><div id="viewport" class="viewport" tabindex="0"><a name="page" accesskey="c"></a><table class="viewport-table" id="container" align="center" cellpadding="0" cellspacing="0"><tr><td valign="top" align="center"><noscript><style type=text/css>.imgg { width:575px;height:835px;background:#eee;padding-bottom:25px}</style><div class=imgg><div align=center><table border=0 cellpadding=0 cellspacing=0 width=500 align=center style="margin-top:2em"><tr><td rowspan=2 valign=top style="width:9px;background:#fff url('/googlebooks/bbl_l.gif') top left repeat-y"><img src="/googlebooks/bbl_tl.gif" width=9 height=7 alt=""></td><td style="background:url('/googlebooks/bbl_t.gif') top left repeat-x"><img width=1 height=7 alt=""></td><td rowspan=2 valign=top style="width:10px;background:#fff url('/googlebooks/bbl_r.gif') top right repeat-y"><img src="/googlebooks/bbl_tr.gif" width=10 height=7 alt=""></td></tr><tr><td align=center style="background:#ff9;text-align:center;line-height:1.2em"><div style="margin:1em"><img width=60 height=60 align=absmiddle src="/googlebooks/restricted_logo.gif" alt=""> <span style="font-weight:bold;font-size:1.2em"><br>Restricted Page</span></div><div style="margin:1em" align=left>You have reached your viewing limit for this book (<a href=https://books.google.com.sg/support/answer/43729?topic=9259&hl=en>why?</a>).</div></td></tr><tr><td><img src="/googlebooks/bbl_bl.gif" width=9 height=9 alt=""></td><td style="background:url('/googlebooks/bbl_b.gif') bottom left repeat-x"><img width=1 height=9 alt=""></td><td><img src="/googlebooks/bbl_br.gif" width=10 height=9 alt=""></td></tr></table></div></div></noscript></td></tr></table></div></div><script>_OC_addFlags({Host:"https://books.google.com.sg/", IsBooksUnifiedLeftNavEnabled:1, IsZipitFolderCollectionEnabled:1, IsBrowsingHistoryEnabled:1, IsBooksRentalEnabled:1});_OC_Run({"page":[{"pid":"PP1","flags":32,"order":0},{"pid":"PR3","order":3,"title":"iii"},{"pid":"PR4","order":4,"title":"iv"},{"pid":"PR5","order":5,"title":"v"},{"pid":"PR6","order":6,"title":"vi"},{"pid":"PR7","order":7,"title":"vii"},{"pid":"PR8","order":8,"title":"viii"},{"pid":"PA1","order":9,"title":"1"},{"pid":"PA2","order":10,"title":"2"},{"pid":"PA3","order":11,"title":"3"},{"pid":"PA4","order":12,"title":"4"},{"pid":"PA5","order":13,"title":"5"},{"pid":"PA6","order":14,"title":"6"},{"pid":"PA7","order":15,"title":"7"},{"pid":"PA8","order":16,"title":"8"},{"pid":"PA9","order":17,"title":"9"},{"pid":"PA10","order":18,"title":"10"},{"pid":"PA11","order":19,"title":"11"},{"pid":"PA12","order":20,"title":"12"},{"pid":"PA13","order":21,"title":"13"},{"pid":"PA14","order":22,"title":"14"},{"pid":"PA15","order":23,"title":"15"},{"pid":"PA16","order":24,"title":"16"},{"pid":"PA17","order":25,"title":"17"},{"pid":"PA18","order":26,"title":"18"},{"pid":"PA19","order":27,"title":"19"},{"pid":"PA20","order":28,"title":"20"},{"pid":"PA21","order":29,"title":"21"},{"pid":"PA22","order":30,"title":"22"},{"pid":"PA23","order":31,"title":"23"},{"pid":"PA24","order":32,"title":"24"},{"pid":"PA25","order":33,"title":"25"},{"pid":"PA26","order":34,"title":"26"},{"pid":"PA27","order":35,"title":"27"},{"pid":"PA28","order":36,"title":"28"},{"pid":"PA29","order":37,"title":"29"},{"pid":"PA30","order":38,"title":"30"},{"pid":"PA31","order":39,"title":"31"},{"pid":"PA32","order":40,"title":"32"},{"pid":"PA33","order":41,"title":"33"},{"pid":"PA34","order":42,"title":"34"},{"pid":"PA35","order":43,"title":"35"},{"pid":"PA36","order":44,"title":"36"},{"pid":"PA37","order":45,"title":"37"},{"pid":"PA38","order":46,"title":"38"},{"pid":"PA39","order":47,"title":"39"},{"pid":"PA40","order":48,"title":"40"},{"pid":"PA41","order":49,"title":"41"},{"pid":"PA42","order":50,"title":"42"},{"pid":"PA43","order":51,"title":"43"},{"pid":"PA44","order":52,"title":"44"},{"pid":"PA45","order":53,"title":"45"},{"pid":"PA46","order":54,"title":"46"},{"pid":"PA47","order":55,"title":"47"},{"pid":"PA48","order":56,"title":"48"},{"pid":"PA49","order":57,"title":"49"},{"pid":"PA50","order":58,"title":"50"},{"pid":"PA51