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functionalized</title> <meta name="description" content="Search results for: functionalized"> <meta name="keywords" content="functionalized"> <meta name="viewport" content="width=device-width, initial-scale=1, minimum-scale=1, maximum-scale=1, user-scalable=no"> <meta charset="utf-8"> <link href="https://cdn.waset.org/favicon.ico" type="image/x-icon" rel="shortcut icon"> <link href="https://cdn.waset.org/static/plugins/bootstrap-4.2.1/css/bootstrap.min.css" rel="stylesheet"> <link href="https://cdn.waset.org/static/plugins/fontawesome/css/all.min.css" rel="stylesheet"> <link href="https://cdn.waset.org/static/css/site.css?v=150220211555" rel="stylesheet"> </head> <body> <header> <div class="container"> <nav class="navbar navbar-expand-lg navbar-light"> <a class="navbar-brand" href="https://waset.org"> <img src="https://cdn.waset.org/static/images/wasetc.png" alt="Open Science Research Excellence" title="Open Science Research Excellence" /> </a> <button class="d-block d-lg-none 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action="https://publications.waset.org/abstracts/search"> <div id="custom-search-input"> <div class="input-group"> <i class="fas fa-search"></i> <input type="text" class="search-query" name="q" placeholder="Author, Title, Abstract, Keywords" value="functionalized"> <input type="submit" class="btn_search" value="Search"> </div> </div> </form> </div> </div> <div class="row mt-3"> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Commenced</strong> in January 2007</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Frequency:</strong> Monthly</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Edition:</strong> International</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Paper Count:</strong> 283</div> </div> </div> </div> <h1 class="mt-3 mb-3 text-center" style="font-size:1.6rem;">Search results for: functionalized</h1> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">283</span> Nitrite Sensor Platform Functionalized Reduced Graphene Oxide with Thionine Dye Based</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Nurulasma%20Zainudin">Nurulasma Zainudin</a>, <a href="https://publications.waset.org/abstracts/search?q=Mashitah%20Mohd%20Yusoff"> Mashitah Mohd Yusoff</a>, <a href="https://publications.waset.org/abstracts/search?q=Kwok%20Feng%20Chong"> Kwok Feng Chong</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Functionalized reduced graphene oxide is essential importance for their end applications. Chemical functionalization of reduced graphene oxide with strange atoms is a leading strategy to modify the properties of the materials moreover maintains the inherent properties of reduced graphene oxide. A thionine functionalized reduce graphene oxide electrode was fabricated and was used to electrochemically determine nitrite. The electrochemical behaviour of thionine functionalized reduced graphene oxide towards oxidation of nitrite via cyclic voltammetry was studied and the proposed method exhibited enhanced electrocatalytic behaviour. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=nitrite" title="nitrite">nitrite</a>, <a href="https://publications.waset.org/abstracts/search?q=sensor" title=" sensor"> sensor</a>, <a href="https://publications.waset.org/abstracts/search?q=thionine" title=" thionine"> thionine</a>, <a href="https://publications.waset.org/abstracts/search?q=reduced%20graphene%20oxide" title=" reduced graphene oxide"> reduced graphene oxide</a> </p> <a href="https://publications.waset.org/abstracts/37261/nitrite-sensor-platform-functionalized-reduced-graphene-oxide-with-thionine-dye-based" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/37261.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">444</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">282</span> Effect of Amine-Functionalized Carbon Nanotubes on the Properties of CNT-PAN Composite Nanofibers</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=O.%20Eren">O. Eren</a>, <a href="https://publications.waset.org/abstracts/search?q=N.%20Ucar"> N. Ucar</a>, <a href="https://publications.waset.org/abstracts/search?q=A.%20Onen"> A. Onen</a>, <a href="https://publications.waset.org/abstracts/search?q=N.%20K%C4%B1z%C4%B1ldag"> N. Kızıldag</a>, <a href="https://publications.waset.org/abstracts/search?q=O.%20F.%20Vurur"> O. F. Vurur</a>, <a href="https://publications.waset.org/abstracts/search?q=N.%20Demirsoy"> N. Demirsoy</a>, <a href="https://publications.waset.org/abstracts/search?q=I.%20Karacan"> I. Karacan </a> </p> <p class="card-text"><strong>Abstract:</strong></p> PAN nanofibers reinforced with amine functionalized carbon nanotubes. The effect of amine functionalization and the effect of concentration of CNT on the conductivity and mechanical and morphological properties of composite nanofibers were examined. 1%CNT-NH2 loaded PAN/CNT nanofiber showed the best mechanical properties. Conductivity increased with the incorporation of carbon nanotubes. While an increase of the concentration of CNT increases the diameter of nanofiber, the use of functionalized CNT results to a decrease of diameter of nanofiber. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=amine%20functionalized%20carbon%20nanotube" title="amine functionalized carbon nanotube">amine functionalized carbon nanotube</a>, <a href="https://publications.waset.org/abstracts/search?q=electrospinning" title=" electrospinning"> electrospinning</a>, <a href="https://publications.waset.org/abstracts/search?q=nanofiber" title=" nanofiber"> nanofiber</a>, <a href="https://publications.waset.org/abstracts/search?q=polyacrylonitrile" title=" polyacrylonitrile"> polyacrylonitrile</a> </p> <a href="https://publications.waset.org/abstracts/7723/effect-of-amine-functionalized-carbon-nanotubes-on-the-properties-of-cnt-pan-composite-nanofibers" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/7723.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">309</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">281</span> Ultradrawing and Ultimate Tensile Properties of Ultrahigh Molecular Weight Polyethylene Composite Fibers Filled with Activated Nanocarbon Particles with Varying Specific Surface Areas</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Wang-Xi%20Fan">Wang-Xi Fan</a>, <a href="https://publications.waset.org/abstracts/search?q=Yi%20Ding"> Yi Ding</a>, <a href="https://publications.waset.org/abstracts/search?q=Zhong-Dan%20Tu"> Zhong-Dan Tu</a>, <a href="https://publications.waset.org/abstracts/search?q=Kuo-Shien%20Huang"> Kuo-Shien Huang</a>, <a href="https://publications.waset.org/abstracts/search?q=Chao-Ming%20Huang"> Chao-Ming Huang</a>, <a href="https://publications.waset.org/abstracts/search?q=Jen-Taut%20%20Yeh"> Jen-Taut Yeh</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Original and/or functionalized activated nanocarbon particles with a quoted specific surface area of 100, 500, 1000 and 1400 m2/g, respectively, were used to investigate the influence of specific surface areas of activated nanocarbon on ultra drawing and ultimate tensile properties of ultrahigh molecular weight polyethylene (UHMWPE), UHMWPE/activated nanocarbon and UHMWPE/ functionalized activated nanocarbon fibers. The specific surface areas of well dispersed functionalized activated nanocarbon in UHMWPE/functionalized activated nanocarbon fibers can positively affect their ultra drawing, orientation, ultimate tensile properties and “micro-fibril” characteristics. Excellent orientation and ultimate tensile properties of UHMWPE/nanofiller fibers can be prepared by ultra drawing the UHMWPE/functionalized activated nanocarbon as-prepared fibers with optimal contents and compositions of functionalized activated nanocarbon. The ultimate tensile strength value of the best prepared UHMWPE/functionalized activated nanocarbon drawn fiber reached 8.0 GPa, which was about 2.86 times of that of the best-prepared UHMWPE drawn fiber prepared in this study. Specific surface area, morphological and Fourier transform infrared analyses of original and functionalized activated nanocarbon and/or investigations of thermal, orientation factor and ultimate tensile properties of as-prepared and/or drawn UHMWPE/functionalized activated nanocarbon fibers were performed to understand the above-improved ultra drawing and ultimate tensile properties of the UHMWPE/functionalized activated nanocarbon fibers. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=activated%20nanocarbon" title="activated nanocarbon">activated nanocarbon</a>, <a href="https://publications.waset.org/abstracts/search?q=specific%20surface%20areas" title=" specific surface areas"> specific surface areas</a>, <a href="https://publications.waset.org/abstracts/search?q=ultradrawing" title=" ultradrawing"> ultradrawing</a>, <a href="https://publications.waset.org/abstracts/search?q=ultrahigh%20molecular%20weight%20polyethylene" title=" ultrahigh molecular weight polyethylene"> ultrahigh molecular weight polyethylene</a> </p> <a href="https://publications.waset.org/abstracts/56276/ultradrawing-and-ultimate-tensile-properties-of-ultrahigh-molecular-weight-polyethylene-composite-fibers-filled-with-activated-nanocarbon-particles-with-varying-specific-surface-areas" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/56276.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">372</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">280</span> Functionalized Nanoparticles for Biomedical Applications</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Temesgen%20Geremew">Temesgen Geremew</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Functionalized nanoparticles have emerged as a revolutionary class of materials with immense potential in various biomedical applications. These engineered nanoparticles possess unique properties tailored to interact with biological systems, offering unprecedented opportunities in drug delivery, imaging, diagnostics, and therapy. This research delves into the design, synthesis, and characterization of functionalized nanoparticles for targeted biomedical applications. The primary focus lies on developing nanoparticles with precisely controlled size, surface chemistry, and biocompatibility for specific medical purposes. The research will also explore the crucial interaction of these nanoparticles with biological systems, encompassing cellular uptake, biodistribution, and potential toxicity evaluation. The successful development of functionalized nanoparticles holds the promise to revolutionize various aspects of healthcare. This research aspires to contribute significantly to this advancement by providing valuable insights into the design and application of these versatile materials within the ever-evolving field of biomedicine. