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On the proper use of a Warburg impedance – Physics World

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</div> <article id="post-116636" class="post-116636 post type-post status-publish format-standard has-post-thumbnail hentry category-instrumentation-measurement article-type-webinars"> <div class="entry-content"> <!-- Issue information --> <!-- Standfirst --> <div class="standfirst"> <p><strong>Join the audience for a live webinar at 3 p.m. GMT/10 a.m. EST on 4 December 2024 </strong></p> <p>Explore the proper use of a Warburg impedance for batteries</p> </div> <!-- Thumbnail --> <div class="cta-block"><div class="cta-block__content category-background-color"><div class="cta-block__left"><p>Want to take part in this webinar?</p></div><div class="cta-block__right"><a class="category-text-color" href="https://attendee.gotowebinar.com/register/2738552953552231765?source=PW+landing+page" target="_blank" rel="nofollow sponsored">Register now</a></div></div></div> <p><img decoding="async" class="alignnone size-full wp-image-116638" src="https://physicsworld.com/wp-content/uploads/2024/09/2024-12-04-webinar-image.jpg" alt="" width="800" height="716" srcset="https://physicsworld.com/wp-content/uploads/2024/09/2024-12-04-webinar-image.jpg 800w, https://physicsworld.com/wp-content/uploads/2024/09/2024-12-04-webinar-image-211x189.jpg 211w, https://physicsworld.com/wp-content/uploads/2024/09/2024-12-04-webinar-image-317x284.jpg 317w, https://physicsworld.com/wp-content/uploads/2024/09/2024-12-04-webinar-image-768x687.jpg 768w, https://physicsworld.com/wp-content/uploads/2024/09/2024-12-04-webinar-image-447x400.jpg 447w, https://physicsworld.com/wp-content/uploads/2024/09/2024-12-04-webinar-image-460x412.jpg 460w, https://physicsworld.com/wp-content/uploads/2024/09/2024-12-04-webinar-image-458x410.jpg 458w, https://physicsworld.com/wp-content/uploads/2024/09/2024-12-04-webinar-image-635x568.jpg 635w, https://physicsworld.com/wp-content/uploads/2024/09/2024-12-04-webinar-image-220x197.jpg 220w, https://physicsworld.com/wp-content/uploads/2024/09/2024-12-04-webinar-image-216x193.jpg 216w, https://physicsworld.com/wp-content/uploads/2024/09/2024-12-04-webinar-image-279x250.jpg 279w, https://physicsworld.com/wp-content/uploads/2024/09/2024-12-04-webinar-image-101x90.jpg 101w, https://physicsworld.com/wp-content/uploads/2024/09/2024-12-04-webinar-image-128x115.jpg 128w" sizes="(max-width: 800px) 100vw, 800px" /></p> <p>Recent battery papers commonly employ interpretation models for which diffusion impedances are in series with interfacial impedance. The models are fundamentally flawed because the diffusion impedance should be part of the interfacial impedance. A general approach is presented that shows how the charge-transfer resistance and diffusion resistance are functions of the concentration of reacting species at the electrode surface. The resulting impedance model incorporates diffusion impedances as part of the interfacial impedance.</p> <p>An interactive Q&amp;A session follows the presentation.</p> <div class="cta-block"><div class="cta-block__content category-background-color"><div class="cta-block__left"><p>Want to take part in this webinar?