","order":59,"title":"51"},{"pid":"PA52","order":60,"title":"52"},{"pid":"PA53","order":61,"title":"53"},{"pid":"PA54","order":62,"title":"54"},{"pid":"PA55","order":63,"title":"55"},{"pid":"PA56","order":64,"title":"56"},{"pid":"PA57","order":65,"title":"57"},{"pid":"PA58","order":66,"title":"58"},{"pid":"PA59","order":67,"title":"59"},{"pid":"PA60","order":68,"title":"60"},{"pid":"PA61","order":69,"title":"61"},{"pid":"PA62","order":70,"title":"62"},{"pid":"PA63","order":71,"title":"63"},{"pid":"PA64","order":72,"title":"64"},{"pid":"PA65","order":73,"title":"65"},{"pid":"PA66","order":74,"title":"66"},{"pid":"PA67","order":75,"title":"67"},{"pid":"PA68","order":76,"title":"68"},{"pid":"PA69","order":77,"title":"69"},{"pid":"PA70","order":78,"title":"70"},{"pid":"PA71","order":79,"title":"71"},{"pid":"PA72","order":80,"title":"72"},{"pid":"PA73","order":81,"title":"73"},{"pid":"PA74","order":82,"title":"74"},{"pid":"PA75","order":83,"title":"75"},{"pid":"PA76","order":84,"title":"76"},{"pid":"PA77","order":85,"title":"77"},{"pid":"PA78","order":86,"title":"78"},{"pid":"PA79","order":87,"title":"79"},{"pid":"PA80","order":88,"title":"80"},{"pid":"PA81","order":89,"title":"81"},{"pid":"PA82","order":90,"title":"82"},{"pid":"PA83","order":91,"title":"83"},{"pid":"PA84","order":92,"title":"84"},{"pid":"PA85","order":93,"title":"85"},{"pid":"PA86","order":94,"title":"86"},{"pid":"PA87","order":95,"title":"87"},{"pid":"PA88","order":96,"title":"88"},{"pid":"PA89","order":97,"title":"89"},{"pid":"PA90","order":98,"title":"90"},{"pid":"PA91","order":99,"title":"91"},{"pid":"PA92","order":100,"title":"92"},{"pid":"PA93","order":101,"title":"93"},{"pid":"PA94","flags":8,"order":102,"title":"94"},{"pid":"PA95","flags":8,"order":103,"title":"95"},{"pid":"PA96","flags":8,"order":104,"title":"96"},{"pid":"PA97","flags":8,"order":105,"title":"97"},{"pid":"PA98","flags":8,"order":106,"title":"98"},{"pid":"PA99","order":107,"title":"99"},{"pid":"PA100","order":108,"title":"100"},{"pid":"PA101","order":109,"title":"101"},{"pid":"PA102","order":110,"title":"102"},{"pid":"PA103","order":111,"title":"103"},{"pid":"PA104","order":112,"title":"104"},{"pid":"PA105","order":113,"title":"105"},{"pid":"PA106","order":114,"title":"106"},{"pid":"PA107","order":115,"title":"107"},{"pid":"PA108","order":116,"title":"108"},{"pid":"PA109","order":117,"title":"109"},{"pid":"PA110","order":118,"title":"110"},{"pid":"PA111","order":119,"title":"111"},{"pid":"PA112","order":120,"title":"112"},{"pid":"PA113","order":121,"title":"113"},{"pid":"PA114","order":122,"title":"114"},{"pid":"PA115","order":123,"title":"115"},{"pid":"PA116","order":124,"title":"116"},{"pid":"PA117","order":125,"title":"117"},{"pid":"PA118","order":126,"title":"118"},{"pid":"PA119","order":127,"title":"119"},{"pid":"PA120","order":128,"title":"120"},{"pid":"PA121","order":129,"title":"121"},{"pid":"PA122","order":130,"title":"122"},{"pid":"PA123","order":131,"title":"123"},{"pid":"PA124","order":132,"title":"124"},{"pid":"PA125","order":133,"title":"125"},{"pid":"PA126","order":134,"title":"126"},{"pid":"PA127","order":135,"title":"127"},{"pid":"PA128","order":136,"title":"128"},{"pid":"PA129","order":137,"title":"129"},{"pid":"PA130","order":138,"title":"130"},{"pid":"PA131","order":139,"title":"131"},{"pid":"PA132","order":140,"title":"132"},{"pid":"PA133","order":141,"title":"133"},{"pid":"PA134","order":142,"title":"134"},{"pid":"PA135","order":143,"title":"135"},{"pid":"PA136","order":144,"title":"136"},{"pid":"PA137","order":145,"title":"137"},{"pid":"PA138","order":146,"title":"138"},{"pid":"PA139","order":147,"title":"139"},{"pid":"PA140","order":148,"title":"140"},{"pid":"PA141","order":149,"title":"141"},{"pid":"PA142","order":150,"title":"142"},{"pid":"PA143","order":151,"title":"143"},{"pid":"PA145","order":153,"title":"145"},{"pid":"PA146","order":154,"title":"146"},{"pid":"PA148","order":156,"title":"148"},{"pid":"PA149","order":157,"title":"149"},{"pid":"PA150","order":158,"title":"150"},{"pid":"PA151","order":159,"title":"151"},{"pid":"PA152","