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The poly - amino acids employed for the Juliá - Colonna epoxidation are sta- tistical mixtures , the maximum of the length distribution\u0026nbsp;...","page_url":"https://books.google.com.sg/books?id=UgNp8-wq-aAC\u0026pg=PA19\u0026vq=derivative\u0026dq=subject:%22Science+Chemistry%22"},{"page_id":"PA31","page_number":"31","snippet_text":"... \u003cb\u003ederivatives\u003c/b\u003e of dioxygen , such as the superoxide radical anion ( 0 ̄ ) and dihydrogen perox- ide ( H2O2 ) ( 21,22 ) . These iron proteins can be divided into heme ( containing a porphyrin group with an iron ( III ) ion ) ( 23 ) and non\u0026nbsp;..."},{"page_id":"PA47","page_number":"47","snippet_text":"... \u003cb\u003ederivative\u003c/b\u003e ( 71 ) . The compound { [ Fe ( pb ) 2 ( H2O ) ] 2O } ( ClO4 ) 4 is able to effect selectively the oxi- dation of cyclohexane ( A / K = 2 ) with a total yield of 30 % based on H2O2 ( 71 ) . The most impressive achievement is\u0026nbsp;..."},{"page_id":"PA52","page_number":"52","snippet_text":"... \u003cb\u003ederivative\u003c/b\u003e ligand of Hpma , the optically active cis - ẞ - epoxide was obtained in about 45 % ee in the oxidation of cis - ẞ - methylstyrene , whereas the epoxidation of trans - ẞ - methylstyrene resulted in the formation of the racemic\u0026nbsp;..."},{"page_id":"PA56","page_number":"56","snippet_text":"... \u003cb\u003ederivatives\u003c/b\u003e that can be transformed under the action of acetic. acid. to. form. an. O. = MnV. -. MnV_OOH. species . The. substrate. RH. reacts. with. the manganese - oxo group resulting in the formation of R radicals , that. further. react."},{"page_id":"PA57","page_number":"57","snippet_text":"... \u003cb\u003ederivative\u003c/b\u003e , pyridine FIG . 21. Proposed mechanism for manganese - catalyzed olefin epoxidations ( 123 ) . H N N CH2 CH3 t - Bu N N Mn CH3 t - Bu + BF H3C Ph H H Ph N Mn CI t -. FIG . 22. Pentadentate dihydrosalen complex of manganese as\u0026nbsp;..."},{"page_id":"PA58","page_number":"58","snippet_text":"... than 99 % ee were obtained with chromenes and . FIG 24. Structure of the H-phox \u003cb\u003ederivatives\u003c/b\u003e. indene, using. FIG . 23. Jacobsen - type catalysts . FIG . 26. Molecular structure of the complex [ Mn. 58 S. TANASE and E. BOUWMAN."},{"page_id":"PA59","page_number":"59","snippet_text":"... \u003cb\u003ederivatives\u003c/b\u003e. indene, using ammonium acetate as co-catalyst. Only marginal improvement in ee values was observed in the presence of coordinating co-catalysts, while both the conversion and the ee decreased in the presence of nitrogen\u0026nbsp;..."},{"page_id":"PA60","page_number":"60","snippet_text":"... \u003cb\u003ederivatives\u003c/b\u003e have been first attributed to the hexa - coordination of the metal center which might prevent the substrate to access the manganese coordination sites ( Fig . 25a ) . As a result , attempts to isolate complexes with labile\u0026nbsp;..."},{"page_id":"PA62","page_number":"62","snippet_text":"... of the didentate oxalate ligand prevents the formation of. FIG . 26. Molecular structure of the complex [ Mn ( Me3tacn ) ( OCH3 ) ] ( PF6 ) . FIG . 27. Some tacn \u003cb\u003ederivatives\u003c/b\u003e used for the synthesis. 62 S. TANASE and E. BOUWMAN."},{"page_id":"PA63","page_number":"63","snippet_text":"... \u003cb\u003ederivatives\u003c/b\u003e have also been carried out . Bolm and co - workers reported the first asymmetric epoxidation catalyzed by an in situ prepared manganese complex of the ligand 5 depicted in Fig . 27 ( 157 ) . Styrene was converted to styrene\u0026nbsp;..."