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=nanoparticles" title="nanoparticles">nanoparticles</a>, <a href="https://publications.waset.org/abstracts/search?q=biomedicals" title=" biomedicals"> biomedicals</a>, <a href="https://publications.waset.org/abstracts/search?q=cancer" title=" cancer"> cancer</a>, <a href="https://publications.waset.org/abstracts/search?q=biocompatibility" title=" biocompatibility"> biocompatibility</a> </p> <a href="https://publications.waset.org/abstracts/183266/functionalized-nanoparticles-for-biomedical-applications" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/183266.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">66</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">279</span> Chitosan Functionalized Fe3O4@Au Core-Shell Nanomaterials for Targeted Drug Delivery</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=S.%20S.%20Pati">S. S. Pati</a>, <a href="https://publications.waset.org/abstracts/search?q=L.%20Herojit%20Singh"> L. Herojit Singh</a>, <a href="https://publications.waset.org/abstracts/search?q=A.%20C.%20Oliveira"> A. C. Oliveira</a>, <a href="https://publications.waset.org/abstracts/search?q=V.%20K.%20Garg"> V. K. Garg</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Chitosan functionalized Fe3O4-Au core shell nanoparticles have been prepared using a two step wet chemical approach using NaBH4 as reducing agent for formation of Au inethylene glycol. X-ray diffraction studies shows individual phases of Fe3O4 and Au in the as prepared samples with crystallite size of 5.9 and 11.4 nm respectively. The functionalization of the core-shell nanostructure with Chitosan has been confirmed using Fourier transform infrared spectroscopy along with signatures of octahedral and tetrahedral sites of Fe3O4 below 600cm-1. Mössbauer spectroscopy shows decrease in particle-particle interaction in presence of Au shell (72% sextet) than pure oleic coated Fe3O4 nanoparticles (88% sextet) at room temperature. At 80K, oleic acid coated Fe3O4 shows only sextets whereas the Chitosan functionalized Fe3O4 and Chitosan functionalized Fe3O4@Au core shell show presence of 5 and 11% doublet, respectively. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=core%20shell" title="core shell">core shell</a>, <a href="https://publications.waset.org/abstracts/search?q=drug%20delivery" title=" drug delivery"> drug delivery</a>, <a href="https://publications.waset.org/abstracts/search?q=gold%20nanoparticles" title=" gold nanoparticles"> gold nanoparticles</a>, <a href="https://publications.waset.org/abstracts/search?q=magnetic%20nanoparticles" title=" magnetic nanoparticles"> magnetic nanoparticles</a> </p> <a href="https://publications.waset.org/abstracts/28882/chitosan-functionalized-fe3o4-at-au-core-shell-nanomaterials-for-targeted-drug-delivery" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/28882.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">375</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">278</span> Preparation of Superparamagnetic Functionalized Magnetite Nanoparticles for Magnetically Separable Catalysis </h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Priya%20Arora">Priya Arora</a>, <a href="https://publications.waset.org/abstracts/search?q=Jaspreet%20K.%20Rajput"> Jaspreet K. Rajput</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Superparamagnetism has accelerated the research and use of more economical and ecological magnetically separable catalysts due to their more efficient isolation by response to an applied magnetic field. Magnetite nanomaterials coated by SiO2 shell have received a great deal of focus in the last decades as it provides high stability and also easy further surface functionalization depending upon the application. In this protocol, Fe3O4 magnetic nanoparticles have been synthesized by co-precipitation combined with sonication method. Further, Fe3O4 superparamagnetic nanoparticles have been functionalized by various moieties to serve as efficient catalysts for multicomponent reactions. The functionalized nanoparticles were characterized by techniques like Fourier transform infrared spectroscopy (FT-IR), transmission electron microscopy (TEM), scanning electron microscopy (SEM), vibrating sample magnetometer (VSM), thermogravimetric analysis (TGA), Brunauer-Emmett-Teller (BET) surface area analysis. The as prepared nanocatalysts can be reused for several times without any significant loss in its activity. The utilization of magnetic nanoparticles as catalysts for this reaction is one approach i.e. green, inexpensive, facile and widely applicable. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=functionalized" title="functionalized">functionalized</a>, <a href="https://publications.waset.org/abstracts/search?q=magnetite" title=" magnetite"> magnetite</a>, <a href="https://publications.waset.org/abstracts/search?q=multicomponent%20reactions" title=" multicomponent reactions"> multicomponent reactions</a>, <a href="https://publications.waset.org/abstracts/search?q=superparamagnetic" title=" superparamagnetic"> superparamagnetic</a> </p> <a href="https://publications.waset.org/abstracts/55353/preparation-of-superparamagnetic-functionalized-magnetite-nanoparticles-for-magnetically-separable-catalysis" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/55353.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">340</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">277</span> Functionalized Nanoparticles for Drug Delivery Applications</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Temesgen%20Geremew">Temesgen Geremew</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Functionalized nanoparticles have emerged as a revolutionary platform for drug delivery, offering significant advantages over traditional methods. By strategically modifying their surface properties, these nanoparticles can be designed to target specific tissues and cells, significantly reducing off-target effects and enhancing therapeutic efficacy. This targeted approach allows for lower drug doses, minimizing systemic exposure and potential side effects. Additionally, functionalization enables controlled release of the encapsulated drug, improving drug stability and reducing the frequency of administration, leading to improved patient compliance. This work explores the immense potential of functionalized nanoparticles in revolutionizing drug delivery, addressing limitations associated with conventional therapies and paving the way for personalized medicine with precise and targeted treatment strategies. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=nanoparticles" title="nanoparticles">nanoparticles</a>, <a href="https://publications.waset.org/abstracts/search?q=drug" title=" drug"> drug</a>, <a href="https://publications.waset.org/abstracts/search?q=nanomaterials" title=" nanomaterials"> nanomaterials</a>, <a href="https://publications.waset.org/abstracts/search?q=applications" title=" applications"> applications</a> </p> <a href="https://publications.waset.org/abstracts/183288/functionalized-nanoparticles-for-drug-delivery-applications" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/183288.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">68</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">276</span> Functionalization of Single-Walled Nanotubes by Synthesied Pigments</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Shahab%20Zomorodbakhsh">Shahab Zomorodbakhsh</a>, <a href="https://publications.waset.org/abstracts/search?q=Hayron%20Nesa%20Motevasel"> Hayron Nesa Motevasel</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Water soluble compoundes were attached to single-walled carbon nanotubes (SWNTs) to form water-soluble nano pigments. functionalized SWNTs were then characterized by Fourier Transform Infrared spectroscopy (FT-IR), Raman spectroscopy, UV analysis, Transmission electron microscopy (TEM)and defunctionalization test and Representative results concerning the solubility. The product can be dissolved in water and High-resolution transmission electron microscope images showed that the SWNTs were efficiently functionalized, thus the p-stacking interaction between aromatic rings and COOH of SWNTs was considered responsible for the high solubility and High transmission electron in singlewall nanotubes. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=functionalized%20CNTs" title="functionalized CNTs">functionalized CNTs</a>, <a href="https://publications.waset.org/abstracts/search?q=singlewalled%20carbon%20nanotubes" title=" singlewalled carbon nanotubes"> singlewalled carbon nanotubes</a>, <a href="https://publications.waset.org/abstracts/search?q=water%20soluble%20compoundes" title=" water soluble compoundes"> water soluble compoundes</a>, <a href="https://publications.waset.org/abstracts/search?q=nano%20pigments" title=" nano pigments"> nano pigments</a> </p> <a href="https://publications.waset.org/abstracts/22309/functionalization-of-single-walled-nanotubes-by-synthesied-pigments" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/22309.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">320</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">275</span> Functionalized PU Foam for Water Filtration</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Nidal%20H.%20Abu-Zahra">Nidal H. Abu-Zahra</a>, <a href="https://publications.waset.org/abstracts/search?q=Subhashini%20Gunashekar"> Subhashini Gunashekar</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Polyurethane foam is functionalized with Sulfonic acid groups to remove lead ions (Pb2+) from drinking water through a action exchange process. The synthesis is based on addition polymerization of the -NCO groups of an isocyanine with the –OH groups of a polio to form the urethane. Toluene-diisocyanateis reacted with Polypropylene glycol to form a linear pre-polymer, which is further polymerized using a chain extender, N, N-bis(2-hydorxyethyl)-2-aminoethane-sulfonic acid (BES). BES acts as a functional group site to exchange Pb2+ ions. A set of experiments was designed to study the effect of various processing parameters on the performance of the synthesized foam. The maximum Pb2+ ion exchange capacity of the foam was found to be 47ppb/g from a 100ppb Pb2+ solution over a period of 60 minutes. A multistage batch filtration process increased the lead removal to 50-54ppb/3g of foam over a period of 90 minutes. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=adsorption" title="adsorption">adsorption</a>, <a href="https://publications.waset.org/abstracts/search?q=functionalized" title=" functionalized"> functionalized</a>, <a href="https://publications.waset.org/abstracts/search?q=ion%20exchange" title=" ion exchange"> ion exchange</a>, <a href="https://publications.waset.org/abstracts/search?q=polyurethane" title=" polyurethane"> polyurethane</a>, <a href="https://publications.waset.org/abstracts/search?q=sulfonic" title=" sulfonic"> sulfonic</a> </p> <a href="https://publications.waset.org/abstracts/3776/functionalized-pu-foam-for-water-filtration" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/3776.