order":160,"title":"152"},{"pid":"PA155","order":163,"title":"155"},{"pid":"PA156","order":164,"title":"156"},{"pid":"PA160","order":168,"title":"160"},{"pid":"PA162","order":170,"title":"162"},{"pid":"PA164","order":172,"title":"164"},{"pid":"PA167","order":175,"title":"167"},{"pid":"PA171","order":179,"title":"171"},{"pid":"PA172","order":180,"title":"172"},{"pid":"PA175","order":183,"title":"175"},{"pid":"PA176","order":184,"title":"176"},{"pid":"PA177","order":185,"title":"177"},{"pid":"PA178","order":186,"title":"178"},{"pid":"PA181","order":189,"title":"181"},{"pid":"PA182","order":190,"title":"182"},{"pid":"PA183","order":191,"title":"183"},{"pid":"PA184","order":192,"title":"184"},{"pid":"PA185","order":193,"title":"185"},{"pid":"PA186","order":194,"title":"186"},{"pid":"PA187","order":195,"title":"187"},{"pid":"PA188","order":196,"title":"188"},{"pid":"PA189","order":197,"title":"189"},{"pid":"PA191","order":199,"title":"191"},{"pid":"PA192","order":200,"title":"192"},{"pid":"PA193","order":201,"title":"193"},{"pid":"PA195","order":203,"title":"195"},{"pid":"PA196","order":204,"title":"196"},{"pid":"PA198","order":206,"title":"198"},{"pid":"PA199","order":207,"title":"199"},{"pid":"PA201","order":209,"title":"201"},{"pid":"PA202","order":210,"title":"202"},{"pid":"PA203","order":211,"title":"203"},{"pid":"PA204","order":212,"title":"204"},{"pid":"PA205","order":213,"title":"205"},{"pid":"PA206","order":214,"title":"206"},{"pid":"PA207","order":215,"title":"207"},{"pid":"PA208","order":216,"title":"208"},{"pid":"PA210","order":218,"title":"210"},{"pid":"PA211","order":219,"title":"211"},{"pid":"PA212","order":220,"title":"212"},{"pid":"PA215","order":223,"title":"215","h":396},{"pid":"PA216","order":224,"title":"216"},{"pid":"PA218","order":226,"title":"218"},{"pid":"PA219","order":227,"title":"219"},{"pid":"PA220","order":228,"title":"220"},{"pid":"PA221","order":229,"title":"221"},{"pid":"PA222","order":230,"title":"222"},{"pid":"PA224","order":232,"title":"224"},{"pid":"PA225","order":233,"title":"225"},{"pid":"PA227","order":235,"title":"227"},{"pid":"PA228","order":236,"title":"228"},{"pid":"PA229","order":237,"title":"229"},{"pid":"PA230","order":238,"title":"230"},{"pid":"PA231","order":239,"title":"231"},{"pid":"PA233","order":241,"title":"233"},{"pid":"PA234","order":242,"title":"234"},{"pid":"PA235","order":243,"title":"235"},{"pid":"PA236","order":244,"title":"236"},{"pid":"PA237","order":245,"title":"237"},{"pid":"PA238","order":246,"title":"238"},{"pid":"PA240","order":248,"title":"240"},{"pid":"PA241","order":249,"title":"241"},{"pid":"PA243","order":251,"title":"243"},{"pid":"PA244","order":252,"title":"244"},{"pid":"PA245","order":253,"title":"245"},{"pid":"PA248","order":256,"title":"248"},{"pid":"PA250","order":258,"title":"250"},{"pid":"PA252","order":260,"title":"252"},{"pid":"PA253","order":261,"title":"253","h":396},{"pid":"PA255","order":263,"title":"255"},{"pid":"PA257","order":265,"title":"257"},{"pid":"PA258","order":266,"title":"258"},{"pid":"PA260","order":268,"title":"260","h":396},{"pid":"PA262","order":270,"title":"262"},{"pid":"PA265","order":273,"title":"265"},{"pid":"PA266","order":274,"title":"266"},{"pid":"PA267","order":275,"title":"267","h":396},{"pid":"PA268","order":276,"title":"268"},{"pid":"PA270","order":278,"title":"270"},{"pid":"PA271","order":279,"title":"271"},{"pid":"PA272","order":280,"title":"272"},{"pid":"PA273","order":281,"title":"273"},{"pid":"PA274","order":282,"title":"274"},{"pid":"PA275","order":283,"title":"275","h":396},{"pid":"PA280","order":288,"title":"280"},{"pid":"PA281","order":289,"title":"281"},{"pid":"PA282","order":290,"title":"282"},{"pid":"PA283","order":291,"title":"283"},{"pid":"PA284","order":292,"title":"284"},{"pid":"PA285","order":293,"title":"285"},{"pid":"PA286","order":294,"title":"286"},{"pid":"PA287","order":295,"title":"287"},{"pid":"PA288","order":296,"title":"288"},{"pid":"PA289","order":297,"title":"289"}],"prefix":"https://books.google.com.sg/books?id=UgNp8-wq-aAC\u0026lpg=PA95\u0026vq=redox\u0026dq=subject:%22Science+Chemistry%22"},{"fullview":false,"page_width":575,"page_height":835,"font_height":12,"first_content_page":9,"disable_twopage":true,"initial_zoom_width_override":685,"show_print_pages_button":false,"title":"Advances