},{"page_id":"PA64","page_number":"64","snippet_text":"... \u003cb\u003ederivatives\u003c/b\u003e as well as the sensitivity of the corresponding metal complexes to the changes in the Me3tacn structure has led to the development of new manganese catalysts based on polypyridine ligands (158). Feringa and co-workers have\u0026nbsp;..."},{"page_id":"PA82","page_number":"82","snippet_text":"... \u003cb\u003ederivative\u003c/b\u003e which performs also direct strand-cleavage from C10 oxidation of DNA (38). Deoxyribonolactone abasic sites were nevertheless observed by Oyushi and Sugiyama . FIG 4. Mechanism of C10 oxidation of DNA by activated Cu(phen) 2\u0026nbsp;..."},{"page_id":"PA87","page_number":"87","snippet_text":"... \u003cb\u003ederivatives\u003c/b\u003e (43) and copper complexes of benzosulfonamides (40). Dizdaroglu et al . studied the oxidation of nucleobases of . FIG 8. Mechanism of C50 oxidation of DNA by activated Cu(phen) 2 . FIG . 11. Redox events involved in the\u0026nbsp;..."},{"page_id":"PA90","page_number":"90","snippet_text":"... \u003cb\u003ederivatives\u003c/b\u003e were always more active than their isomers with a junction at C2 of phen . Differences between 2- and 3 - Clip - Phen series also clearly appeared during electrochemical analyses of the different copper complexes that\u0026nbsp;..."},{"page_id":"PA91","page_number":"91","snippet_text":"... \u003cb\u003ederivatives\u003c/b\u003e . So , conjugates of Cu ( Clip - Phen ) with the natural polyamine spermine have shown an enhanced nuclease activity after their activation in the presence of a reductant and air ( 83 ) . Interestingly , an analog containing\u0026nbsp;..."},{"page_id":"PA93","page_number":"93","snippet_text":"... \u003cb\u003ederivatives\u003c/b\u003e ( bleomycin ) ( 45,46,118 ) , polyphenols ( catechin , resor- sinol ) ( 119-121 ) or methoxyphenols ( syringaresinol , syringaldehyde ) ( 119 ) , ami- noquinone ( mitomycine C ) ( 122 ) ; ( iv ) pollutants and their\u0026nbsp;..."},{"page_id":"PA102","page_number":"102","snippet_text":"... \u003cb\u003ederivative\u003c/b\u003e of the meso - tetrakis- ( 2 - N - methylpyridiniumyl ) - porphyrin isomer was surprisingly stable ( a few minutes ) allowing its char- acterization by 1H NMR ( 166 ) . Recently , a direct proof of a manganese - oxo salen\u0026nbsp;..."},{"page_id":"PA104","page_number":"104","snippet_text":"... \u003cb\u003ederivative\u003c/b\u003e was a better DNA cleaving agent than the salen \u003cb\u003ederivative\u003c/b\u003e . To achieve similar levels of double - strand scission the salen complex had to be used in higher concentration and for longer time com- pared to the Mn - TMPyP\u0026nbsp;..."},{"page_id":"PA106","page_number":"106","snippet_text":"... \u003cb\u003ederivative\u003c/b\u003e carrying four pyridi- nium substituents was more active than the porphyrin with three charges and so forth ( 185 ) . The shape of the porphyrin was important too . Porphyrin \u003cb\u003ederivatives\u003c/b\u003e with 2 - N - methylpyridiniumyl groups\u0026nbsp;..."},{"page_id":"PA107","page_number":"107","snippet_text":"... \u003cb\u003ederivatives\u003c/b\u003e owing to the higher affinity binding constant of this metalloporphyrin with DNA and to the efficiency of the formation of the high - valent manganese - oxo species with KHSO5 under physiological conditions . D.2\u0026nbsp;..."},{"page_id":"PA114","page_number":"114","snippet_text":"... \u003cb\u003ederivative\u003c/b\u003e of guanine , ( G - H ) + , which is trapped by the most electrophilic entity in the reaction medium , namely KHSO5 . After several steps , the imidazolone \u003cb\u003ederivative\u003c/b\u003e formed after the release of formamide which could also be\u0026nbsp;..."