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">244</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">274</span> Removal of Nickel and Zinc Ions from Aqueous Solution by Graphene Oxide and Graphene Oxide Functionalized Glycine</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=M.%20Rajabi">M. Rajabi</a>, <a href="https://publications.waset.org/abstracts/search?q=O.%20Moradi"> O. Moradi</a> </p> <p class="card-text"><strong>Abstract:</strong></p> In this study, removal of Nickel and Zinc by graphene oxide and functionalized graphene oxide–gelaycin surfaces was examined. Amino group was added to surface of graphene oxide to produced functionalized graphene oxide–gelaycin. Effect of contact time and initial concentration of Ni (II) and Zn(II) ions were studied. Results showed that with increase of initial concentration of Ni (II) and Zn(II) adsorption capacity was increased. After 50 min has not a large change at adsorption capacity therefore, 50 min was selected as optimaze time. Scanning electron microscope (SEM) and fourier transform infrared (FT-IR) spectroscopy spectra used for the analysis confirmed the successful fictionalization of the Graphene oxide surface. Adsorption experiments of Ni (II) and Zn(II) ions graphene oxide and functionalized graphene oxide–gelaycin surfaces fixed at 298 K and pH=6. The Pseudo Firs-order and the Pseudo Second-order (types I, II, III and IV) kinetic models were tested for adsorption process and results showed that the kinetic parameters best fits with to type (I) of pseudo-second-order model because presented low X2 values and also high R2 values. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=graphene%20oxide" title="graphene oxide">graphene oxide</a>, <a href="https://publications.waset.org/abstracts/search?q=gelaycin" title=" gelaycin"> gelaycin</a>, <a href="https://publications.waset.org/abstracts/search?q=nickel" title=" nickel"> nickel</a>, <a href="https://publications.waset.org/abstracts/search?q=zinc" title=" zinc"> zinc</a>, <a href="https://publications.waset.org/abstracts/search?q=adsorption" title=" adsorption"> adsorption</a>, <a href="https://publications.waset.org/abstracts/search?q=kinetic" title=" kinetic"> kinetic</a>, <a href="https://publications.waset.org/abstracts/search?q=graphene%20oxide" title=" graphene oxide"> graphene oxide</a>, <a href="https://publications.waset.org/abstracts/search?q=gelaycin" title=" gelaycin"> gelaycin</a>, <a href="https://publications.waset.org/abstracts/search?q=nickel" title=" nickel"> nickel</a>, <a href="https://publications.waset.org/abstracts/search?q=zinc" title=" zinc"> zinc</a>, <a href="https://publications.waset.org/abstracts/search?q=adsorption" title=" adsorption"> adsorption</a>, <a href="https://publications.waset.org/abstracts/search?q=kinetic" title=" kinetic"> kinetic</a> </p> <a href="https://publications.waset.org/abstracts/39809/removal-of-nickel-and-zinc-ions-from-aqueous-solution-by-graphene-oxide-and-graphene-oxide-functionalized-glycine" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/39809.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">308</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">273</span> Functionalized Single Walled Carbon Nanotubes: Targeting, Cellular Uptake, and Applications in Photodynamic Therapy</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Prabhavathi%20Sundaram">Prabhavathi Sundaram</a>, <a href="https://publications.waset.org/abstracts/search?q=Heidi%20Abrahamse"> Heidi Abrahamse</a> </p> <p class="card-text"><strong>Abstract:</strong></p> In recent years, nanotechnology coupled with photodynamic therapy (PDT) has received considerable attention in terms of improving the effectiveness of drug delivery in cancer therapeutics. The development of functionalized single-walled carbon nanotubes (SWCNTs) has become revolutionary in targeted photosensitizers delivery since it improves the therapeutic index of drugs. The objective of this study was to prepare, characterize and evaluate the potential of functionalized SWCNTs using hyaluronic acid and loading it with photosensitizer and to effectively target colon cancer cells. The single-walled carbon nanotubes were covalently functionalized with hyaluronic acid and the loaded photosensitizer by non-covalent interaction. The photodynamic effect of SWCNTs is detected under laser irradiation in vitro. The hyaluronic acid-functionalized nanocomposites had a good affinity with CD44 receptors, and it avidly binds on to the surface of CACO-2 cells. The cellular uptake of nanocomposites was studied using fluorescence microscopy using lyso tracker. The anticancer activity of nanocomposites was analyzed in CACO-2 cells using different studies such as cell morphology, cell apoptosis, and nuclear morphology. The combined effect of nanocomposites and PDT improved the therapeutic effect of cancer treatment. The study suggested that the nanocomposites and PDT have great potential in the treatment of colon cancer. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=colon%20cancer" title="colon cancer">colon cancer</a>, <a href="https://publications.waset.org/abstracts/search?q=hyaluronic%20acid" title=" hyaluronic acid"> hyaluronic acid</a>, <a href="https://publications.waset.org/abstracts/search?q=single%20walled%20carbon%20nanotubes" title=" single walled carbon nanotubes"> single walled carbon nanotubes</a>, <a href="https://publications.waset.org/abstracts/search?q=photosensitizers" title=" photosensitizers"> photosensitizers</a>, <a href="https://publications.waset.org/abstracts/search?q=photodynamic%20therapy" title=" photodynamic therapy"> photodynamic therapy</a> </p> <a href="https://publications.waset.org/abstracts/112208/functionalized-single-walled-carbon-nanotubes-targeting-cellular-uptake-and-applications-in-photodynamic-therapy" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/112208.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">116</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">272</span> Synthesis, Characterization of Pd Nanoparticle Supported on Amine-Functionalized Graphene and Its Catalytic Activity for Suzuki Coupling Reaction</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Surjyakanta%20Rana">Surjyakanta Rana</a>, <a href="https://publications.waset.org/abstracts/search?q=Sreekantha%20B.%20Jonnalagadda"> Sreekantha B. Jonnalagadda</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Synthesis of well distributed Pd nanoparticles (3 – 7 nm) on organo amine-functionalized graphene is reported, which demonstrated excellent catalytic activity towards Suzuki coupling reaction. The active material was characterized by X-ray diffraction (XRD), BET surface area, X-ray photoelectron spectra (XPS), Fourier-transfer infrared spectroscopy (FTIR), Raman spectra, Scanning electron microscope (SEM), Transmittance electron microscopy (TEM) analysis and HRTEM. FT-IR revealed that the organic amine functional group was successfully grafted onto the graphene oxide surface. The formation of palladium nanoparticles was confirmed by XPS, TEM and HRTEM techniques. The catalytic activity in the coupling reaction was superb with 100% conversion and 98 % yield and also activity remained almost unaltered up to six cycles. Typically, an extremely high turnover frequency of 185,078 h-1 is observed in the C-C Suzuki coupling reaction using organo di-amine functionalized graphene as catalyst. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=Di-amine" title="Di-amine">Di-amine</a>, <a href="https://publications.waset.org/abstracts/search?q=graphene" title=" graphene"> graphene</a>, <a href="https://publications.waset.org/abstracts/search?q=Pd%20nanoparticle" title=" Pd nanoparticle"> Pd nanoparticle</a>, <a href="https://publications.waset.org/abstracts/search?q=suzuki%20coupling" title=" suzuki coupling"> suzuki coupling</a> </p> <a href="https://publications.waset.org/abstracts/31977/synthesis-characterization-of-pd-nanoparticle-supported-on-amine-functionalized-graphene-and-its-catalytic-activity-for-suzuki-coupling-reaction" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/31977.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">375</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">271</span> Preparation and Characterization of AlkylAmines’ Surface Functionalized Activated Carbons for Dye Removal</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Said%20M.%20AL-Mashaikhi">Said M. AL-Mashaikhi</a>, <a href="https://publications.waset.org/abstracts/search?q=El-Said%20I.%20El-Shafey"> El-Said I. El-Shafey</a>, <a href="https://publications.waset.org/abstracts/search?q=Fakhreldin%20O.%20Suliman"> Fakhreldin O. Suliman</a>, <a href="https://publications.waset.org/abstracts/search?q=Saleh%20Al-Busafi"> Saleh Al-Busafi</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Activated carbon (AC) was prepared from date palm leaflets via NaOH activation. AC was oxidized using nitric acid, producing oxidized activated carbon (OAC). OAC was surface functionalized using different amine surfactants, including methylamine (ONM), ethylamine (ONE), and diethylamine (ONDE) using the amide coupling process. Produced carbons were surface characterized for surface area and porosity, X-ray diffraction, SEM, FTIR, and TGA. AC surface area (580 m²/g) has shown a decrease in oxidation to 260 m²/g for OAC. On amine functionalization, the surface area has further decreased to 218, 108, and 20 m²/g on functionalization with methylamine, ethylamine, and diethylamine, respectively. FTIR and TGA showed that the nature of amine functionalization of AC is chemical. Methylene blue sorption was tested on these carbons in terms of kinetics and equilibrium. Sorption was found faster on amine-functionalized carbons than both AC and OAC, and this is due to hydrophobic interaction with the alkyl groups immobilized with data following pseudo second-order reaction. On the other hand, AC showed the slowest adsorption kinetic process due to the diffusion in the porous structure of AC. Sorption equilibrium data was found to follow the Langmuir sorption isotherm with maximum sorption found on ONE. Regardless of its lower surface area than activated carbon, ethylamine functionalized AC showed better performance than AC in terms of kinetics and equilibrium for dye removal. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=activated%20carbon" title="activated carbon">activated carbon</a>, <a href="https://publications.waset.org/abstracts/search?q=dye%20removal" title=" dye removal"> dye removal</a>, <a href="https://publications.waset.org/abstracts/search?q=functionalization" title=" functionalization"> functionalization</a>, <a href="https://publications.waset.org/abstracts/search?q=hydrophobic%20interaction" title=" hydrophobic interaction"> hydrophobic interaction</a>, <a href="https://publications.waset.org/abstracts/search?q=water%20treatment" title=" water treatment"> water treatment</a> </p> <a href="https://publications.waset.org/abstracts/136863/preparation-and-characterization-of-alkylamines-surface-functionalized-activated-carbons-for-dye-removal" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/136863.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">166</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">270</span> Solubility of Carbon Dioxide in Methoxy and Nitrile-Functionalized Ionic Liquids</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=D.%20A.%20Bruzon">D. A. Bruzon</a>, <a href="https://publications.waset.org/abstracts/search?q=G.%20Tapang"> G. Tapang</a>, <a href="https://publications.waset.org/abstracts/search?q=I.%20S.%20Martinez"> I. S. Martinez</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Global warming and climate change are significant environmental concerns, which require immediate global action in carbon emission mitigation. The capture, sequestration, and conversion of carbon dioxide to other products such as methane or ethanol are ways to control excessive emissions. Ionic liquids have shown great potential among the materials studied as carbon capture solvents and catalysts in the reduction of CO2. In this study, ionic liquids comprising of a methoxy (-OCH3) and cyano (-CN) functionalized imidazolium cation, [MOBMIM] and [CNBMIM] respectively, paired with tris(pentafluoroethyl)trifluorophosphate [FAP] anion were evaluated as effective capture solvents, and organocatalysts in the reduction of CO2. An in-situ electrochemical set-up, which can measure controlled amounts of CO2 both in the gas and in the ionic liquid phase, was used. Initially, reduction potentials of CO2 in the CO2-saturated ionic liquids containing the internal standard cobaltocene were determined using cyclic voltammetry. Chronoamperometric transients were obtained at potentials slightly less negative than the reduction potentials of CO2 in each ionic liquid. The time-dependent current response was measured under a controlled atmosphere. Reduction potentials of CO2 in methoxy and cyano-functionalized [FAP] ionic liquids were observed to occur at ca. -1.0 V (vs. Cc+/Cc), which was significantly lower compared to the non-functionalized analog [PMIM][FAP], with an observed reduction potential of CO2 at -1.6 V (vs. Cc+/Cc). This decrease in the potential required for CO2 reduction in the functionalized ionic liquids shows that the functional groups methoxy and cyano effectively decreased the free energy of formation of the radical anion CO2●⁻, suggesting that these electrolytes may be used as organocatalysts in the reduction of the greenhouse gas. However, upon analyzing the solubility of the gas in each ionic liquid, [PMIM][FAP] showed the highest absorption capacity, at 4.81 mM under saturated conditions, compared to [MOBMIM][FAP] at 1.86 mM, and [CNBMIM][FAP] at 0.76 mM. Also, calculated Henry’s constant determined from the concentration-pressure graph of each functionalized ionic liquid shows that the groups -OCH3 and -CN attached terminal to a C4 alkyl chain do not significantly improve CO2 solubility. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=carbon%20capture" title="carbon capture">carbon capture</a>, <a href="https://publications.waset.org/abstracts/search?q=CO2%20reduction" title=" CO2 reduction"> CO2 reduction</a>, <a href="https://publications.waset.org/abstracts/search?q=electrochemistry" title=" electrochemistry"> electrochemistry</a>, <a href="https://publications.waset.org/abstracts/search?q=ionic%20liquids" title=" ionic liquids"> ionic liquids</a> </p> <a href="https://publications.waset.org/abstracts/61672/solubility-of-carbon-dioxide-in-methoxy-and-nitrile-functionalized-ionic-liquids" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/61672.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">402</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">269</span> Drug Delivery of Cyclophosphamide Functionalized Zigzag (8,0) CNT, Armchair (4,4) CNT, and Nanocone Complexes in Water</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Morteza%20Keshavarz">Morteza Keshavarz</a> </p> <p class="card-text"><strong>Abstract:</strong></p> In this work, using density functional theory (DFT) thermodynamic stability and quantum molecular descriptors of cyclophoshphamide (an anticancer drug)-functionalized zigzag (8,0) CNT, armchair (4,4) CNT and nanocone complexes in water, for two attachment namely the sidewall and tip, is considered. Calculation of the total electronic energy (Et) and binding energy (Eb) of all complexes indicates that the most thermodynamic stability belongs to the sidewall-attachment of cyclophosphamide into functional nanocone. On the other hand, results from chemical hardness show that drug-functionalized zigzag (8,0) and armchair (4,4) complexes in the tip-attachment configuration possess the smallest and greatest chemical hardness, respectively. By computing the solvation energy, it is found that the solution of the drug and all complexes are spontaneous in water. Furthermore, chirality, type of nanovector (nanotube or nanocone), or attachment configuration have no effects on solvation energy of complexes. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=carbon%20nanotube" title="carbon nanotube">carbon nanotube</a>, <a href="https://publications.waset.org/abstracts/search?q=drug%20delivery" title=" drug delivery"> drug delivery</a>, <a href="https://publications.waset.org/abstracts/search?q=cyclophosphamide%20drug" title=" cyclophosphamide drug"> cyclophosphamide drug</a>, <a href="https://publications.waset.org/abstracts/search?q=density%20functional%20theory%20%28DFT%29" title=" density functional theory (DFT) "> density functional theory (DFT) </a> </p> <a href="https://publications.waset.org/abstracts/36834/drug-delivery-of-cyclophosphamide-functionalized-zigzag-80-cnt-armchair-44-cnt-and-nanocone-complexes-in-water" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/36834.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">370</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">268</span> Antimicrobial Activity of Functionalized Alpaca Fabrics with Silver Nanoparticles</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Gina%20Zavaleta-Espejo">Gina Zavaleta-Espejo</a>, <a href="https://publications.waset.org/abstracts/search?q=Segundo%20R.%20J%C3%A1uregui-Rosas"> Segundo R. Jáuregui-Rosas</a>, <a href="https://publications.waset.org/abstracts/search?q=Fanny%20V.%20Samanamud-Moreno"> Fanny V. Samanamud-Moreno</a>, <a href="https://publications.waset.org/abstracts/search?q=Jos%C3%A9%20Salda%C3%B1a%20Jim%C3%A9nez"> José Saldaña Jiménez</a>, <a href="https://publications.waset.org/abstracts/search?q=Anibal%20Felix-Quintero"> Anibal Felix-Quintero</a>, <a href="https://publications.waset.org/abstracts/search?q=V%C3%ADctor%20Montero-Del%20Aguila"> Víctor Montero-Del Aguila</a>, <a href="https://publications.waset.org/abstracts/search?q=Elsi%20Mej%C3%ADa-Uriarte"> Elsi Mejía-Uriarte</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Vicugnapacos "alpaca" fabrics are considered special for their finesse, and the garments in the textile market are very luxurious. It has many special characteristics such as antiallergic, soft, hygroscopic, among others. In this sense, the research aimed to evaluate the antimicrobial activity of alpaca fabrics functionalized with silver nanoparticles on the bacteria Escherichia coli ATCC 25922 and Staphylococcus aureus ATCC 25923. For the functionalization of the fabrics, AgNO3 and different concentrations of trisodium citrate (TSC) 2, 6, and 10 mg. Tissue characterization was performed using Raman spectroscopy, Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM). The determination of the antimicrobial activity of the alpaca tissues was made by the Kirby-Bauer method with alpaca tissue discs functionalized with silver nanoparticles, an experimental design was made in completely randomized blocks with three treatments and a negative control with three repetitions. The results showed that inhibition halos were formed for both bacteria, therefore, the functionalized tissues have a high antimicrobial activity, whose mechanism of action is attributed to the free radicals (ROS) generated by the nanoparticles that cause oxidative damage to the bacteria. proteins and lipids of the bacterial cell wall. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=antimicrobial" title="antimicrobial">antimicrobial</a>, <a href="https://publications.waset.org/abstracts/search?q=animal%20fibers" title=" animal fibers"> animal fibers</a>, <a href="https://publications.waset.org/abstracts/search?q=fabrics" title=" fabrics"> fabrics</a>, <a href="https://publications.waset.org/abstracts/search?q=functionalization" title=" functionalization"> functionalization</a>, <a href="https://publications.waset.org/abstracts/search?q=trisodium%20citrate" title=" trisodium citrate"> trisodium citrate</a> </p> <a href="https://publications.waset.org/abstracts/149105/antimicrobial-activity-of-functionalized-alpaca-fabrics-with-silver-nanoparticles" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/149105.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">137</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">267</span> Dependence of Free Fatty Acid and Chlorophyll Content on Thermal Stability of Extra Virgin Olive Oil</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Yongjun%20Ahn">Yongjun Ahn</a>, <a href="https://publications.waset.org/abstracts/search?q=Sung%20Gyu%20Choi"> Sung Gyu Choi</a>, <a href="https://publications.waset.org/abstracts/search?q=Seung-Yeop%20Kwak"> Seung-Yeop Kwak</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Selective removal of free fatty acid (FFA) and chlorophyll in extra virgin olive oil (EVOO) is necessary to enhance the thermal stability in the condition of the deep frying. In this work, we demonstrated improving the thermal stability of EVOO by selective removal of free fatty acid and chlorophyll using (3-Aminopropyl)trimethoxysilane (APTMS) functionalized mesoporous silica with controlled pore size. The adsorption kinetics of free fatty acid and chlorophyll into the mesoporous silica were quantitatively analyzed by Freundlich and Langmuir model. The highest chlorophyll adsorption efficiency was shown in the pore size at 5 nm, suggesting that the interaction between the silica and the chlorophyll could be optimized at this point. The amino-functionalized mesoporous silica showed drastically improved removal efficiency of FFA than the bare silica. Moreover, beneficial compounds like tocopherol and phenolic compounds maintained even after adsorptive removal. Extra virgin olive oil treated by aminopropyl-functionalized silica had a smoke point high enough to be used as commercial frying oil. Based on these results, it is expected to attract the considerable amount of interest toward facile adsorptive refining process of EVOO using pore size controlled and amino-functionalized mesoporous silica. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=mesoporous%20silica" title="mesoporous silica">mesoporous silica</a>, <a href="https://publications.waset.org/abstracts/search?q=extra%20virgin%20olive%20oil" title=" extra virgin olive oil"> extra virgin olive oil</a>, <a href="https://publications.waset.org/abstracts/search?q=selective%20adsorption" title=" selective adsorption"> selective adsorption</a>, <a href="https://publications.waset.org/abstracts/search?q=thermal%20stability" title=" thermal stability"> thermal stability</a> </p> <a href="https://publications.waset.org/abstracts/96136/dependence-of-free-fatty-acid-and-chlorophyll-content-on-thermal-stability-of-extra-virgin-olive-oil" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/96136.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">241</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">266</span> Inulinase Immobilization on Functionalized Magnetic Nanoparticles Prepared with Soy Protein Isolate Conjugated Bovine Serum Albumin for High Fructose Syrup Production</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Homa%20Torabizadeh">Homa Torabizadeh</a>, <a href="https://publications.waset.org/abstracts/search?q=Mohaddeseh%20Mikani"> Mohaddeseh Mikani </a> </p> <p class="card-text"><strong>Abstract:</strong></p> Inulinase from <em>Aspergillus niger</em> was covalently immobilized on magnetic nanoparticles (MNPs/Fe<sub>3</sub>O<sub>4</sub>) covered with soy protein isolate (SPI/Fe<sub>3</sub>O<sub>4</sub>) functionalized by bovine serum albumin (BSA) nanoparticles. MNPs are promising enzyme carriers because they separate easily under external magnetic fields and have enhanced immobilized enzyme reusability. As MNPs aggregate simply, surface coating strategy was employed. SPI functionalized by BSA was a suitable candidate for nanomagnetite coating due to its superior biocompatibility and hydrophilicity. Fe<sub>3</sub>O<sub>4</sub>@SPI-BSA nanoparticles were synthesized as a novel carrier with narrow particle size distribution. Step by step fabrication monitoring of Fe<sub>3</sub>O<sub>4</sub>@SPI-BSA nanoparticles was performed using field emission scanning electron microscopy and dynamic light scattering. The results illustrated that nanomagnetite with the spherical morphology was well monodispersed with the diameter of about 35 nm. The average size of the SPI-BSA nanoparticles was 80 to 90 nm, and their zeta potential was around −34 mV. Finally, the mean diameter of fabricated Fe<sub>3</sub>O<sub>4</sub>@SPI-BSA NPs was less than 120 nm. Inulinase enzyme from <em>Aspergillus niger</em> was covalently immobilized through gluteraldehyde on Fe<sub>3</sub>O<sub>4</sub>@SPI-BSA nanoparticles successfully. Fourier transform infrared spectra and field emission scanning electron microscopy images provided sufficient proof for the enzyme immobilization on the nanoparticles with 80% enzyme loading. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=high%20fructose%20syrup" title="high fructose syrup">high fructose syrup</a>, <a href="https://publications.waset.org/abstracts/search?q=inulinase%20immobilization" title=" inulinase immobilization"> inulinase immobilization</a>, <a href="https://publications.waset.org/abstracts/search?q=functionalized%20magnetic%20nanoparticles" title=" functionalized magnetic nanoparticles"> functionalized magnetic nanoparticles</a>, <a href="https://publications.waset.org/abstracts/search?q=soy%20protein%20isolate" title=" soy protein isolate"> soy protein isolate</a> </p> <a href="https://publications.waset.org/abstracts/68691/inulinase-immobilization-on-functionalized-magnetic-nanoparticles-prepared-with-soy-protein-isolate-conjugated-bovine-serum-albumin-for-high-fructose-syrup-production" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/68691.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">299</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">265</span> Removal of Chromium (VI) from Contaminated Synthetic Groundwater Using Functionalized Carbon Nanomaterials Modified with Zinc and Potassium</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=P.%20D.%20Ibikunle">P. D. Ibikunle</a>, <a href="https://publications.waset.org/abstracts/search?q=D.%20O.%20Bala"> D. O. Bala</a>, <a href="https://publications.waset.org/abstracts/search?q=A.%20P.%20Olawolu"> A. P. Olawolu</a>, <a href="https://publications.waset.org/abstracts/search?q=A.%20A.%20Adebayo"> A. A. Adebayo</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Chromium has been discovered as a significant contributor to water pollution that causes cancer. Modified carbon nanotubes' (CNTs) potential as an adsorbent hasn't been thoroughly investigated. The study aimed at investigating the potentials of various functionalized carbon nanomaterials for Cr (VI) removal from contaminated synthetic groundwater. Functionalized carbon nanomaterials with layered and tube-like structures were designed based on thermal (KOH-activated micrographite sheets) and impregnation methods by anchoring K and Zn on carbon nanotubes (CNTs), respectively for the removal of Cr (VI) from contaminated synthetic groundwater. Zinc acetate modified carbon nanotubes (Zn-CNTs) and potassium hydroxide modified carbon nanotubes (K-CNTs) exhibited greater adsorption capacity for the Cr (VI) adsorbate compared to KOH-activated graphite (AC-1 and AC-0). Maximum removal efficiency for both adsorbents occurred at pH 2. Omu Aran Hand dug wells can therefore be treated with K–CNTs, since the experimental outcomes showed that CNTs adsorbent could operate well in a range of the experimental scenarios. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=carbon%20nanotubes" title="carbon nanotubes">carbon nanotubes</a>, <a href="https://publications.waset.org/abstracts/search?q=Chromium%20%28VI%29" title=" Chromium (VI)"> Chromium (VI)</a>, <a href="https://publications.waset.org/abstracts/search?q=adsorption" title=" adsorption"> adsorption</a>, <a href="https://publications.waset.org/abstracts/search?q=water%20treatment" title=" water treatment"> water treatment</a>, <a href="https://publications.waset.org/abstracts/search?q=graphitic%20carbon" title=" graphitic carbon"> graphitic carbon</a>, <a href="https://publications.waset.org/abstracts/search?q=kinetics" title=" kinetics"> kinetics</a> </p> <a href="https://publications.waset.org/abstracts/188568/removal-of-chromium-vi-from-contaminated-synthetic-groundwater-using-functionalized-carbon-nanomaterials-modified-with-zinc-and-potassium" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/188568.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">39</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">264</span> Development of Hybrid Materials Combining Biomass as Fique Fibers with Metal-Organic Frameworks, and Their Potential as Mercury Adsorbents</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Karen%20G.%20Bastidas%20Gomez">Karen G. Bastidas Gomez</a>, <a href="https://publications.waset.org/abstracts/search?q=Hugo%20R.%20Zea%20Ramirez"> Hugo R. Zea Ramirez</a>, <a href="https://publications.waset.org/abstracts/search?q=Manuel%20F.%20Ribeiro%20Pereira"> Manuel F. Ribeiro Pereira</a>, <a href="https://publications.waset.org/abstracts/search?q=Cesar%20A.%20Sierra%20Avila"> Cesar A. Sierra Avila</a>, <a href="https://publications.waset.org/abstracts/search?q=Juan%20A.%20Clavijo%20Morales"> Juan A. Clavijo Morales</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The contamination of water sources with heavy metals such as mercury has been an environmental problem; it has generated a high impact on the environment and human health. In countries such as Colombia, mercury contamination due to mining has reached levels much higher than the world average. This work proposes the use of fique fibers as adsorbent in mercury removal. The evaluation of the material was carried out under five different conditions (raw, pretreated by organosolv, functionalized by TEMPO oxidation, fiber functionalized plus MOF-199 and fiber functionalized plus MOF-199-SH). All the materials were characterized using FTIR, SEM, EDX, XRD, and TGA. Regarding the mercury removal, it was done under room pressure and temperature, also pH = 7 for all materials presentations, followed by Atomic Absorption Spectroscopy. The high cellulose content in fique is the main particularity of this lignocellulosic biomass since the degree of oxidation depends on the number of hydroxyl groups on the surface capable of oxidizing into carboxylic acids, a functional group capable of increasing ion exchange with mercury in solution. It was also expected that the impregnation of the MOF would increase the mercury removal; however, it was found that the functionalized fique achieved a greater percentage of removal, resulting in 81.33% of removal, 44% for the fique with the MOF-199 and 72% for the MOF-199-SH with. The pretreated fiber and raw also showed 74% and 56%, respectively, which indicates that fique does not require considerable modifications in its structure to achieve good performances. Even so, the functionalized fiber increases the percentage of removal considerably compared to the pretreated fique, which suggests that the functionalization process is a feasible procedure to apply with the purpose of improving the removal percentage. In addition, this is a procedure that follows a green approach since the reagents involved have low environmental impact, and the contribution to the remediation of natural resources is high. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=biomass" title="biomass">biomass</a>, <a href="https://publications.waset.org/abstracts/search?q=nanotechnology" title=" nanotechnology"> nanotechnology</a>, <a href="https://publications.waset.org/abstracts/search?q=science%20materials" title=" science materials"> science materials</a>, <a href="https://publications.waset.org/abstracts/search?q=wastewater%20treatment" title=" wastewater treatment"> wastewater treatment</a> </p> <a href="https://publications.waset.org/abstracts/123729/development-of-hybrid-materials-combining-biomass-as-fique-fibers-with-metal-organic-frameworks-and-their-potential-as-mercury-adsorbents" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/123729.