in Inorganic Chemistry","subtitle":"Homogeneous Biomimetic Oxidation Catalysis","attribution":"By Rudi van Eldik, Jan Reedijk","additional_info":{"[JsonBookInfo]":{"BuyLinks":[{"Seller":"Buy Direct from Elsevier","Url":"https://www.elsevier.com/books/advances-in-inorganic-chemistry/van-eldik/978-0-12-023658-9","TrackingUrl":"/url?client=ca-print-elsevier-academic_press\u0026format=googleprint\u0026num=0\u0026id=UgNp8-wq-aAC\u0026q=https://www.elsevier.com/books/advances-in-inorganic-chemistry/van-eldik/978-0-12-023658-9\u0026usg=AOvVaw3t0n6E_aFSl4BwFIeW_SC9","IsPublisher":true},{"Seller":"Amazon.com","Url":"http://www.amazon.com/gp/search?index=books\u0026linkCode=qs\u0026keywords=9780080462172","TrackingUrl":"/url?client=ca-print-elsevier-academic_press\u0026format=googleprint\u0026num=0\u0026id=UgNp8-wq-aAC\u0026q=http://www.amazon.com/gp/search%3Findex%3Dbooks%26linkCode%3Dqs%26keywords%3D9780080462172\u0026usg=AOvVaw1zDPXY4buAsPqNIqWJvHq8"},{"Seller":"MPH","Url":"http://www.mphonline.com/books/nsearch.aspx?do=detail\u0026pcode=9780080462172","TrackingUrl":"/url?client=ca-print-elsevier-academic_press\u0026format=googleprint\u0026num=0\u0026id=UgNp8-wq-aAC\u0026q=http://www.mphonline.com/books/nsearch.aspx%3Fdo%3Ddetail%26pcode%3D9780080462172\u0026usg=AOvVaw2ex_OvBz-jZwZdrNm3b5Z6"},{"Seller":"Popular","Url":"https://www.popular.com.sg/catalogsearch/result/?q=9780080462172","TrackingUrl":"/url?client=ca-print-elsevier-academic_press\u0026format=googleprint\u0026num=0\u0026id=UgNp8-wq-aAC\u0026q=https://www.popular.com.sg/catalogsearch/result/%3Fq%3D9780080462172\u0026usg=AOvVaw31RPIQA7d8S3dmU-l_v8sC"}],"AboutUrl":"https://books.google.com.sg/books?id=UgNp8-wq-aAC","PreviewUrl":"https://books.google.com.sg/books?id=UgNp8-wq-aAC","allowed_syndication_flags":{"allow_disabling_chrome":true},"online_access":{"url":"https://play.google.com/store/books/details?id=UgNp8-wq-aAC\u0026rdid=book-UgNp8-wq-aAC\u0026rdot=1","price":"SGD 317.81","list_price":"SGD 402.66"},"TocLine":[{"Title":"DiversityBased Approaches to Selective Biomimetic Oxidation Catalysis","Pid":"PA1","PgNum":"1","Order":9},{"Title":"Selective Conversion of Hydrocarbons with H2O2 Using Biomimetic Nonheme Iron and Manganese Oxidation Catalysts","Pid":"PA29","PgNum":"29","Order":37},{"Title":"DNA Oxidation by Copper and Manganese Complexes","Pid":"PA77","PgNum":"77","Order":85},{"Title":"Ligand Influences in CopperDioxygen ComplexFormation and Substrate Oxidations","Pid":"PA131","PgNum":"131","Order":139},{"Title":"Biomimetic Oxidations by Dinuclear and Trinuclear Copper Complexes","Pid":"PA185","PgNum":"185","Order":193},{"Title":"Green oxidation of alcohols using biomimetic Cu complexes and Cu enzymes as catalysts","Pid":"PA235","PgNum":"235","Order":243},{"Title":"Index","Pid":"PA281","PgNum":"281","Order":289},{"Title":"Contents of Previous Volumes","Pid":"PA285","PgNum":"285","Order":293}]}},"table_of_contents_page_id":"PR5","max_resolution_image_width":1280,"max_resolution_image_height":1858,"num_toc_pages":2,"quality_info":"We have no quality information about this book.","volume_id":"UgNp8-wq-aAC","permission_info":"Pages displayed by permission of \u003ca class=link_aux href=\"https://books.google.com.sg/url?id=UgNp8-wq-aAC\u0026pg=PA95\u0026q=https://www.elsevier.com/books-and-journals\u0026clientid=ca-print-elsevier-academic_press\u0026linkid=1\u0026usg=AOvVaw1hufpoNvVr3WhSU8JGve-N\u0026source=gbs_pub_info_r\"\u003eElsevier\u003c/a\u003e","is_ebook":true,"volumeresult":{"has_flowing_text":false,"has_scanned_text":true,"can_download_pdf":false,"can_download_epub":false,"is_pdf_drm_enabled":false,"is_epub_drm_enabled":false},"publisher":"Elsevier","publication_date":"2006.01.18","subject":"Science","num_pages":298,"sample_url":"https://play.google.com/books/reader?id=UgNp8-wq-aAC\u0026source=gbs_vpt_hover","synposis":"Advances