</p></div><div class="cta-block__right"><a class="category-text-color" href="https://attendee.gotowebinar.com/register/2738552953552231765?source=PW+landing+page" target="_blank" rel="nofollow sponsored">Register now</a></div></div></div> <figure class="size-thumbnail" id="attachment_116637"><a data-fancybox data-src="https://physicsworld.com/wp-content/uploads/2024/09/Mark-Orazem.jpg" data-caption="Mark Orazem" title="Click to open image in popup" href="https://physicsworld.com/wp-content/uploads/2024/09/Mark-Orazem.jpg"><img loading="lazy" decoding="async" width="261" height="317" src="https://physicsworld.com/wp-content/uploads/2024/09/Mark-Orazem-261x317.jpg" class="attachment-thumbnail size-thumbnail" alt="" srcset="https://physicsworld.com/wp-content/uploads/2024/09/Mark-Orazem-261x317.jpg 261w, https://physicsworld.com/wp-content/uploads/2024/09/Mark-Orazem-174x211.jpg 174w, https://physicsworld.com/wp-content/uploads/2024/09/Mark-Orazem-768x931.jpg 768w, https://physicsworld.com/wp-content/uploads/2024/09/Mark-Orazem-330x400.jpg 330w, https://physicsworld.com/wp-content/uploads/2024/09/Mark-Orazem-340x412.jpg 340w, https://physicsworld.com/wp-content/uploads/2024/09/Mark-Orazem-338x410.jpg 338w, https://physicsworld.com/wp-content/uploads/2024/09/Mark-Orazem-635x770.jpg 635w, https://physicsworld.com/wp-content/uploads/2024/09/Mark-Orazem-162x197.jpg 162w, https://physicsworld.com/wp-content/uploads/2024/09/Mark-Orazem-159x193.jpg 159w, https://physicsworld.com/wp-content/uploads/2024/09/Mark-Orazem-206x250.jpg 206w, https://physicsworld.com/wp-content/uploads/2024/09/Mark-Orazem-74x90.jpg 74w, https://physicsworld.com/wp-content/uploads/2024/09/Mark-Orazem-106x128.jpg 106w, https://physicsworld.com/wp-content/uploads/2024/09/Mark-Orazem.jpg 833w" sizes="(max-width: 261px) 100vw, 261px" /></a><script type="application/json">"Mark Orazem"</script><figcaption class="gallery-item__caption">Mark Orazem</figcaption></figure> <p><strong>Mark Orazem </strong>obtained his BS and MS degrees from Kansas State University and his PhD in 1983 from the University of California, Berkeley. In 1983, he began his career as assistant professor at the University of Virginia, and in 1988 joined the faculty of the University of Florida, where he is Distinguished Professor of Chemical Engineering and Associate Chair for Graduate Studies. Mark is a fellow of The Electrochemical Society, International Society of Electrochemistry, and American Association for the Advancement of Science. He served as President of the International Society of Electrochemistry and co-authored, with Bernard Tribollet of the Centre national de la recherche scientifique (CNRS), the textbook entitled <em>Electrochemical Impedance Spectroscopy</em>, now in its second edition. Mark received the ECS Henry B. Linford Award, ECS Corrosion Division H. H. Uhlig Award, and with co-author Bernard Tribollet, the 2019 Claude Gabrielli Award for contributions to electrochemical impedance spectroscopy. In addition to writing books, he has taught short courses on impedance spectroscopy for The Electrochemical Society since 2000.</p> <p>&nbsp;</p> <p><a class="no-caption size-medium" href="ttps://www.electrochem.org/webinars" data-featherlight=""><img loading="lazy" decoding="async" class="wp-image-89822 size-full alignnone" src="https://physicsworld.com/wp-content/uploads/2020/08/ECS_Logo_2015_CS6-e1620911266638.jpg" alt="The Electrochemical Society" width="1200" height="174" /></a></p> <p><a class="no-caption size-medium" href="https://www.gamry.com " data-featherlight=""><img loading="lazy" decoding="async" class="wp-image-114320 size-full alignnone" src="https://physicsworld.com/wp-content/uploads/2024/04/Gamry-Instruments-logo-5.jpg" alt="" width="1667" height="204" srcset="https://physicsworld.com/wp-content/uploads/2024/04/Gamry-Instruments-logo-5.jpg 1667w, https://physicsworld.com/wp-content/uploads/2024/04/Gamry-Instruments-logo-5-211x26.jpg 211w, 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