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">118</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">263</span> Mannose-Functionalized Lipopolysaccharide Nanoparticles for Macrophage-Targeted Dual Delivery of Rifampicin and Isoniazid</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Mumuni%20Sumaila">Mumuni Sumaila</a>, <a href="https://publications.waset.org/abstracts/search?q=Viness%20Pillay"> Viness Pillay</a>, <a href="https://publications.waset.org/abstracts/search?q=Yahya%20E.%20Choonara"> Yahya E. Choonara</a>, <a href="https://publications.waset.org/abstracts/search?q=Pradeep%20Kumar"> Pradeep Kumar</a>, <a href="https://publications.waset.org/abstracts/search?q=Pierre%20P.%20Kondiah"> Pierre P. Kondiah</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Tuberculosis (TB) remains a serious challenge to public health globally, despite every effort put together to curb the disease. Current TB therapeutics available have proven to be inefficient due to a multitude of drawbacks that range from serious adverse effects/drug toxicity to inconsistent bioavailability, which ultimately contributes to the emergence of drug-resistant TB. An effective ‘cargo’ system designed to cleverly deliver therapeutic doses of anti-TB drugs to infection sites and in a sustained-release manner may provide a better therapeutic choice towards winning the war against TB. In the current study, we investigated mannose-functionalized lipopolysaccharide hybrid nanoparticles for safety and efficacy towards macrophage-targeted simultaneous delivery of the two first-line anti-TB drugs, rifampicin (RF) and isoniazid (IS). RF-IS-loaded lipopolysaccharide hybrid nanoparticles were fabricated using the solvent injection technique (SIT), incorporating soy lecithin (SL) and low molecular weight chitosan (CS) as the lipid and polysaccharide components, respectively. Surface-functionalized nanoparticles were obtained through the reaction of the aldehyde group of mannose with free amine functionality present at the surface of the nanoparticles. The functionalized nanocarriers were spherical with average particle size and surface charge of 107.83 nm and +21.77 mV, respectively, and entrapment efficiencies (EE) were 53.52% and 69.80% for RF and IS, respectively. FTIR spectrum revealed high-intensity bands between 1663 cm⁻¹ and 1408 cm⁻¹ wavenumbers (absent in non-functionalized nanoparticles), which could be attributed to the C=N stretching vibration produced by the formation of Schiff’s base (–N=CH–) during the mannosylation reaction. In vitro release studies showed a sustained-release profile for RF and IS, with less than half of the total payload released over a 48-hour period. The nanocarriers were biocompatible and safe, with more than 80% cell viability achieved when incubated with RAW 264.7 cells at concentrations 30 to 500 μg/mL over a 24-hour period. Cellular uptake studies (after a 24-hour incubation period with the murine macrophage cells, RAW 264.7) revealed a 13- and a 9-fold increase in intracellular accumulation of RF and IS, respectively, when compared with the unformulated RF+IS solution. A 6- and a 3-fold increase in intracellular accumulation of RF and IS, respectively, were observed when compared with the non-functionalized nanoparticles. Furthermore, fluorescent microscopy images showed nanoparticle internalization and accumulation within the RAW 264.7 cells, which was more significant in the mannose-functionalized system compared to the non-functionalized nanoparticles. The overall results suggested that the fabricated mannose-functionalized lipopolysaccharide nanoparticles are a safe and promising platform for macrophage-targeted delivery of anti-TB therapeutics. However, in vivo pharmacokinetic/pharmacodynamics studies are required to further substantiate the therapeutic efficacy of the nanosystem. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=anti-tuberculosis%20therapeutics" title="anti-tuberculosis therapeutics">anti-tuberculosis therapeutics</a>, <a href="https://publications.waset.org/abstracts/search?q=hybrid%20nanosystem" title=" hybrid nanosystem"> hybrid nanosystem</a>, <a href="https://publications.waset.org/abstracts/search?q=lipopolysaccharide%20nanoparticles" title=" lipopolysaccharide nanoparticles"> lipopolysaccharide nanoparticles</a>, <a href="https://publications.waset.org/abstracts/search?q=macrophage-targeted%20delivery" title=" macrophage-targeted delivery"> macrophage-targeted delivery</a> </p> <a href="https://publications.waset.org/abstracts/134936/mannose-functionalized-lipopolysaccharide-nanoparticles-for-macrophage-targeted-dual-delivery-of-rifampicin-and-isoniazid" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/134936.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">172</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">262</span> Preparation of Poly(Acrylic Acid) Functionalized Magnetic Graphene Oxide Composite and Its Application for Pb(II) Removal</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Yu%20Wang">Yu Wang</a>, <a href="https://publications.waset.org/abstracts/search?q=Xibang%20Chen"> Xibang Chen</a>, <a href="https://publications.waset.org/abstracts/search?q=Maolin%20Zhai"> Maolin Zhai</a>, <a href="https://publications.waset.org/abstracts/search?q=Jing%20Peng"> Jing Peng</a>, <a href="https://publications.waset.org/abstracts/search?q=Jiuqiang%20Li"> Jiuqiang Li</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Poly(acrylic acid) (PAA) functionalized magnetic graphene oxide (GO) composite was synthesized through a two-step process. Magnetic Fe₃O₄/GO was first prepared by a facile hydrothermal method. A radiation-induced grafting technique was used to graft PAA to Fe₃O₄/GO to obtain the Fe₃O₄/GO-g-PAA subsequently. The characteristics results of FTIR, Raman, XRD, SEM, TEM, and VSM showed that Fe₃O₄/GO-g-PAA was successfully prepared. The Fe₃O₄/GO-g-PAA composites were used as sorbents for the removal of Pb(II) ions, and the maximum adsorption capacity for Pb(II) was 176.92 mg/g. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=Fe%E2%82%83O%E2%82%84" title="Fe₃O₄">Fe₃O₄</a>, <a href="https://publications.waset.org/abstracts/search?q=graphene%20oxide" title=" graphene oxide"> graphene oxide</a>, <a href="https://publications.waset.org/abstracts/search?q=magnetic" title=" magnetic"> magnetic</a>, <a href="https://publications.waset.org/abstracts/search?q=Pb%28II%29%20removal" title=" Pb(II) removal"> Pb(II) removal</a>, <a href="https://publications.waset.org/abstracts/search?q=radiation-induced" title=" radiation-induced"> radiation-induced</a> </p> <a href="https://publications.waset.org/abstracts/130434/preparation-of-polyacrylic-acid-functionalized-magnetic-graphene-oxide-composite-and-its-application-for-pbii-removal" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/130434.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">158</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">261</span> The Effect of Interfacial Chemistry on Mechanical Properties of Epoxy Composites Containing Poly (Ether Ether Ketone) Grafted Multiwall Carbon Nanotubes</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Prajakta%20Katti">Prajakta Katti</a>, <a href="https://publications.waset.org/abstracts/search?q=Suryasarathi%20Bose"> Suryasarathi Bose</a>, <a href="https://publications.waset.org/abstracts/search?q=S.%20Kumar"> S. Kumar</a> </p> <p class="card-text"><strong>Abstract:</strong></p> In this work, carboxyl functionalized multiwall carbon nanotubes (a-MWNTs) covalently grafted with hydroxylated functionalized poly (ether ether ketone), HPEEK, which is miscible with the pre-polymer (epoxy) through the esterification reaction. The functionalized MWNTs were systematically characterized using spectroscopic techniques. The epoxy composites containing a-MWNTs and HPEEK grafted multiwall carbon nanotubes (HPEEK-g-MWNTs) were formulated using mechanical stirring coupled with a bath sonicator to improve the dispersion property of the nanoparticles and were subsequently cured at 80 ̊C and post cured at 180 ̊C. With the addition of 0.5 wt% of HPEEK-g-MWNTs, an impressive 44% enhancement in the storage modulus, 22% increase in tensile strength and 38% increase in fracture toughness was observed with respect to neat epoxy. In addition to these mechanical properties, the epoxy composites displayed significant enhancement in the hardness without reducing thermal stability. These improved properties were attributed to the tailored interface between HPEEK-MWNTs and epoxy matrix. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=epoxy" title="epoxy">epoxy</a>, <a href="https://publications.waset.org/abstracts/search?q=MWNTs" title=" MWNTs"> MWNTs</a>, <a href="https://publications.waset.org/abstracts/search?q=HPEEK-g-MWNTs" title=" HPEEK-g-MWNTs"> HPEEK-g-MWNTs</a>, <a href="https://publications.waset.org/abstracts/search?q=tensile%20properties" title=" tensile properties"> tensile properties</a>, <a href="https://publications.waset.org/abstracts/search?q=nanoindentation" title=" nanoindentation"> nanoindentation</a>, <a href="https://publications.waset.org/abstracts/search?q=fracture%20toughness" title=" fracture toughness"> fracture toughness</a> </p> <a href="https://publications.waset.org/abstracts/63639/the-effect-of-interfacial-chemistry-on-mechanical-properties-of-epoxy-composites-containing-poly-ether-ether-ketone-grafted-multiwall-carbon-nanotubes" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/63639.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">309</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">260</span> Exfoliation of Functionalized High Structural Integrity Graphene Nanoplatelets at Extremely Low Temperature</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Mohannad%20N.%20H.%20Al-Malichi">Mohannad N. H. Al-Malichi</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Because of its exceptional properties, graphene has become the most promising nanomaterial for the development of a new generation of advanced materials from battery electrodes to structural composites. However, current methods to meet requirements for the mass production of high-quality graphene are limited by harsh oxidation, high temperatures, and tedious processing steps. To extend the scope of the bulk production of graphene, herein, a facile, reproducible and cost-effective approach has been developed. This involved heating a specific mixture of chemical materials at an extremely low temperature (70 C) for a short period (7 minutes) to exfoliate functionalized graphene platelets with high structural integrity. The obtained graphene platelets have an average thickness of 3.86±0.71 nm and a lateral size less than ~2 µm with a low defect intensity ID/IG ~0.06. The thin film (~2 µm thick) exhibited a low surface resistance of ~0.63 Ω/sq⁻¹, confirming its high electrical conductivity. Additionally, these nanoplatelets were decorated with polar functional groups (epoxy and carboxyl groups), thus have the potential to toughen and provide multifunctional polymer nanocomposites. Moreover, such a simple method can be further exploited for the novel exfoliation of other layered two-dimensional materials such as MXenes. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=functionalized%20graphene%20nanoplatelets" title="functionalized graphene nanoplatelets">functionalized graphene nanoplatelets</a>, <a href="https://publications.waset.org/abstracts/search?q=high%20structural%20integrity%20graphene" title=" high structural integrity graphene"> high structural integrity graphene</a>, <a href="https://publications.waset.org/abstracts/search?q=low%20temperature%20exfoliation%20of%20graphene" title=" low temperature exfoliation of graphene"> low temperature exfoliation of graphene</a>, <a href="https://publications.waset.org/abstracts/search?q=functional%20graphene%20platelets" title=" functional graphene platelets"> functional graphene platelets</a> </p> <a href="https://publications.waset.org/abstracts/121709/exfoliation-of-functionalized-high-structural-integrity-graphene-nanoplatelets-at-extremely-low-temperature" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/121709.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">120</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">259</span> Functionalized Magnetic Iron Oxide Nanoparticles for Extraction of Protein and Metal Nanoparticles from Complex Fluids</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Meenakshi%20Verma">Meenakshi Verma</a>, <a href="https://publications.waset.org/abstracts/search?q=Mandeep%20Singh%20Bakshi"> Mandeep Singh Bakshi</a>, <a href="https://publications.waset.org/abstracts/search?q=Kultar%20Singh"> Kultar Singh</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Magnetic nanoparticles have received incredible importance in view of their diverse applications, which arise primarily due to their response to the external magnetic field. The magnetic behaviour of magnetic nanoparticles (NPs) helps them in numerous different ways. The most important amongst them is the ease with which they can be purified and also can be separated from the media in which they are present merely by applying an external magnetic field. This exceptional ease of separation of the magnetic NPs from an aqueous media enables them to use for extracting/removing metal pollutants from complex aqueous medium. Functionalized magnetic NPs can be subjected for the metallic impurities extraction if are favourably adsorbed on the NPs surfaces. We have successfully used the magnetic NPs as vehicles for gold and silver NPs removal from the complex fluids. The NPs loaded with gold and silver NPs pollutant fractions has been easily removed from the aqueous media by using external magnetic field. Similarly, we have used the magnetic NPs for extraction of protein from complex media and then constantly washed with pure water to eliminate the unwanted surface adsorbed components for quantitative estimation. The purified and protein loaded magnetic NPs are best analyzed with SDS Page to not only for characterization but also for separating the protein fractions. A collective review of the results indicates that we have synthesized surfactant coated iron oxide NPs and then functionalized these with selected materials. These surface active magnetic NPs work very well for the extraction of metallic NPs from the aqueous bulk and make the whole process environmentally sustainable. Also, magnetic NPs-Au/Ag/Pd hybrids have excellent protein extracting properties. They are much easier to use in order to extract the magnetic impurities as well as protein fractions under the effect of external magnetic field without any complex conventional purification methods. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=magnetic%20nanoparticles" title="magnetic nanoparticles">magnetic nanoparticles</a>, <a href="https://publications.waset.org/abstracts/search?q=protein" title=" protein"> protein</a>, <a href="https://publications.waset.org/abstracts/search?q=functionalized" title=" functionalized"> functionalized</a>, <a href="https://publications.waset.org/abstracts/search?q=extraction" title=" extraction"> extraction</a> </p> <a href="https://publications.waset.org/abstracts/122882/functionalized-magnetic-iron-oxide-nanoparticles-for-extraction-of-protein-and-metal-nanoparticles-from-complex-fluids" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/122882.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">100</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">258</span> Design, Synthesis, and Catalytic Applications of Functionalized Metal Complexes and Nanomaterials for Selective Oxidation and Coupling Reactions</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Roghaye%20Behroozi">Roghaye Behroozi</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The development of functionalized metal complexes and nanomaterials has gained significant attention due to their potential in catalyzing selective oxidation and coupling reactions. These catalysts play a crucial role in various industrial and pharmaceutical processes, enhancing the efficiency, selectivity, and sustainability of chemical reactions. This research aims to design and synthesize new functionalized metal complexes and nanomaterials to explore their catalytic applications in the selective oxidation of alcohols and coupling reactions, focusing on improving yield, selectivity, and catalyst reusability. The study involves the synthesis of a nickel Schiff base complex stabilized within 41-MCM as a heterogeneous catalyst. A Schiff base ligand derived from glycine was used to create a tin (IV) metal complex characterized through spectroscopic techniques and computational analysis. Additionally, iron-based magnetic nanoparticles functionalized with melamine were synthesized for catalytic evaluation. Lastly, a palladium (IV) complex was prepared, and its oxidative stability was analyzed. The nickel Schiff base catalyst showed high selectivity in converting primary and secondary alcohols to aldehydes and ketones, with yields ranging from 73% to 90%. The tin (IV) complex demonstrated accurate structural and electronic properties, with consistent results between experimental and computational data. The melamine-functionalized iron nanoparticles exhibited efficient catalytic activity in producing triazoles, with enhanced reaction speed and reusability. The palladium (IV) complex displayed remarkable stability and low reactivity towards C–C bond formation due to its symmetrical structure. The synthesized metal complexes and nanomaterials demonstrated significant potential as efficient, selective, and reusable catalysts for oxidation and coupling reactions. These findings pave the way for developing environmentally friendly and cost-effective catalytic systems for industrial applications. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=catalysts" title="catalysts">catalysts</a>, <a href="https://publications.waset.org/abstracts/search?q=Schiff%20base%20complexes" title=" Schiff base complexes"> Schiff base complexes</a>, <a href="https://publications.waset.org/abstracts/search?q=metal-organic%20frameworks" title=" metal-organic frameworks"> metal-organic frameworks</a>, <a href="https://publications.waset.org/abstracts/search?q=oxidation%20reactions" title=" oxidation reactions"> oxidation reactions</a>, <a href="https://publications.waset.org/abstracts/search?q=nanoparticles" title=" nanoparticles"> nanoparticles</a>, <a href="https://publications.waset.org/abstracts/search?q=reusability" title=" reusability"> reusability</a> </p> <a href="https://publications.waset.org/abstracts/192967/design-synthesis-and-catalytic-applications-of-functionalized-metal-complexes-and-nanomaterials-for-selective-oxidation-and-coupling-reactions" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/192967.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">15</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">257</span> Performance Evaluation of Polyethyleneimine/Polyethylene Glycol Functionalized Reduced Graphene Oxide Membranes for Water Desalination via Forward Osmosis</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Mohamed%20Edokali">Mohamed Edokali</a>, <a href="https://publications.waset.org/abstracts/search?q=Robert%20Menzel"> Robert Menzel</a>, <a href="https://publications.waset.org/abstracts/search?q=David%20Harbottle"> David Harbottle</a>, <a href="https://publications.waset.org/abstracts/search?q=Ali%20Hassanpour"> Ali Hassanpour</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Forward osmosis (FO) process has stood out as an energy-efficient technology for water desalination and purification, although the practical application of FO for desalination still relies on RO-based Thin Film Composite (TFC) and Cellulose Triacetate (CTA) polymeric membranes which have a low performance. Recently, graphene oxide (GO) laminated membranes have been considered an ideal selection to overcome the bottleneck of the FO-polymeric membranes owing to their simple fabrication procedures, controllable thickness and pore size and high water permeability rates. However, the low stability of GO laminates in wet and harsh environments is still problematic. The recent developments of modified GO and hydrophobic reduced graphene oxide (rGO) membranes for FO desalination have demonstrated attempts to overcome the ongoing trade-off between desalination performance and stability, which is yet to be achieved prior to the practical implementation. In this study, acid-functionalized GO nanosheets cooperatively reduced and crosslinked by the hyperbranched polyethyleneimine (PEI) and polyethylene glycol (PEG) polymers, respectively, are applied for fabrication of the FO membrane, to enhance the membrane stability and performance, and compared with other functionalized rGO-FO membranes. PEI/PEG doped rGO membrane retained two compacted d-spacings (0.7 and 0.31 nm) compared to the acid-functionalized GO membrane alone (0.82 nm). Besides increasing the hydrophilicity, the coating layer of PEG onto the PEI-doped rGO membrane surface enhanced the structural integrity of the membrane chemically and mechanically. As a result of these synergetic effects, the PEI/PEG doped rGO membrane exhibited a water permeation of 7.7 LMH, salt rejection of 97.9 %, and reverse solute flux of 0.506 gMH at low flow rates in the FO desalination process. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=desalination" title="desalination">desalination</a>, <a href="https://publications.waset.org/abstracts/search?q=forward%20osmosis" title=" forward osmosis"> forward osmosis</a>, <a href="https://publications.waset.org/abstracts/search?q=membrane%20performance" title=" membrane performance"> membrane performance</a>, <a href="https://publications.waset.org/abstracts/search?q=polyethyleneimine" title=" polyethyleneimine"> polyethyleneimine</a>, <a href="https://publications.waset.org/abstracts/search?q=polyethylene%20glycol" title=" polyethylene glycol"> polyethylene glycol</a>, <a href="https://publications.waset.org/abstracts/search?q=reduced%20graphene%20oxide" title=" reduced graphene oxide"> reduced graphene oxide</a>, <a href="https://publications.waset.org/abstracts/search?q=stability" title=" stability"> stability</a> </p> <a href="https://publications.waset.org/abstracts/162019/performance-evaluation-of-polyethyleneiminepolyethylene-glycol-functionalized-reduced-graphene-oxide-membranes-for-water-desalination-via-forward-osmosis" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/162019.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">98</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">256</span> Synthesis, Characterization and Applications of Some Selected Dye-Functionalized P and N-Type Nanoparticles in Dye Sensitized Solar Cells</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Arifa%20Batool">Arifa Batool</a>, <a href="https://publications.waset.org/abstracts/search?q=Ghulam%20Hussain%20Bhatti"> Ghulam Hussain Bhatti</a>, <a href="https://publications.waset.org/abstracts/search?q=Syed%20Mujtaba%20Shah"> Syed Mujtaba Shah</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Inorganic n-type (TiO2, CdO) and p-type (NiO, CuO) metal oxide nanoparticles were synthesized by a facile wet chemical method at room temperature. The morphological, compositional, structural and optical properties were investigated by scanning electron microscopy, energy dispersive X-ray spectroscopy, FT-IR, XRD analysis, UV/Visible and fluorescence spectroscopy. All semiconducting nanoparticles were photosensitized with Ru (II) based Z907 dye in ethanol solvent by grafting. Grafting of dye on the surface of nanoparticles was confirmed by UV/Visible and FT-IR spectroscopy. The synthesized photo-active nanohybrid was thoroughly blended with P3HT, a solid electrolyte and I-V measurements under solar stimulated radiations 1000 W/m2 (AM 1.5) were recorded. Maximum incident photon to current conversion efficiency (IPCE) of 0.9% was achieved with dye functionalized Z907-TiO2 hybrid, IPCE of 0.72% was achieved with bulk-heterojunction of TiO2-Z907-CuO and IPCE of 0.68% was attained with nanocomposite of TiO2-CdO. TiO2 based Solar cells have maximum Jscvalue i.e.4.63 mA/cm2. Dye-functionalized TiO2-based photovoltaic devices were found more efficient than the reference device but the morphology of the device was a major check in progress. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=solar%20cell" title="solar cell">solar cell</a>, <a href="https://publications.waset.org/abstracts/search?q=bulk%20heterojunction" title=" bulk heterojunction"> bulk heterojunction</a>, <a href="https://publications.waset.org/abstracts/search?q=nanocomposites" title=" nanocomposites"> nanocomposites</a>, <a href="https://publications.waset.org/abstracts/search?q=photosensitization" title=" photosensitization"> photosensitization</a>, <a href="https://publications.waset.org/abstracts/search?q=dye%20sensitized%20solar%20cell" title=" dye sensitized solar cell"> dye sensitized solar cell</a> </p> <a href="https://publications.waset.org/abstracts/73329/synthesis-characterization-and-applications-of-some-selected-dye-functionalized-p-and-n-type-nanoparticles-in-dye-sensitized-solar-cells" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/73329.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">284</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">255</span> Functionalized Mesoporous Silica: Absorbents for Water Purification</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Saima%20Nasreen">Saima Nasreen</a>, <a href="https://publications.waset.org/abstracts/search?q=Uzaira%20Rafique"> Uzaira Rafique</a>, <a href="https://publications.waset.org/abstracts/search?q=Shery%20Ehrman"> Shery Ehrman</a>, <a href="https://publications.waset.org/abstracts/search?q=Muhammad%20Aqeel%20Ashraf"> Muhammad Aqeel Ashraf</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The release of heavy metals into the environment is a potential threat to water and soil quality as well as to plant, animal and human health. In current research work, organically functionalized mesoporous silicates (MSU-H) were prepared by the co-condensation between sodium silicate and oregano alkoxysilanes in the presence of the nonionic surfactant triblock copolymer P104. The surfactant was used as a template for improving the porosity of the hybrid gels. Synthesized materials were characterized by TEM, FT-IR, SEM/EDX, TG, surface area analysis. The surface morphology and textural properties of such materials varied with various kinds of groups in the channels. In this study, removal of some heavy metals ions from aqueous solution by adsorption process was investigated. Batch adsorption studies show that the adsorption capacity of metal ions on the functionalized silicates is more than that on pure MSU-H. Data shows adsorption on synthesized materials is a time efficient process, suggesting adsorption on external surface as well as the mesoporous process. Adsorption models of Langmuir, Freundlich, and Temkin depicted equal goodness for all adsorbents, whereas pseudo 2nd order kinetics is in best agreement with experimental data. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=heavy%20metals" title="heavy metals">heavy metals</a>, <a href="https://publications.waset.org/abstracts/search?q=mesoporous%20silica" title=" mesoporous silica"> mesoporous silica</a>, <a href="https://publications.waset.org/abstracts/search?q=hybrid" title=" hybrid"> hybrid</a>, <a href="https://publications.waset.org/abstracts/search?q=adsorption" title=" adsorption"> adsorption</a>, <a href="https://publications.waset.org/abstracts/search?q=freundlich" title=" freundlich"> freundlich</a>, <a href="https://publications.waset.org/abstracts/search?q=langmuir" title=" langmuir"> langmuir</a>, <a href="https://publications.waset.org/abstracts/search?q=temkin" title=" temkin"> temkin</a> </p> <a href="https://publications.waset.org/abstracts/39518/functionalized-mesoporous-silica-absorbents-for-water-purification" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/39518.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">269</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">254</span> Boron Nitride Nanoparticle Enhanced Prepreg Composite Laminates </h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Qiong%20Tian">Qiong Tian</a>, <a href="https://publications.waset.org/abstracts/search?q=Lifeng%20Zhang"> Lifeng Zhang</a>, <a href="https://publications.waset.org/abstracts/search?q=Demei%20Yu"> Demei Yu</a>, <a href="https://publications.waset.org/abstracts/search?q=Ajit%20D.%20Kelkar"> Ajit D. Kelkar </a> </p> <p class="card-text"><strong>Abstract:</strong></p> Low specific weight and high strength is the basic requirement for aerospace materials. Fiber-reinforced epoxy resin composites are attractive materials for this purpose. Boron nitride nanoparticles (BNNPs) have good radiation shielding capacity, which is very important to aerospace materials. Herein a processing route for an advanced hybrid composite material is demonstrated by introducing dispersed BNNPs in standard prepreg manufacturing. The hybrid materials contain three parts: E-fiberglass, an aerospace-grade epoxy resin system, and BNNPs. A vacuum assisted resin transfer molding (VARTM) was utilized in this processing. Two BNNP functionalization approaches are presented in this study: (a) covalent functionalization with 3-aminopropyltriethoxysilane (KH-550); (b) non-covalent functionalization with cetyltrimethylammonium bromide (CTAB). The functionalized BNNPs were characterized by Fourier-transform infrared spectroscopy (FT-IR), X-ray diffraction(XRD) and scanning electron microscope (SEM). The results showed that BN powder was successfully functionalized via the covalent and non-covalent approaches without any crystal structure change and big agglomerate particles were broken into platelet-like nanoparticles (BNNPs) after functionalization. Compared to pristine BN powder, surface modified BNNPs could result in significant improvement in mechanical properties such as tensile, flexural and compressive strength and modulus. CTAB functionalized BNNPs (CTAB-BNNPs) showed higher tensile and flexural strength but lower compressive strength than KH-550 functionalized BNNPs (KH550-BNNPs). These reinforcements are mainly attributed to good BNNPs dispersion and interfacial adhesion between epoxy matrix and BNNPs. This study reveals the potential in improving mechanical properties of BNNPs-containing composites laminates through surface functionalization of BNNPs. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=boron%20nitride" title="boron nitride">boron nitride</a>, <a href="https://publications.waset.org/abstracts/search?q=epoxy" title=" epoxy"> epoxy</a>, <a href="https://publications.waset.org/abstracts/search?q=functionalization" title=" functionalization"> functionalization</a>, <a href="https://publications.waset.org/abstracts/search?q=prepreg" title=" prepreg"> prepreg</a>, <a href="https://publications.waset.org/abstracts/search?q=composite" title=" composite "> composite </a> </p> <a href="https://publications.waset.org/abstracts/24228/boron-nitride-nanoparticle-enhanced-prepreg-composite-laminates" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/24228.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">434</span> </span> </div> </div> <ul class="pagination"> <li class="page-item disabled"><span class="page-link">&lsaquo;</span></li> <li class="page-item active"><span class="page-link">1</span></li> <li class="page-item"><a class="page-link" href="https://publications.waset.org/abstracts/search?q=functionalized&page=2">2</a></li> <li class="page-item"><a class="page-link" href="https://publications.waset.org/abstracts/search?q=functionalized&page=3">3</a></li> <li class="page-item"><a class="page-link" href="https://publications.waset.org/abstracts/search?q=functionalized&page=4">4</a></li> <li class="page-item"><a class="page-link" href="https://publications.waset.org/abstracts/search?q=functionalized&page=5">5</a></li> <li class="page-item"><a class="page-link" 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