in Inorganic Chemistry Volume 58 focuses on homogeneous biomimetic oxidation catalysis. Contributions by leading experts in the field cover important advances in inorganic and bioinorganic chemistry. Contributions include diversity-based approaches to selective biomimetic oxidation catalysis; the selective conversion of hydrocarbons with H2O2 using biomimetic non-heme iron and manganese oxidation catalysis; DNA oxidation by copper and manganese complexes; influences of the ligand in copper-dioxygen complex-formation and substrate oxidations; biomimetic oxidations by dinuclear and trinuclear copper complexes. In the final contribution the authors focus on green oxidation of alcohols using biomimetic copper complexes and enzymes as catalysts. Volume 58 provides another welcomed addition to the widely acclaimed series, Advances in Inorganic Chemistry.* Includes new information on the important advances in inorganic and bioinorganic chemistry * Each chapter is fully referenced * Contains comprehensive reviews written by leading experts in the field","my_library_url":"https://www.google.com/accounts/Login?service=print\u0026continue=https://books.google.com.sg/books%3Fop%3Dlibrary\u0026hl=en","is_magazine":false,"is_public_domain":false,"last_page":{"pid":"PA290","order":298,"title":"290"}},{"enableUserFeedbackUI":true,"pseudocontinuous":true,"is_cobrand":false,"sign_in_url":"https://www.google.com/accounts/Login?service=print\u0026continue=https://books.google.com.sg/books%3Fid%3DUgNp8-wq-aAC%26q%3Dredox%26dq%3Dsubject:%2522Science%2BChemistry%2522%26source%3Dgbs_word_cloud_r%26hl%3Den\u0026hl=en","isEntityPageViewport":false,"showViewportOnboarding":false,"showViewportPlainTextOnboarding":false},{"page":[{"pid":"PA95","highlights":[{"X":184,"Y":196,"W":29,"H":11},{"X":179,"Y":391,"W":29,"H":11},{"X":180,"Y":564,"W":29,"H":11}],"flags":8,"order":103,"vq":"redox"}]},null,{"number_of_results":40,"search_results":[{"page_id":"PA17","page_number":"17","snippet_text":"... \u003cb\u003eredox\u003c/b\u003e - active TOAC ( 31 ) is necessary for efficient oxidation cataly- sis . Control experiments established that it is indeed the intact peptide ligand that renders the Cu - ion catalytically active . For example , simple mixtures of\u0026nbsp;...","page_url":"https://books.google.com.sg/books?id=UgNp8-wq-aAC\u0026pg=PA17\u0026vq=redox\u0026dq=subject:%22Science+Chemistry%22"},{"page_id":"PA29","page_number":"29","snippet_text":"... \u003cb\u003eredox\u003c/b\u003e enzymes D. Ligand design for biomimetic non - heme iron and manganese complexes III . Biomimetic iron catalysts A. Alkane hydroxylation B. cis - Dihydroxylation vs. olefin epoxidation C. Aromatic hydroxylation D. Role of additives\u0026nbsp;..."},{"page_id":"PA31","page_number":"31","snippet_text":"... \u003cb\u003eredox\u003c/b\u003e enzymes . The focus of this review is on complexes that are able to catalyze hydrocarbon oxidation reactions using dihydrogen peroxide as oxidant . A. INTRODUCTION II . Biological Enzymes and Catalytic Oxidation In nature\u0026nbsp;..."},{"page_id":"PA32","page_number":"32","snippet_text":"... \u003cb\u003eredox\u003c/b\u003e dismutation ( 176 ) Isopenicillin N synthase Isopenicillin N formation ( 177 ) Lipoxygenases Unsaturated fatty acid oxidation ( 178 ) Nitrile hydratase Nitrile to amide hydration ( 179 ) Rieske oxygenase Bleomycin Methane\u0026nbsp;..."},{"page_id":"PA34","page_number":"34","snippet_text":"... \u003cb\u003eREDOX\u003c/b\u003e ENZYMES Several enzymes are known, that naturally contain manganese in the active site and include classes as oxidoreductases, transferases, hydrolases, lyases, isomerases, ligases, lectins, and integrins (24). Some representative\u0026nbsp;..."},{"page_id":"PA35","page_number":"35","snippet_text":"... \u003cb\u003eREDOX\u003c/b\u003e ENZYMES INVOLVED IN OXIDATIVE CONVERSIONS Enzyme class Superoxide dismutase Mn catechol dioxygenase Mn catalase Oxygen evolving complex Mn lipoxygenase Function Ref . Superoxide decomposition ( 190 ) Catechol oxidation ( 191 )\u0026nbsp;..."