},{"page_id":"PA115","page_number":"115","snippet_text":"... \u003cb\u003ederivative\u003c/b\u003e was not the major product . The HPLC peak detected at 260 nm ( Fig . 29A ) and containing this lesion ( in - line ESI - MS data ) eluted at a retention time of 40.1 min . This product incorporated one oxygen atom from labeled\u0026nbsp;..."},{"page_id":"PA116","page_number":"116","snippet_text":"... \u003cb\u003ederivative\u003c/b\u003e 32 ( Fig . 30 ) is deduced from labeling data and from literature on a related product found from guanine oxidation ( 257 ) or 8 - oxoguanine oxidation , namely , a spiroiminodihydantoin \u003cb\u003ederivative\u003c/b\u003e ( 258-260 ) . Labeling\u0026nbsp;..."},{"page_id":"PA117","page_number":"117","snippet_text":"... \u003cb\u003ederivative\u003c/b\u003e 35 in amounts compatible with NMR analysis (261). However, 35 is not stable and was ¢rst stabilized in two ways for the FIG . 32. Characterization of the dehydro-guanidinohydantoin \u003cb\u003ederivative\u003c/b\u003e by its. DNA OXIDATION BY COPPER\u0026nbsp;..."},{"page_id":"PA118","page_number":"118","snippet_text":"... \u003cb\u003ederivative\u003c/b\u003e by its hydrolysis into an oxaluric acid \u003cb\u003ederivative\u003c/b\u003e or its reduction into a mixture of two diastereoisomers of a guanidinohydantoin \u003cb\u003ederivative\u003c/b\u003e on a dinucleotide. Numbering of carbon atoms corresponds to that of guanine. NMR\u0026nbsp;..."},{"page_id":"PA139","page_number":"139","snippet_text":"... . A number of AO protein X-ray studies are available, including a \u003cb\u003ederivative\u003c/b\u003e with an end-on (hydro)peroxo moiety present (48). Recently, structures of laccase have been LIGAND INFLUENCES IN COPPER-DIOXYGEN COMPLEX-FORMATION 139."},{"page_id":"PA146","page_number":"146","snippet_text":"... \u003cb\u003ederivatives\u003c/b\u003e of the TREN ligand ( Fig . 8 ) have been used for Cu1 / O2 chemistry : At -90 ° C in acetone the copper ( I ) complex of the hexamethyl substituted TREN ligand ( Fig . 8 , R1 and R2 = Me ) produces an end - on peroxo\u0026nbsp;..."},{"page_id":"PA188","page_number":"188","snippet_text":"... \u003cb\u003ederivative\u003c/b\u003e are simultaneously bound to the metal centers , that is the neces- sary condition to promote the enzymatic activities of catechol oxidase and tyrosinase ( see below ) . Therefore , in the case of hemocyanin the catecholase\u0026nbsp;..."},{"page_id":"PA193","page_number":"193","snippet_text":"... \u003cb\u003ederivative\u003c/b\u003e of laccase where type 1 Cu has been replaced with the. FIG. 3. Structure of the active site of multicopper oxidases. Type 1 Cu in fungal laccase lacks the methionine ligand. in a sequence of two-electron steps by multicopper\u0026nbsp;..."},{"page_id":"PA198","page_number":"198","snippet_text":"... \u003cb\u003ederivatives\u003c/b\u003e, which are therefore much less frequently employed. Aliphatic amine donors, generally tertiary amine groups, normally occur in the linking units between heterocyclic residues; however, chelating ligands with entirely\u0026nbsp;..."},{"page_id":"PA208","page_number":"208","snippet_text":"... . Mechanism of hydroxylation of a series of para - X - C6H4O ̄Li + \u003cb\u003ederivatives\u003c/b\u003e by the dioxygen complex [ Cu2 ( LPy2 ) 2 ( O2 ) ] 2+ at -94 ° C . is very similar to the reaction constant recently determined by. 208 G. BATTAINI et al ."