},{"page_id":"PA40","page_number":"40","snippet_text":"... \u003cb\u003eredox\u003c/b\u003e cycle easily ( 46 ) . In fact , if not carried out in suitable organic solvents , the simple Fenton reaction will take place , involving Fell and dihydrogen peroxide , which is not very effective to carry out the oxidation of\u0026nbsp;..."},{"page_id":"PA60","page_number":"60","snippet_text":"... \u003cb\u003eredox\u003c/b\u003e. couples. (. 135. ) . The. oxidation. potentials. of. the complexes generally increase with a more electron - donating nature of the substituents ( 135 ) . The use of Mn - phox complexes with the more electron - donating ligands\u0026nbsp;..."},{"page_id":"PA70","page_number":"70","snippet_text":"... \u003cb\u003eredox\u003c/b\u003e enzymes . In : “ Metal Ions in Biological Systems ” ; vol . 37 , Marcel Dekker : New York , 2000 , p . 429 . 35. Yocum , C. F .; Pecoraro , V. L. Curr . Opin . Chem . Biol . 1999 , 3 , 182 . 36. Iwata , S .; Barber , J. Curr\u0026nbsp;..."},{"page_id":"PA77","page_number":"77","snippet_text":"... \u003cb\u003eRedox\u003c/b\u003e-active metal complexes have been known for decades to be able to mediate oxidative degradation of DNA. Because of the large literature on iron complexes, the most famous representatives of which are Fe-bleomycin and Fe-edta, this\u0026nbsp;..."},{"page_id":"PA79","page_number":"79","snippet_text":"... \u003cb\u003eredox\u003c/b\u003e events has been proposed for the generation of the active species (Fig. 3). The CuII complex is ¢rst reduced to the CuI complex [Eq. (3)], which reacts with dioxygen to produce superoxide anion [Eq. (4)]. The CuI complex reduced\u0026nbsp;..."},{"page_id":"PA87","page_number":"87","snippet_text":"... (40). Dizdaroglu et al . studied the oxidation of nucleobases of . FIG 8. Mechanism of C50 oxidation of DNA by activated Cu(phen) 2 . FIG . 11. \u003cb\u003eRedox\u003c/b\u003e events involved in the formation of. DNA OXIDATION BY COPPER AND MANGANESE COMPLEXES 87."},{"page_id":"PA89","page_number":"89","snippet_text":"... \u003cb\u003eredox\u003c/b\u003e active 2 : 1 complex due to steric clash between N 2 N N 3 N N -NH2 -NH2 N N 2 - Clip - Phen 3 - Clip - Phen FIG . 9. Structure of 2- and 3 - Clip - Phen . II the ortho methyl groups ( which inhibits \u003cb\u003eredox\u003c/b\u003e cycling. DNA OXIDATION BY\u0026nbsp;..."},{"page_id":"PA90","page_number":"90","snippet_text":"... \u003cb\u003eredox\u003c/b\u003e cycling through the square planar Cut complex ) ( 3,80 ) ; ( vi ) the new ligand must be as simple as possible and easy to prepare in large quantity if needed , so therefore must be symmetric . The first bridge tested was serinol\u0026nbsp;..."},{"page_id":"PA93","page_number":"93","snippet_text":"... \u003cb\u003eredox\u003c/b\u003e potential couples were generally observed between +0.2 and +0.8 V ( 125,126 ) . These values are easily accessible in biological condi- tions and allow , as summarized in Fig . 11 , Cu1 species , derived from the reduction of\u0026nbsp;..."},{"page_id":"PA94","page_number":"94","snippet_text":"... \u003cb\u003eredox\u003c/b\u003e events for the oxidation of. FIG . 11. \u003cb\u003eRedox\u003c/b\u003e events involved in the formation of di¡usible reactive oxygen species by CuII complexes in the presence of reductant and dioxygen. DNA radical formation by HOl. . FIG 14. Proposed\u0026nbsp;..."},{"page_id":"PA95","page_number":"95","snippet_text":"... \u003cb\u003eredox\u003c/b\u003e events for the oxidation of DNA deoxyribose by an \u0026#39;\u0026#39;encaged\u0026#39;\u0026#39; hydroxyl radical, a proposed non-di¡usible active species formed in the pre- sence of a CuI complex and H2O2 . . FIG 13. Proposed \u003cb\u003eredox\u003c/b\u003e events for the oxidation of DNA\u0026nbsp;..."},{"page_id":"PA96","page_number":"96","snippet_text":"... \u003cb\u003eredox\u003c/b\u003e events for the oxidation of DNA deoxyribose by a CuIII-oxo non-di¡usible active species formed in the presence of a CuI complex and H2O2 . . FIG 16. Proposed \u003cb\u003eredox\u003c/b\u003e events for the oxidation of DNA deoxyribose by a CuII- hydroperoxo\u0026nbsp;..."