},{"page_id":"PA224","page_number":"224","snippet_text":"... \u003cb\u003ederivatives\u003c/b\u003e of the enzyme show that the EPR active copper in the cluster is one of the type 3 Cu centers and, therefore, the magnetic coupling must occur between the remain- ing type 3 Cu and type 2 Cu (187). Then the coupling pattern\u0026nbsp;..."},{"page_id":"PA238","page_number":"238","snippet_text":"... \u003cb\u003ederivatives\u003c/b\u003e are more reac- tive than the o - \u003cb\u003ederivative\u003c/b\u003e . Remarkably m - substituted benzyl alcohols display larger reactivities than p - substituted benzyl alcohols . Whittaker performed quantitative structure - activity correlation\u0026nbsp;..."},{"page_id":"PA243","page_number":"243","snippet_text":"... \u003cb\u003ederivatives\u003c/b\u003e form a unique case : one - electron oxidation of TEMPO affords the oxoammonium cation which oxidizes the alcohol via a heterolytic pathway ( Fig . 6 ) , giving the carbonyl product and the hydroxylamine . The T1 copper\u0026nbsp;..."},{"page_id":"PA250","page_number":"250","snippet_text":"... \u003cb\u003ederivatives\u003c/b\u003e, namely ( )-N,N0-bis(3,5-di-tert-butylsalicylidene)- trans-cyclohexane-1,2-diamine and ( )-N,N0-bis(3,5-di-tert-butylsalicyl)- trans-cyclohexane-1,2-diamine (H2Lam) of Cu(OAc) 2 H2O and sodium hydroxide as shown in Fig. 13\u0026nbsp;..."},{"page_id":"PA252","page_number":"252","snippet_text":"... \u003cb\u003ederivatives\u003c/b\u003e , namely 2,3 - dimethylbutane - 2,3 - diol and 1,1,2,2 - tetraphenyl- ethane - 1,2 - diol ... \u003cb\u003ederivative\u003c/b\u003e by the second phenoxyl radical . In the case of 2 - propanol and diphenylmethanol , two alcohol molecules\u0026nbsp;..."},{"page_id":"PA274","page_number":"274","snippet_text":"... \u003cb\u003ederivatives\u003c/b\u003e in the presence of 10 to 15 equivalents of dihydrogen peroxide. Secondary alcohols like cyclohexanol or 1-phenylethanol were oxidized faster to the correspond- ing ketones using only 5 equivalents of dihydrogen peroxide\u0026nbsp;..."},{"page_id":"PA281","page_number":"281","snippet_text":"... \u003cb\u003ederivatives\u003c/b\u003e 93 polyphenols 93 polypyrrole 93 Arene residue 199 reaction 179 ring 201 , 202 hydroxylation 201 , 203 ligand substituents 53 Aromatic hydrocarbons hydroxylation 53 , 54 , 132 , 165–7 , 177 , 203 electrophilic substitution\u0026nbsp;...","page_url":"https://books.google.com.sg/books?id=UgNp8-wq-aAC\u0026pg=PA281\u0026vq=derivative\u0026dq=subject:%22Science+Chemistry%22"},{"page_id":"PA285","page_number":"285","snippet_text":"... \u003cb\u003eDerivatives\u003c/b\u003e in the s- and p - Block Elements Supported by Poly ( pyrazolyl ) borato Ligation : Models for Carbonic Anhydrase , Receptors for Anions , and the Study of Controlled Crystallographic Disorder Gerard Parkin INDEX VOLUME 43\u0026nbsp;...","page_url":"https://books.google.com.sg/books?id=UgNp8-wq-aAC\u0026pg=PA285\u0026vq=derivative\u0026dq=subject:%22Science+Chemistry%22"},{"page_id":"PA288","page_number":"288","snippet_text":"... \u003cb\u003eDerivatives\u003c/b\u003e Lincoln A. Hall and David J. Williams Applications for Polyaza Macrocycles with Nitrogen - Attached Pendant Arms Kevin P. Wainwright Perfluorinated Cyclic Phosphazenes Anil J. Elias and Jean \u0026#39; ne M. Shreeve INDEX VOLUME 54\u0026nbsp;..."}],"search_query_escaped":"derivative"},{});</script></div></div></div><script>(function() {var href = window.location.href;if (href.indexOf('?') !== -1) {var parameters = href.split('?')[1].split('&');for (var i = 0; i < parameters.length; i++) {var param = parameters[i].split('=');if (param[0] == 'focus') {var elem = document.getElementById(param[1]);if (elem) {elem.focus();}}}}})();</script>