},{"page_id":"PA97","page_number":"97","snippet_text":"... \u003cb\u003eredox\u003c/b\u003e events involving non - diffusible active species for the oxida- tion of DNA deoxyribose by a dinuclear Cut complex in the presence of dioxygen . ( a ) The \u0026quot; Cu - O - O - CuII \u0026quot; pathway . ( b ) Initiation of the \u0026quot; Cu - hydroperoxo\u0026nbsp;..."},{"page_id":"PA99","page_number":"99","snippet_text":"... \u003cb\u003eredox\u003c/b\u003e active Cu1 complexes unable to oxidize DNA . III . Oxidative DNA Damage by Manganese Complexes The few examples of manganese complexes able to damage DNA by oxida- tive processes came from the intensive work on metal complexes\u0026nbsp;..."},{"page_id":"PA111","page_number":"111","snippet_text":"... \u003cb\u003eredox\u003c/b\u003e potential of the guanine base of guanosine was measured at 1.29 V vs. NHE and is significantly lower ( 0.5V ) than that of the nearest nucleoside , adenosine ( 214 ) . However , depending on the DNA sequence , the guanine bases\u0026nbsp;..."},{"page_id":"PA122","page_number":"122","snippet_text":"... oxidative species that are two \u003cb\u003eredox\u003c/b\u003e equivalents above the initial state of the complex . These activated complexes are powerful oxidants not only in terms of electron transfer , but also in oxygen transfer reactions. 122 M. PITIÉ et al ."},{"page_id":"PA136","page_number":"136","snippet_text":"... \u003cb\u003eredox\u003c/b\u003e properties , and their consequences on O2 reactivity including thermodynamic , kinetic , and bonding properties of derived copper - dioxygen adducts ( 19 ) . Inorganic model studies have shown that several different O2 binding\u0026nbsp;..."},{"page_id":"PA142","page_number":"142","snippet_text":"... \u003cb\u003eredox\u003c/b\u003e potential of the copper(I) and copper(II) (60) complexes increase as the ligand increases in arm length. This e¡ect is understood as arising from the relative stability (i.e., formation constants) of the Cu(II) ions for a 5\u0026nbsp;..."},{"page_id":"PA143","page_number":"143","snippet_text":"... \u003cb\u003eredox\u003c/b\u003e potential and ligand chelate ring size of derived copper(I) complexes (Fig. 10). B. ELECTRONIC EFFECTS IN TETRADENTATE LIGAND SYSTEMS More recently, we modi¢ed the TMPA ligand in terms of its electronic donating ability to the\u0026nbsp;..."},{"page_id":"PA162","page_number":"162","snippet_text":"... \u003cb\u003eredox\u003c/b\u003e properties, and steric accessibility, all a¡ect the oxidative capability of the activated copper-O 2 complex. Here, we ¢rst highlight some initial observations from our group demonstrating reactivity di¡erences from end-on, and\u0026nbsp;..."},{"page_id":"PA176","page_number":"176","snippet_text":"... \u003cb\u003eredox\u003c/b\u003e potentials of each [{Cu(R-MePY2)} 2 ]2 þ oxidant, seeking an understanding of the preferential ETPT and ET/PT pathways from a thermodynamic perspective. In CH2 O2 Cl2 , [{Cu(H-MePY2)} the low temperature (^808C) cyclic 2O2 ]2þ and\u0026nbsp;..."},{"page_id":"PA178","page_number":"178","snippet_text":"... \u003cb\u003eredox\u003c/b\u003e potentials of the oxidant and / or the substrate involved . Finally , as substrate binding appears to be a key step in the oxidation reaction , it is probably more correct to say that ET oxidations by [ { Cu ( R - MePY2 ) } 2O2 ]\u0026nbsp;..."},{"page_id":"PA186","page_number":"186","snippet_text":"... \u003cb\u003eredox\u003c/b\u003e organic cofactors , resulting from posttranslational modifications of endogenous amino acids ( 7 ) , as in galactose oxidase ( 8 ) and amine oxidase ( 2,9 ) , or additional distant copper centers , as in dopamine ẞ - hydroxylase\u0026nbsp;..."},{"page_id":"PA192","page_number":"192","snippet_text":"... spectroscopic properties in the +2 \u003cb\u003eredox\u003c/b\u003e state as type 1 (or blue) Cu,. SCHEME 2. The catecholase catalytic cycle of tyrosinase (adapted from (44)). FIG. 3. Structure of the active site of multicopper oxidases. 192 G. BATTAINI et al."},{"page_id":"PA193","page_number":"193","snippet_text":"... \u003cb\u003eredox\u003c/b\u003e active Cu centers need to store reducing equivalents coming from four substrate molecules and transfer the electrons to dioxygen. From spectroscopic studies and fast kinetic experiments carried out on laccase it has been shown\u0026nbsp;..."},{"page_id":"PA198","page_number":"198","snippet_text":"... \u003cb\u003eredox\u003c/b\u003e properties of the copper centers and this is, inter alia, an important parameter to take into account when the properties of the biomimetic complexes are consid- ered. For instance, aliphatic amine ligands are strong s-donors and\u0026nbsp;..."},{"page_id":"PA220","page_number":"220","snippet_text":"... \u003cb\u003eredox\u003c/b\u003e potential of the two partners and the overlap between the orbitals involved, while the activation entropy, AS61⁄4 1⁄4 73(6) J mol 1 K 1 shows a negative value. The analysis of the activa- tion parameters for the second step, AH61\u0026nbsp;..."},{"page_id":"PA236","page_number":"236","snippet_text":"... \u003cb\u003eredox\u003c/b\u003e - catalysts that could be used for the green and selective oxidation of alcohols . Copper - containing oxidases can be divided into enzymes with mono- nuclear copper - sites , dinuclear copper - sites , and enzymes with\u0026nbsp;..."},{"page_id":"PA243","page_number":"243","snippet_text":"... \u003cb\u003eredox\u003c/b\u003e potential of ca. 0.8 V vs. NHE . Consequently , fungal laccases can easily oxidize TEMPO to the corresponding oxoammonium cation , since the oxidation potential of the latter , which was first measured by Golubev and co - workers\u0026nbsp;..."},{"page_id":"PA244","page_number":"244","snippet_text":"... \u003cb\u003eredox\u003c/b\u003e metal ion , one of the phenol ligands is most likely involved in the oxidative transformation . Indeed , in the active form of the biocatalyst , the equatorial plane is formed by two nitrogen atoms from two histidine imidazoles\u0026nbsp;..."},{"page_id":"PA284","page_number":"284","snippet_text":"... \u003cb\u003eRedox\u003c/b\u003e cycling 90 Reductants 80 , 98 , 176 NADH ( 2 - electron reductants ) 80 superoxide anion and thiol ( 1 - electron reductant ) 80 used for the activation of Cu II 80 Regioselectivity 42 , 67 Retention of configuration ( RC ) 42\u0026nbsp;...","page_url":"https://books.google.com.sg/books?id=UgNp8-wq-aAC\u0026pg=PA284\u0026vq=redox\u0026dq=subject:%22Science+Chemistry%22"},{"page_id":"PA286","page_number":"286","snippet_text":"... \u003cb\u003eRedox\u003c/b\u003e Enzymes and Model Systems : Properties , Structures , and Reactivity VOLUME 48 Cumulative Index for Volumes 1^47 VOLUME 49 Inorganic. Neil A. Law , M. Tyler Caudle , and Vincent L. Pecoraro Calcium - Binding Proteins Bryan E. Finn\u0026nbsp;...","page_url":"https://books.google.com.sg/books?id=UgNp8-wq-aAC\u0026pg=PA286\u0026vq=redox\u0026dq=subject:%22Science+Chemistry%22"},{"page_id":"PA288","page_number":"288","snippet_text":"... \u003cb\u003eRedox\u003c/b\u003e Chemistry and Functionalities of Conjugated Ferrocene Systems Hiroshi Nishihara New Aspects of Metal - Nucleobase Chemistry Andrew Houlton INDEX VOLUME 55 Dioxygen Activation by Transition Metal Complexes . Atom Transfer and Free\u0026nbsp;..."},{"page_id":"PA289","page_number":"289","snippet_text":"Homogeneous Biomimetic Oxidation Catalysis Rudi van Eldik, Jan Reedijk. \u003cb\u003eRedox\u003c/b\u003e Reactivity of Coordinated Ligands in Pentacyano ( L ) Ferrate Complexes José A. Olabe Carbonato Complexes : Models for Carbonic Anhydrase Achyuta N. Acharya\u0026nbsp;..."}],"search_query_escaped":"redox"},{});</script></div></div></div><script>(function() {var href = window.location.href;if (href.indexOf('?') !== -1) {var parameters = href.split('?')[1].split('&');for (var i = 0; i < parameters.length; i++) {var param = parameters[i].split('=');if (param[0] == 'focus') {var elem = document.getElementById(param[1]);if (elem) {elem.focus();}}}}})();</script>